Abstract:
Cathodoluminescent petrography of crinoidal limestones and dolomites from the Mississippian (Osagean) Burlington and Keokuk Formations in Iowa and Illinois has revealed a complex diagenetic history of calcite cementation, dolomitization, chertification and compaction. Dolomite occurs abundantly in subtidal, open-marine facies throughout the study area. Three luminescently and chemically distinct generations of dolomite can be recognized regionally. Dolomite I, the oldest generation, is luminescent, thinly zoned, and occurs mainly as a replacement of lime mud. Dolomite II has dull red unzoned luminescence, and occurs mainly as a replacement of dolomite I rhombs. Dolomite III is non-luminescent, and occurs as a syntaxial cement on, and replacement of, older dolomite I and II rhombs. Petrography of these dolomite generations, integrating calcite cement stratigraphy, chertification and compaction histories has established the diagenetic sequence. Dolomites I and II pre-date all calcite cements, most chert, intergranular compaction and styloites. Dolomite III precipitation occurred within the calcite cement sequence, after all chert, and after at least some stylolitization. The stratigraphic limit of these dolomites to rocks older than the St Louis Limestone (Meramecian) suggests that dolomitization took place before or during a regional mid-Meramecian subaerial unconformity. A single dolomitization model cannot reasonably explain all three generations of dolomite in the Burlington and Keokuk limestones. Petrographic and geochemical characteristics coupled with timing constraints suggest that dolomite I formed in a sea water-fresh water mixing zone associated with a meteoric groundwater system established beneath the pre-St Louis unconformity. Dolomite II and III may have formed from externally sourced warm brines that replaced precursor dolomite at shallow burial depths. These models therefore suggest that the required Mg for dolomite I was derived mainly from sea water, whereas that for dolomites II and III was derived mainly from precursor Burlington--Keokuk dolomites through replacement or pressure solution