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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That epikarst; epikarst zone is a relatively thick (the thickness may vary significantly, but 15 to 30 meters thick is a good generalization) portion of bedrock that extends from the base of the soil zone and is characterized by extreme fracturing and enhanced solution. it is separated from the phreatic zone by an inactive, relatively waterless interval of bedrock that is locally breached by vadose percolation. significant water storage and transport are known to occur in this zone. synonym: subcutaneous zone.?

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
See all featured articles
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for constituents (Keyword) returned 21 results for the whole karstbase:
Showing 1 to 15 of 21
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, , Bontognali Tomaso R. R. , D’angeli Ilenia M. , Tisato Nicola, Vasconcelos Crisogono, Bernasconi Stefano M. , Gonzales Esteban R. G. , De Waele Jo

Unusual speleothems resembling giant mushrooms occur in Cueva Grande de Santa
Catalina, Cuba. Although these mineral buildups are considered a natural heritage, their
composition and formation mechanism remain poorly understood. Here we characterize
their morphology and mineralogy and present a model for their genesis. We propose that
the mushrooms, which are mainly comprised of calcite and aragonite, formed during four
different phases within an evolving cave environment. The stipe of the mushroom is an
assemblage of three well-known speleothems: a stalagmite surrounded by calcite rafts
that were subsequently encrusted by cave clouds (mammillaries). More peculiar is the
cap of the mushroom, which is morphologically similar to cerebroid stromatolites and
thrombolites of microbial origin occurring in marine environments. Scanning electron
microscopy (SEM) investigations of this last unit revealed the presence of fossilized
extracellular polymeric substances (EPS)—the constituents of biofilms and microbial
mats. These organic microstructures are mineralized with Ca-carbonate, suggesting that
the mushroom cap formed through a microbially-influenced mineralization process. The
existence of cerebroid Ca-carbonate buildups forming in dark caves (i.e., in the absence
of phototrophs) has interesting implications for the study of fossil microbialites preserved
in ancient rocks, which are today considered as one of the earliest evidence for life on

Carbonate rocks in the Black Sea basin: indicators for shallow water and subaerial exposure during Miocene--Pliocene time, 1979, Stoffers P. , Muller G. ,
Drilling in the Black Sea in general revealed three types of sediments: terrigenous, chemical, and biogenic. Terrigenous muds predominate in the Pleistocene whereas chemical sediments are abundant in the lower Pleistocene--Pliocene to Late Miocene sedimentary section. Biogenic constituents play a minor role only. The chemical sediments include calcite (lake chalk), Mg-calcite, aragonite, siderite and dolomite. Among these, the dolomites of Pliocene to Late Miocene age are most interesting. They were encountered in the two drill sites close to the Bosporus drilled in 2115 to 1750 m water depth, respectively. The dolomites show a great variety of criteria (e.g. intraclasts, algae mats, crusts, pellets, oolites), indicating a shallow water environment with occasional subaerial exposure and supratidal evaporitic conditions. The formation of these shallow water carbonates in the Black Sea is supposed to correlate with the Messinian salinity crisis in the Mediterranean

Travertines: depositional morphology and the bacterially constructed constituents, 1984, Chafetz H. S. , Folk R. L.

A Preliminary Survey of Water Chemistry in the Limestone of the Buchan Area Under Low Flow Conditions, 1984, Ellaway Mark, Finlayson Brian

Water samples from selected sites in the Buchan area were collected on two different occasions (survey 1 and survey 2) in an preliminary attempt to characterise the samples taken in terms of chemical composition. Chemical constituents such as Ca++, Mg++, and titration alkalinity (as mg/l CaCO3) varied considerably and ranged from 9.0 - 187.0 mg/l, 2.5 - 43.3 mg/l and 27 - 417 mg/l (survey 1) and 3.5 - 188.7 mg/l, 3.5 - 40.0 mg/l and 44 - 424 mg/l (survey 2) respectively. This range in values is attributed to the differing lithology of the sample sites chosen and reflects the geological control on water chemistry of karst landscapes. A computer program for determining equilibrium speciation of aqueous solutions was used to calculate partial pressure of carbon dioxide and saturation indices with respect to calcite and dolomite.

