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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That magnetic north is the direction to the north magnetic pole at a given place and time. this differs from the direction towards which the north end of a compass points by a small individual compass error and by the effect of any local magnetic attraction [25].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for grading (Keyword) returned 27 results for the whole karstbase:
Showing 1 to 15 of 27
Barbuda--an emerging reef and lagoon complex on the edge of the Lesser Antilles island are, 1985, Brasier M, Donahue J,
The Pliocene to Holocene limestones of Barbuda have formed on a wide, shallow, outlying bank of the Lesser Antilles island arc, some 50 km east of the older axis of the Limestone Caribbees and 100 km east of the newer axis of the active Volcanic Caribbees. Contrasts with neighbouring islands of similar size include the lack of exposed igneous basement or mid-Tertiary sediments, the dominance of younger flat-lying carbonates, and the greater frequency of earthquake shocks. The history of emergence of the island has been studied through aerial reconnaissance, mapping, logging, hand coring, facies and microfacies analysis. These show a pattern of progressively falling high sea level stands (from more than 50 m down to the present level) on which are superimposed at least three major phases of subaerial exposure, when sea levels were close to, or below, their present level. This sequence can be summarized as follows: 1, bank edge facies (early Pliocene Highlands Formation) deposited at not more than c. 50-100 m above the present sea level; 2, emergence with moderate upwarping in the north, associated with the Bat Hole subaerial phase forming widespread karst; 3, older Pleistocene transgression with fringing reefs and protected bays formed at l0 to l5 m high sea level stands (Beazer Formation); 4, Marl Pits subaerial phase with widespread karst and soil formation; 5, late Pleistocene transgression up to m high stand with fringing and barrier reefs, protected backreefs and bays (Codrington Formation Phase I); 6, gradual regression resulting in emergence of reefs, enclosure of lagoons, and progradation of beach ridges at heights falling from c. 5 m to below present sea level (Codrington Phase II); 7, Castle Bay subaerial phase produced karst, caliche and coastal dunes that built eastwards to below present sea level; and 8, Holocene transgression producing the present mosaic, with reefs, lagoons and prograding beach ridge complexes, with the present sea level reached before c. 4085 years BP. The evidence suggests that slight uplift took place in the north of the island after early Pliocene times. Subsequent shoreline fluctuations are consistent with glacio-eustatic changes in sea level, indicating that the island has not experienced significant uplift during the Quaternary

Sannur Cave: A Crescent shaped cave developed in Alabaster formation in Eastern Desert, Egypt, 1995, Gü, Nay G. , Elbedewy F. , Ekmekci M. , Bayari S. , Kurttas T.
An expedition to Egypt set out to explore the Wadi Sannur where no speleological work had taken place. The most notable karst feature identified to date is the Sannur Cave, the largest subterranean chamber known in Egypt. It is situated about 70 km to the southeast of Beni-Suef city in the remote Wadi Sannur of the Eastern Desert where the main rock units belong to Eocene and Pliocene periods. The Eocene is represented by limestone including alabaster which is known to be quarried first by the ancient Egyptians. Sannur Cave is first explored during blasting in the alabaster quarry which caused an artificial entrance to the cave. The cave is a single crescent shape chamber approximately 275 m long and can be arbitrarily divided into two sectionshaving different characteristics; left side gallery and right side gallery. Few speleothems occur in the left side gallery while the right side gallery is decorated intensively with many kinds of spelethem including stalagtites, stalagmites, flowstones, microgours, helictites and soda-straws etc. In addition to surveying the cave, based on the geologic, structural and morphologic observation inside and outside the cave some interpretations on the paleoenvironment an the origin of the cave. Surveying was performed with grade 5D according to BCRA Gradings.

