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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That age of caves is the ages of individual caves may vary enormously. in most regions the youngest cave passages have reached their present dimensions during the last 10,000 years, or since the last pleistocene glacial retreat. in higher latitudes most caves can be related to erosion during the later pleistocene climatic variations of the last million years, and older caves have largely been removed by continuing surface lowering. in tropical regions less interrupted erosion conditions have encouraged survival of older caves; the mulu caves of sarawak include large passages at least two million years old. relict caves hundreds of millions of years old may survive in some buried limestones, but are commonly filled with younger sediments (see neptunian deposits), minerals or, very rarely, igneous rocks. these fill materials may themselves be dateable, either on the basis of contained fossil material (including pollen), by comparison with similar rock types that occur at the surface or by isotopic age determination methods identical to those applied to suitable surface rock materials. see also dating of cave sediments [9].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for binding (Keyword) returned 4 results for the whole karstbase:
Marine carbonate cements, which are superficially like travertines from meteoric caves, are coating and binding some intertidal sedimentary rock surfaces occurring in coastal Abu Dhabi, the United Arab Emirates, (UAE). Near Jebel Dhana these surficial cements can be up to 3 cm thick and envelope beach rock surfaces and fossils. They are also present both as thin coats and a fracture-fill cement in the intertidal hard grounds associated with the Khor Al Bazam algal flats. The thickness, microscopic characteristics, and morphology of the marine cement coatings from Jebel Dhana indicates incremental deposition of aragonite in conjunction with traces of sulfate minerals. Most of these cement coatings are micritic, but the layers which encrust the hard grounds from the algae flat of the Khor al Bazam have a more radial and fibrous micro-structure and are composed solely of aragonite. The stable isotopic composition of coatings from Jebel Dhana (delta(18)O = .35, delta(13)C = .00) falls within the compositional range for modem marine non skeletal aragonite and suggests that the marine travertine-like cements precipitate from the agitated slightly hypersaline Arabian Gulf sea water during repeated cycles of exposure, evaporation and immersion. Similar cement coatings and microfabrics are present in the tepee structured and brecciated sediments of the Guadalupe Mountains (Permian) and the Italian Alps (Triassic), in Holocene algal head cements from the Great Salt Lace, and in similar Tertiary algal heads in the Green River Formation of the western US. The petrographic similarity of these ancient ''flow stone'' like cements with Recent hypersaline marine cement coatings suggests that high rates of carbonate cementation and hypersaline conditions contribute to tepee formation and cavity fill

Kinetics and mechanisms of precipitation of calcite as affected by P-CO2 and organic ligands at 25 degrees C, 1998, Lebron I. , Suarez D. L. ,
This study was conducted to develop a model for the precipitation rate of calcite under varying CO2 partial pressures and concentrations of dissolved organic carbon (DOG). Precipitation rates of calcite were measured in solutions with supersaturation values (Omega) between 1 and 20 and in the presence of 2 m(2)L(-1) of calcite. Experiments were run at partial pressures of CO2 (P-CO2) in the range of 0.035-10 kPa and DOC concentrations in the range of 0.02-3.50 mM. The effects of these two variables were quantified separately for the precipitation mechanisms of crystal growth and heterogeneous nucleation. We found an increase in precipitation rate (at constant Omega) when P-CO2 increased. For constant Omega, we also found a linear relationship between calcite precipitation rate and activity of CaHCO3, indicating that CaHCO3 species have an active role in the mechanism of calcite precipitation. These findings suggest that the increase in the precipitation rate with higher P-CO2 levels is likely caused by the increase in the negative charge on the calcite surface together with an increase in the activity of CaHCO3 species in solution. The mechanism of inhibition of calcite crystal growth by organic ligands has been shown to be surface coating of the crystals by DOG. The amount of DOC adsorbed on the surface of the calcite crystals follows a Langmuir isotherm for all the P-CO2 levels studied; however, the amount of DOC necessary to inhibit calcite precipitation increased. With increasing P-CO2, the negative charge on the crystal increases, which affects crystal growth, but also these increases in P-CO2 cause a decrease in the solution pH and increase in the ionic strength for constant Omega. Solution pH and ionic strength affect the structure and degree of dissociation of the organic functional groups, which in turn affects the and DOC concentration on the inhibition of crystal growth and heterogeneous nucleation. The effect of P-CO2 and DOC concentration on the precipitation rate of calcite is expressed in a precipitation rate model which reflects the contributions of crystal growth and heterogeneous nucleation. Copyright (C) 1998 Elsevier Science Ltd