Chemical hydrogeology in natural and contaminated environments, 1989, Back W, Baedecker Mj,
Chemical hydrogeology, including organic and inorganic aspects, has contributed to an increased understanding of groundwater flow systems, geologic processes, and stressed environments. Most of the basic principles of inorganic-chemical hydrogeology were first established by investigations of organic-free, regional-scale systems for which simplifying assumptions could be made. The problems of groundwater contamination are causing a shift of emphasis to microscale systems that are dominated by organic-chemical reactions and that are providing an impetus for the study of naturally occurring and manmade organic material. Along with the decrease in scale, physical and chemical heterogeneity become major controls.Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how application of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Phenomena associated with the mixing zone generated by encroaching sea water include an increase in heterogeneity of permeability, diagenesis of minerals, and formation of geomorphic features, such as caves, lagoons, and bays. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity and consequences of organic reactions in determining the distributions and concentrations cf. constituents are provided by several studies, including infiltration of sewage effluent and migration of creosote in coastal plain aquifers. These studies show that heterogeneity and the dominance of organically controlled reactions greatly increase the complexity of investigations

Karst Geomorphology and Hydrogeology of the Northeastern Mackenzie Mountains, District of Mackenzie, N.W.T., PhD Thesis, 1995, Hamilton, James P.

This thesis describes the geomorphology and hydrogeology of karst systems in portions of the northeastern Canyon Ranges of the Mackenzie Mountains and the Norman Range of the Franklin Mountains. N.W.T. In the region, mean annual temperatures are -6 to -8°C, total annual precipitation is 325 to 500 mm, and permafrost has a widespread to continuous distribution. The area was glaciated in the Late Wisconsinan by the Laurentide Ice Sheet.
The Canyon Ranges and Norman Range are composed of a sequence of faulted and folded miogeoclinal sedimentary rocks that span the Proterozoic to Eocene. The geology is reviewed with an emphasis on strata that display karst. Included are several dolomite and limestone formations, two of which are interbedded with evaporites in the subsurface. The principal groundwater aquifer is the Lower Devonian Bear Rock Formation. In subcrop, the Bear Rock Formation is dolomite and anhydrite, outcrops are massive calcareous solution breccias. This is the primary karst rock.
The regional distribution and range of karst landforms and drainage systems are described. Detailed mapping is presented from four field sites. These data were collected from aerial photography and ground surveys. The karst has examples of pavement, single and compound dolines, subsidence troughs, polje, sinking streams and lakes. and spring deposits. The main types of depressions are subsidence and collapse dolines. Doline density is highest on the Bear Rock Formation. Surficial karst is absent of less frequent in the zone of continuous permafrost or outside the glacial limit.
At the field sites, water samples were collected at recharge and discharge locations. Samples were analyzed for a full range of ionic constituents and many for natural isotopes. In addition, several springs were monitored continuously for discharge, temperature, and conductivity. Dye tracing established linkages between recharge and discharge at some sites. These data are summarized for each site, as is the role of permafrost in site hydrology.
The relationships between geological structure, topography, ,and groundwater systems are described. Conduit aquifers are present in both dolomite and limestone. These systems are characterized by discharge waters of low hardness and dissolved ion content. Aquifers in the Bear Rock Formation have a fixed flow regime and often have highly mineralized discharge. At the principal field site. there was a time lag of 40 to 60 days between infiltration and discharge in this unit. At a second site, flow through times were on the order of years. Variability in these systems is attributed to bedrock properties and boundary conditions.
Preliminary rates of denudation are calculated from the available hydrochemical data. Total solutional denudation at the primary field site is approximately 45 m³ kmˉ² aˉ¹ (mm kaˉ¹). The majority is attributed to the subsurface dissolution of halite and anhydrite. The predominance of subsurface dissolution is linked to the high frequency of collapse and subsidence dolines and depressions.
The karst features and drainage systems of the northern Mackenzie Mountains date to the Tertiary. Glaciation has had a stimulative effect on karst development through the subglacial degradation of permafrost and the altering of boundary conditions by canyon incision.