Terrestrial hot-spring Co-rich Mn mineralization in the Pliocene-Quaternary Calatrava Region (central Spain), 1997, Crespo A, Lunar R,
Central Spain hosts a series of high-Co (up to 1.7% Co) Mn mineralizations displaying a variety of morphologies: spring aprons and feeders, pisolitic beds, wad beds and tufa-like replacements of plants and plant debris. The Mn mineralogy consist of cryptomelane, lithiophorite, birnessite and todorokite. The spring apron deposits formed in close proximity to Pliocene volcanic rocks (alkaline basaltic lava flows and pyroclastics) belonging to the so-called Calatrava Volcanic Field. The spring aprons are found along or near to normal faults bounding small basins and topographic highs. Mn tufa-like deposits are found near to the spring sources, while both pisolitic and wad beds are clearly distal facies occuring well within the Pliocene basins. The two latter are interbedded with clastic lacustrine and fluvial sediments. Collectively, these deposits contain a complex suite of Mn-(Co) mineralization ranging from proximal, hot-spring-type Mn facies, grading into more distant sedimentary, stratabound mineralization. Volcanism, basin formation and Mn deposition took place within a failed rift environment which triggered hydrothermal activity and Mn-(Co) deposition as proximal (near to the volcanic axes) and distal (of sedimentary affinities, within the basins) facies

Facies differentiation and sequence stratigraphy in ancient evaporite basins - An example from the basal Zechstein (Upper Permian of Germany), 1999, Steinhoff I. , Strohmenger C. ,
Due to excellent preservation, the Werra Anhydrite (Al), the upper member of the Upper Permian Zechstein cycle I (Ist cycle, Z1), is readily studied in terms of the distribution of sulfate facies and sequence stratigraphy that can be interpreted from these facies. In this study cores taken from seven wells in the Southern Zechstein Basin were examined for their sedimentary structures and various petrographic features. Facies interpretation and depositional sequences are based on detailed examination of core material. Four main facies environments have been identified: (I) supratidal (II) intertidal (III) shallow subtidal, and (IV) deeper (hypersaline) subtidal. These are further subdivided into 10 subfacies types: (1) karst and (2) sabkha within the supratidal environment (I), (3) algal tidal-flat, (4) tidal flat and (5) beach deposit within the intertidal environment (II), (6) salina, and (7) sulfate arenites within the shallow subtidal enviromnent (III). The (8) slope subfacies type commonly associated with (9) turbidites and the (10) basin subfacies type subdivide the deeper subtidal environment (IV). Vertical stacking patterns of these facies and subfacies types reveal the sequence stratigraphic development of the sulfate cycles in response to sea-level and salinity fluctuations. The lower Werra Anhydrite (belonging to Zechstein Sequence ZS2) is characterized by a transgressive systems tract (IST) overlying the transgressive surface of Zechstein Sequence ZS2 within the Al-underlying upper Zechstein Limestone (Cal). The TST of the AT is several tens of meters thick in platform areas, where it is built up by sulfate arenites and swallow-tail anhydrite-after-gypsum, and thins out to a few meters of thickness toward the condensed basinal section, where laminites ('Linien-Anhydrit') are predominant. Most of the Al succession consists of three relatively thick parasequences belonging to the highstand systems tract (HST) that shows typical prograding sets. Enhanced platform Buildup, including sulfate arenites, salina deposits, intertidal sediments, and sabkha precipitation as well as turbidite shedding off the platforms produced marginal ''sulfate walls' up to 400 m thick as platform to slope portions of the Werra Anhydrite. Seaward, the Al thins to a few tens of meters of laminated sulfate basin muds. Increasingly pronounced Al topography during highstand narrowed the slope subfacies belt parallel to the platform margin This contrasts with the broad but considerably thinner slope deposits of transgressive times with much shallower slopes. The ensuing sea-level lowstand is reflected by a sequence boundary on top of the karstified Al-platform and a lowstand wedge (Zechstein Sequence ZS3) overlying portions of the slope and basinal subfacies of the Al highstand systems tract Beyond the lateral limits of the lowstand wedge, the sequence boundary merges with the transgressive surface of ZS3, shown by the lithologic change from the Al anhydrites to the overlying carbonates of the Stassfurt Carbonates ('Haupt Dolomit' Main Dolomite, Ca2). The Basal Anhydrite (A2), which overlies and seals the carbonate reservoir of the Ca2, can also be subdivided into systems tracts by means of facies analysis. It is, however, much less complex than the Al and is comprised almost exclusively of a transgressive systems tract of Zechstein Sequence ZS4