Comparison of immunofluorescence assay and immunomagnetic electrochemiluminescence in detection of Cryptosporidium parvum oocysts in karst water samples, 2003, Kuczynska E. , Boyer D. G. , Shelton D. R. ,
Immunofluorescence assay (IFA) and immunomagneticelectrochemiluminescence (IM-ECL) were used for comparison of the percent recovery of Cryptosporidium parvum in environmental water samples obtained from a spring draining a karst basin. The monoclonal antibodies to C. parvum, isotype IgG3 were used for optimization of the IM-ECL protocol. The combination of biotinylated and TAG-labeled anti-C. parvum antibodies with the streptavidin beads gave a linear regression slope for log ECL vs. log fresh oocysts of 0.79 (from 5 to 5000 oocysts), which indicates a constant ECL signal per oocyst. Standard curves gave a dynamic range of 5 to 5000 oocysts/ml (fresh) and 10 to 100,000 cells/ml (4-month-old oocysts) with the maximum limit of linear detection higher than 100,000. The linear slope of 4-month-old oocysts decreased to 0.62, which indicates that ECL signal is a function of oocyst age. The experiment associated with bead storage time shows that even after 4 months of storage of the biotinylated antibodies, the complex retains the ability for binding the oocysts and generating the ECL signal. Based on the IFA results in the experiment evaluating different protocols for oocysts recovery from karst water samples, the most efficient protocol involved dispersion, followed by flotation and immunomagnetic separation (IMS) (24% recovery). The ECL results obtained in that experiment were very similar to the results obtained in the IFA method, which indicates that the IM-ECL method is accurate. Results of the IFA in the study of the prevalence of C. parvum in the groundwater showed that oocysts were present in 78% of 1 L water samples with average number of oocysts of 6.4 5.5 and ranged from 0 (13 samples) to 23.3 (2 samples). The ECL signal generated from these water samples ranged from 3771 to 622 (average 1620 465). However, the background value estimated in groundwater samples with low number of oocysts detected by IFA was highly variable and elevated (from 3702 to 272, average 1503 475). The background value as a result of nonspecific binding to beads by unidentified organic components in the water can inhibit or even completely mask the signal generated by oocysts. Our investigations showed that the IM-ECL method appears to be promising for the qualitative and quantitative detection of C parvum from the environmental water; however, the method requires further development to improve sensitivity and account for background signals. Published by Elsevier Science B.V

From soil to cave: Transport of trace metals by natural organic matter in karst dripwaters, 2012, Hartland A. , Fairchild I. J. , Lead J. R. , Borsato A. , Baker A. , Frisia S. , Baalousha M.

This paper aims to establish evidence for the widespread existence of metal binding and transport by natural organic matter (NOM) in karst dripwaters, the imprint of which in speleothems may have important climatic significance. We studied the concentration of trace metals and organic carbon (OC) in sequentially filtered dripwaters and soil leachates from three contrasting sites: Poole's Cavern (Derbyshire, UK), Lower Balls Green Mine (Gloucestershire, UK) and Grotta di Ernesto (Trentino, Italy). The size-distribution of metals in the three soils was highly similar, but distinct from that found in fractionated dripwaters: surface-reactive metals were concentrated in the coarse fraction (>100 nm) of soils, but in the fine colloidal (b100 nm) and nominally dissolved (b1 nm) fractions of dripwaters. The concentration of Cu, Ni and Co in dripwater samples across all sites were well correlated (R2=0.84 and 0.70, Cu vs. Ni, Cu vs. Co, respectively), indicating a common association. Furthermore, metal ratios (Cu:Ni, Cu:Co) were consistent with NICA-Donnan n1 humic binding affinity ratios for these metals, consistent with a competitive hierarchy of binding affinity (Cu>Ni>Co) for sites in colloidal or dissolved NOM. Large shifts in Cu:Ni in dripwaters coincided with high fluxes of particulate OC (following peak infiltration) and showed increased similarity to ratios in soils, diagnostic of qualitative changes in NOMsupply (i.e. fresh inputs of more aromatic/hydrophobic soil organic matter (SOM) with Cu outcompeting Ni for suitable binding sites). Results indicate that at high-flows (i.e. where fracture-fed flow dominates) particulates and colloids migrate at similar rates, whereas, in slow seepage-flow dripwaters, particulates (>1 μm) and small colloids (1–100 nm) decouple, resulting in two distinct modes of NOM–metal transport: high-flux and low-flux. At the hyperalkaline drip site PE1 (in Poole's Cavern), high-fluxes of metals (Cu, Ni, Zn, Ti, Mn, Fe) and particulate NOM occurred in rapid, short-lived pulses following peak infiltration events, whereas low-fluxes of metals (Co and V>Cu, Ni and Ti) and fluorescent NOM (b ca. 100 nm) were offset from infiltration events, probably because small organic colloids (1–100 nm) and solutes (b1 nm) were slower to migate through the porous matrix than particulates. These results demonstrate the widespread occurrence of both colloidal and particulate NOM–metal transport in cave dripwaters and the importance of karst hydrology in affecting the breakthrough times of different species. Constraints imposed by soil processes (colloid/particle release), direct contributions of metals and NOM from rainfall, and flow-routing (colloid/particle migration) are expected to determine the strength of correlations between NOM-transported metals in speleothems and climatic signals. Changes in trace metal ratios (e.g. Cu:Ni) in speleothems may encode information on NOMcomposition, potentially aiding in targeting of compound-specific investigations and for the assessment of changes in the quality of soil organic matter.

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