Dated co-occurrence of Homo erectus and Gigantopithecus from Tham Khuyen Cave, Vietnam, 1996, Ciochon R, Long Vt, Larick R, Gonzalez L, Grun R, Devos J, Yonge C, Taylor L, Yoshida H, Reagan M,
Tham Khuyen Cave (Lang Son Province, northern Vietnam) is one of the more significant sites to yield fossil vertebrates In east Asia, During the mid-1960s, excavation in a suite of deposits produced important hominoid dental remains of middle Pleistocene age, We undertake more rigorous analyses of these sediments to understand the fluvial dynamics of Pleistocene cave infilling as they determine how skeletal elements accumulate within Tham Khuyen and other east Asian sites, Uranium/thorium series analysis of speleothems brackets the Pleistocene chronology for breaching, infilling, and exhuming the regional paleokarst, Clast analysis indicates sedimentary constituents, Including hominoid teeth and cranial fragments, accumulated from very short distances and under low fluvial energy, Electron spin resonance analysis of vertebrate tooth enamel and sediments shows that the main fossil-bearing suite (S1-S3) was deposited about 475 thousand years ago, Among the hominoid teeth excavated from S1-S3, some represent Homo erectus and Gigantopithecus blacki, Criteria are defined to differentiate these teeth from more numerous Pongo pygmaeus elements, The dated cooccurrence of Homo erectus and Gigantopithecus blacki at Tham Khuyen helps to establish the long co-existence of these two species throughout east Asia during the Early and Middle Pleistocene

Interactions between ground water and surface water in the Suwannee River Basin, Florida, 1997, Katz B. G. , Dehan R. S. , Hirten J. J. , Catches J. S. ,
Ground water and surface water constitute a single dynamic system in most parts of the Suwannee River basin due to the presence of karst features that facilitate the interaction between the surface and subsurface. Low radon-222 concentrations (below background levels) and enriched amounts of oxygen-18 and deuterium in ground water indicate mixing with surface water in parts of the basin. Comparison of surface water and regional ground water flow patterns indicate that boundaries for ground water basins typically do not coincide with surface water drainage subbasins. There are several areas in the basin where around water flow that originates outside of the Suwannee River basin crosses surface water basin boundaries during both low-flow and high-flow conditions. In a study area adjacent to the Suwannee River that consists predominantly of agricultural land use, 18 wells tapping the Upper Floridan aquifer and 7 springs were sampled three times during 1990 through 1994 for major dissolved inorganic constituents, trace elements, and nutrients. During a period of above normal rainfall that resulted in high river stage and high ground water levels in 1991, the combination of increased amounts of dissolved organic carbon and decreased levels of dissolved oxygen in ground water created conditions favorable for the natural reduction of nitrate by denitrification reactions in the aquifer. As a result, less nitrate was discharged by ground water to the Suwannee River

Minor, trace and ultra-trace constituents of speleothems, 1997, James J. M.

Diagenetic concretions from the cave clastic sediment, Cave in Tounj quarry, Croatia, 1998, Lackovič, Damir

Diagenetic concretions from Cave in Tounj quarry (central Croatia) are studied. Concretions are found in non-cemented unsorted clastic cave deposit. They consist of particles of different size (clay to pebble) and from different provenance. One part of calcite and clay minerals are coming from speleothems and cave walls limestone. Detrital particles: chert, quartz, muscovite, chlorite, ilmenite, magnetite and most of clay, are probable transported into the cave from Triassic and Pleistocene clastic sediments from the surface. Autochthonous constituents of concretions are limonitic pizoids and some calcite cement. Composition of concretion is similar to the composition of surrounding non-cemented sediment.

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas, Kansas, Missouri and Oklahoma, USA, 2000, Adamski Jc,
Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate-rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field-measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water-rock interactions. Water from wells flow through small fractures, which restrict how and increase water-rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright (C) 2000 John Wiley & Sons, Ltd

Patterns of collapse chambers in the endokarsts of Mallorca (Balearic Islands, Spain), 2000, Giné, S À, Ngel

A general overview on the patterns of collapse chambers in the karsts of Mallorca is presented. The great significance of single breakdown chambers and strings of large rooms as one of the major constituents of cave patterns is easy to recognize in the cave surveys of many Majorcan caves. Detailed mapping of several collapse features such as breakdown piles, sloped boulder floors, vault profiles, coalescence areas, boulder chokes and dome structures can yield useful information regarding description and better understanding of cave collapse patterns.

Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators, 2001, Panno S. V. , Hackley K. C. , Hwang H. H. , Kelly W. R. ,
The sources of nitrate (NO3-) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO3- concentrations in excess of the USEPA's drinking water standard of 10 mg N/1 Relative to background levels, the NO3- concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO3- to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and delta (15) N and delta O-18 of the NO3- ions. The isotopic data were most definitive and suggested that the sources of NO3- in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO3- and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO3- and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for delta N-15 and delta O-18 of the NO3- ranged from 3.2%o to 19.1%o and from 7.2%o to 18.7%o respectively. The trend of delta N-15 and delta O-18 data for NO3- also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. (C) 2001 Elsevier Science B.V. All rights reserved

Transport of suspended solids from a karstic to an alluvial aquifer: the role of the karst/alluvium interface, 2002, Massei N. , Lacroix M. , Wang H. Q. , Mahler B. J. , Dupont J. P. ,
This study focuses on the coupled transport of dissolved constituents and particulates, from their infiltration on a Karst plateau to their discharge from a karst spring and their arrival at a well in an alluvial plain, Particulate markers were identified and the transport of solids was characterised in situ in porous and karstic media, based on particle size analyses, SEM, and traces. Transport from the sinkhole to the spring appeared to be dominated by flow through karst: particulate transport was apparently conservative between the two sites, and there was little difference in the overall character of the particle size distribution of the particulates infiltrating the sinkhole and of those discharging from the spring. Qualitatively, the mineralogy of the infiltrating and discharging material was similar, although at the spring an autochthonous contribution from die aquifer was noted (chalk particles eroded from the parent rock by weathering). In contrast, transport between the spring and the well appears to be affected by the overlying alluvium: particles in the water from the well, showed evidence of considerable size-sorting. Additionally, SEM images of the well samples showed the presence of particles originating from the overlying alluvial system; these particles were not found in samples from the sinkhole or the spring. The differences between the particulates discharging from the spring and the well indicate that the water pumped from the alluvial plain is coming from the Karst aquifer via the very transmissive, complex geologic interface between the underlying chalk formation and the gravel at the base of the overlying alluvial system. (C) 2002 Elsevier Science B.V. All rights reserved

Eustatic sea-level and climate changes over the last 600 ka as derived from mollusc-based ESR-chronostratigraphy and pollen evidence in Northern Eurasia, 2002, Molodkov Anatoly N. , Bolikhovskaya Nataliya S. ,
We reconstruct and correlate palaeoclimatic events and deposits from shelf, glacial, periglacial, and extraglacial zones of northern Eurasia over the last 600,000 years. The chronostratigraphical correlation of identified palaeoenvironmental and sea-level events and corresponding horizons is based on electron spin resonance (ESR) analysis of subfossil mollusc skeletal remains from marine, freshwater and Acheulian-bearing cave-site deposits. Over 230 shell samples from more than 40 sites along the continental margin of Eurasian north, in the Black and Caspian sea basins and terrestrial shells from a Lower Palaeolithic cave-site in the Northern Caucasus were dated via ESR to produce a late Quaternary geochronology. The Pleistocene composite section of the loess-palaeosoil formation includes two reference sections--Likhvin and Arapovichi--from the centre of the East-European plain. The palyno-chronostratigraphic record is interpreted as the product of six warm-climate/high sea-level events including the current interglacial, and six glacial events. They are presented either as complete climatic rhythms of glacial and interglacial rank, or by considerable portions of climatic-phytocoenotic phases constituents of the rhythm. The full-interglacial conditions are centred at about 580, 400, 310, 220 and between 145-70 calendar ka. A broad correspondence between long palynological sequence, directly ESR-dated warm-climate-related events and other palaeoenvironmental records described in the literature has been noted for 11 upper oxygen isotope stages (11 to 1). The results obtained in this study exemplify the potential of integrated chrono-climatostratigraphic sequences in linking marine and terrestrial palaeoclimate records that may eventually span the whole Brunhes chron

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