The stratigraphical record and activity of evaporite dissolution subsidence in Spain, 2001, Gutierrez F. , Orti F. , Gutierrez M. , Perezgonzalez A. , Benito G. , Prieto J. G. , Valsero J. J. D. ,
The evaporite formations tin outcrop and at shallow depth) cover an extensive area of the Spanish territory. These soluble sediments are found in diverse geological domains and record a wide time span from the Triassic up to the present day. Broadly, the Mesozoic and Paleogene formations (Alpine cycle) are affected by compressional structures, whereas the Neogene (post-orogenic) sediments remain undeformed. The subsidence caused by subsurface dissolution of the evaporites (subjacent karst) takes place in three main types of stratigraphical settings: a) Subsidence affecting evaporite-bearing Mesozoic and Tertiary successions (interstratal karst); b) Subsidence in Quaternary alluvial deposits related to the exorheic evolution of the present-day fluvial systems (alluvial or mantled karst); c) Subsidence in exposed evaporites (uncovered karst). These types may be represented by paleosubsidence phenomena (synsedimentary and/or postsedimentary) recognizable in the stratigraphical record, or by equivalent currently active or modem examples with surface expression. The interstratal karstification of the Mesozoic marine evaporites and the consequent subsidence of the topstrata is revealed by stratiform collapse breccias and wedge-outs in the evaporites grading into unsoluble residues. In several Tertiary basins, the sediments overlying evaporites locally show synsedimentary and/or postsedimentary subsidence structures. The dissolution-induced subsidence coeval to sedimentation gives place to local thickenings in basin-like structures with convergent dips and cumulative wedge out systems. This sinking process controls the generation of depositional environments and lithofacies distribution. The postsedimentary subsidence produces a great variety of gravitational deformations in the Tertiary supra-evaporitic units including both ductile and brittle structures (flexures, synforms, fractures, collapse and brecciation). The Quaternary fluvial terrace deposits on evaporite sediments show anomalous thickenings (> 150 m) caused by a dissolution-induced subsidence process in the alluvial plain which is balanced by alluvial aggradation. The complex space and time evolution pattern of the paleosubsidence gives place to intricate and anarchical structures in the alluvium which may be erroneously interpreted as pure tectonic deformations. The current subsidence and generation of sinkholes due to suballuvial karstification constitutes a geohazard which affects to large densely populated areas endangering human safety and posing limitations to the development. An outstanding example corresponds to Calatayud historical city, where subsidence severely damages highly valuable monuments. The subsidence resulting from the underground karstification of evaporites has determined or influenced the generation of some important modem lacustrine basins like Gallocanta, Fuente de Piedra and Banyoles lakes. The sudden formation of sinkholes due to the collapse of cave roofs is relatively frequent in some evaporite outcrops. Very harmful and spectacular subsidence activity is currently occurring in the Cardona salt diapir where subsidence has been dramatically exacerbated by mining practices

Water-upwelling pipes and soft-sediment-deformation structures in lower Pleistocene calcarenites (Salento, southern Italy), 2001, Massari F. , Ghibaudo G. , D'alessandro A. , Davaud E. ,
A thin sedimentary blanket, consisting mostly of subtidal, unconformity-bounded calcarenite units, was deposited in the small Novoli graben (Apulian foreland, southern Italy) in Pliocene-Pleistocene time. In a limited part of the study area the lower Pleistocene 'Calcarenite di Gravina,' forming the thicker part of this blanket, is crossed by continuous to discontinuous cylindrical pipes as much as 12 m high, most commonly consisting of stacked concave- upward laminae, locally grading upward into soft-sediment-deformation features and large dishes. The evidence favors an origin linked to upwelling of overpressured groundwater from a large karstic reservoir hosted in the Mesozoic carbonate rocks; the reservoir periodically developed a relatively high hydrostatic head due to Tertiary to Pleistocene cover acting as an aquitard or aquiclude. As a result, submarine springs were generated, the activity of which was primarily controlled by relative sea-level fluctuations. It is suggested that the pipes were located in those points where the hydrostatic pressure was sufficient to fluidize the overlying sediment and could be released without notably affecting the surrounding sediments. Some pipes cross calcarenitic infills of karstic sinkholes developed in the underlying units, whereas others follow the course of vertical to high-angle extensional synsedimentary tectonic fractures generated when the calcarenites were still in an unconsolidated to semiconsolidated state. The former relationships suggest that vertical routes of water upwelling during highstand of base level commonly coincided with axes of vadose solution during base-level lowstand; the latter suggest that opening of fractures enhanced the connection of the deep aquifer with the surface, hence intensifying water upwelling. We think that fluidization along the fractures was not hindered by the partially coherent state, and that pipes with a cylindrical geometry could form in spite of the planarity of the fractures. The formation of the pipes and their internal structure of stacked concave-upward laminae is thought to be consistent with a process of fluidization due to through-flowing waters. We believe that essential in this process is the role of upward-migrating transient water-filled cavities, akin to the voidage waves (Hassett's [1961a, 1961b] parvoids) experimentally reproduced by several authors in liquid fluidized beds, and regarded as true instability phenomena of a fluidized suspension occurring above minimum fluidization velocity. It is suggested that the process is akin to the production of the dish structure. It consists of the filling of transient, upward-migrating, water-filled cavities through steady fallout of particles from the cavity roof, their redeposition in a more consolidated state, and subsidence of the roof due to water seepage upward from the cavity. The process was accompanied by segregation of grains according to their size and density, as well by elutriation of finest particles, and led to a new pattern of sediment texture, packing, and fabric with respect to the surrounding calcarenites

Paleosubsidence and active subsidence due to evaporite dissolution in Spain, 2002, Gutierrez F. , Orti F. , Gutierrez M. , Perezgonzalez A. , Benito G. , Gracia F. J. , Duran J. J. ,
Evaporite formations crop out or are at shallow depth present in an extensive area of Spain. These soluble sediments occur in diverse geological domains and were deposited over a long time span, from the Triassic up to the present day. Broadly, the Mesozoic and Paleogene formations (Alpine cycle) are affected by compressional structures, whereas the Neogene (post-orogenic) sediments remain undeformed. Subsidence caused by subsurface dissolution of evaporites (subjacent karst) takes place in three main types of stratigraphic settings: a) subsidence affecting evaporite-bearing Mesozoic and Tertiary successions (interstratal karst); b) subsidence in Quaternary alluvial deposits related to the exorheic evolution of present-day fluvial systems (alluvial or mantled karst); and c) subsidence in exposed evaporites (uncovered karst). These types may be represented by paleosubsidence phenomena (synsedimentary and/or postsedimentary) recognizable in the stratigraphic record, or by equivalent, currently active or modem examples which have a surface expression. Interstratal karstification of Mesozoic marine evaporites, and the consequent subsidence of overlying strata, is revealed by stratiform collapse breccias and wedge outs of the evaporites grading into unsoluble residues. In several Tertiary basins, the sediments overlying evaporites locally show synsedimentary and/or postsedimentary subsidence structures. Dissolution-induced subsidence coeval with sedimentation is accompanied by local thickening of strata in basin-like structures with convergent dips and cumulative wedge-out systems. This sinking process controls the generation of depositional environments and lithofacies distribution. Postsedimentary subsidence produces a great variety of gravitational deformations in Tertiary supra-evaporitic units, including both ductile and brittle structures (flexures, synforms, fractures, collapse, and brecciation). Quaternary fluvial terrace deposits overlying evaporites show anomalous thickenings (>150 m) caused by a dissolution-induced subsidence process in the alluvial plain, which is balanced by alluvial aggradation. The complex evolution (in time and space) of paleosubsidence leads to intricate and chaotic structures in the alluvium, which may be erroneously interpreted as pure tectonic deformations. The current subsidence and generation of sinkholes due to suballuvial karstification constitutes a geohazard which affects large, densely populated areas, and thus endangers human safety and poses limitations on development. An outstanding example can be seen in Calatayud, an important historical city where subsidence has severely damaged highly valuable monuments. Subsidence resulting from the underground karstification of evaporites has caused or influenced the generation of some important modem lacustrine basins, such as Gallocanta, Fuente de Piedra, and Banyoles Lakes. The sudden formation of sinkholes due to collapse of cave roofs is fairly frequent in some evaporite outcrops. Very harmful and spectacular subsidence activity is currently occurring in the Cardona salt diapir, where subsidence has been dramatically exacerbated by mining practices

Seismic stratigraphy of Late Quaternary deposits from the southwestern Black Sea shelf: evidence for non-catastrophic variations in sea-level during the last ~10[punctuation space]000 yr, 2002, Aksu Ae, Hiscott Rn, Yasar D, Isler Fi, Marsh S,
Detailed interpretation of single channel seismic reflection and Huntec deep-tow boomer and sparker profiles demonstrates that the southwestern Black Sea shelf formed by a protracted shelf-edge progradation since the Miocene-Pliocene. Five seismic-stratigraphic units are recognized. Unit 1 represents the last phase of the progradational history, and was deposited during the last glacial lowstand and Holocene. It is divided into four subunits: Subunit 1A is interpreted as a lowstand systems tract, 1B and 1C are interpreted as a transgressive systems tract, and Subunit 1D is interpreted as a highstand systems tract. The lowstand systems tract deposits consist of overlapping and seaward-prograding shelf-edge wedges deposited during the lowstand and the subsequent initial rise of sea level. These shelf-edge wedges are best developed along the westernmost and easternmost segments of the study area, off the mouths of rivers. The transgressive systems tract deposits consist of a set of shingled, shore-parallel, back-stepping parasequences, deposited during a phase of relatively rapid sea-level rise, and include a number of prograded sediment bodies (including barrier islands, beach deposits) and thin veneers of seismically transparent muds showing onlap onto the flanks of older sedimentary features. A number of radiocarbon dates from gravity cores show that the sedimentary architecture of Unit 1 contain a detailed sedimentary record for the post-glacial sea-level rise along the southwestern Black Sea shelf. These data do not support the catastrophic refilling of the Black Sea by waters from the Mediterranean Sea at 7.1 ka postulated by [Ryan, Pitman, Major, Shimkus, Maskalenko, Jones, Dimitrov, Gorur, Sakinc, Yuce, Mar. Geol. 138 (1997) 119-126], [Ryan, Pitman, Touchstone Book (1999) 319 pp.], and [Ballard, Coleman, Rosenberg, Mar. Geol. 170 (2000) 253-261]

Gypsum wedging and cavern breakdown: Studies in the Mammoth Cave System Kentucky, 2003, White, W. B. , White, E. L.
Many segments of dry passages in the Mammoth Cave System contain an unusual breakdown lying unconformably over underlying stream sediments. The association of many of these breakdown areas with sulfate minerals (primarily gypsum) suggests that crystal wedging and replacement of limestone by gypsum are important factors in this type of cavern collapse. The following features are characteristic of mineral-activated breakdown: 1) Walls and ceilings fractured in irregular patterns often with visible veins of gypsum following the fractures; 2) Breakdown consisting of characteristic thin, irregular splinters and shards of bedrock; 3) Curved plates of bedrock ranging in size from a few centimeters to more than a meter hanging from the ceiling at steep angles and cemented only by a thin layer of gypsum; 4) Collapses that take the form of symmetrical mounds with coarse irregular blocks at the base grading upward into a rock flour at the top. Thin sections of the curved plates clearly show gypsum replacing limestone. Possible sources for the sulfate-bearing solutions are from the weathering of pyrite either at the top of the overlying Big Clifty Sandstone or in the limestone wall rock surrounding the cave passage. Reactions of the percolating solutions produce sulfate minerals in the wallrock adjacent to cave passages. Gypsum and other sulfate minerals created in the wall rock are less dense than calcite and exert sufficient pressure to spall off bits of the rock, some of which remain cemented in place by the gypsum.

Karst development on carbonate islands, 2003, Mylroie J. E. , Carew J. L.

Karst development on carbonate platforms occurs continuously on emergent portions of the platform. Surficial karst processes produce an irregular pitted and etched surface, or epikarst. The karst surface becomes mantled with soil, which may eventually result in the production of a resistant micritic paleosol. The epikarst transmits surface water into vadose pit caves, which in turn deliver their water to a diffuse-flow aquifer. These pit caves form within a 100,000 yr time frame. On islands with a relatively thin carbonate cover over insoluble rock, vadose flow perched at the contact of carbonate rock with insoluble rock results in the lateral growth of vadose voids along the contact, creating large collapse chambers that may later stope to the surface.
Carbonate islands record successive sequences of paleosols (platform emergence) and carbonate sedimentation (platform submergence). The appropriate interpretation of paleosols as past exposure surfaces is difficult, because carbonate deposition is not distributed uniformly, paleosol material is commonly transported into vadose and phreatic voids at depth, and micritized horizons similar in appearance to paleosols can develop within existing carbonates.
On carbonate islands, large dissolution voids called flank margin caves form preferentially in the discharging margin of the freshwater lens from the effects that result from fresh-water/salt-water mixing. Similarly, smaller dissolution voids also develop at the top of the lens where vadose and phreatic fresh-waters mix. Independent of fluid mixing, oxidation of organic carbon and oxidation/reduction reactions involving sulfur can produce acids that play an important role in phreatic dissolution. This enhanced dissolution can produce caves in fresh-water lenses of very small size in less than 15,000 yr. Because dissolution voids develop at discrete horizons, they provide evidence of past sea-level positions. The glacio-eustatic sea-level changes of the Quaternary have overprinted the dissolutional record of many carbonate islands with multiple episodes of vadose, fresh-water phreatic, mixing zone, and marine phreatic conditions. This record is further complicated by collapse of caves, which produces upwardly prograding voids whose current position does not correlate with past sea level positions.
The location and type of porosity development on emergent carbonate platforms depends on the degree of platform exposure, climate, carbonate lithology, and rate of sea-level change. Slow, steady, partial transgression or regression will result in migration of the site of phreatic void production as the fresh-water lens changes elevation and moves laterally in response to sea-level change. The result can be a continuum of voids that may later lead to development solution-collapse breccias over an extended area.

Geology and Geochemistry of the Reocin Zinc-Lead Deposit, Basque-Cantabrian Basin, Northern Spain, 2003, Velasco Francisco, Herrero Jose Miguel, Yusta Inaki, Alonso Jose Antonio, Seebold Ignacio, Leach David,
The Reocin Zn-Pb deposit, 30 km southwest of Santander, Spain, occurs within Lower Cretaceous dolomitized Urgonian limestones on the southern flank of the Santillana syncline. The Reocin deposit is one of the largest known strata-bound, carbonate-hosted, zinc-lead deposits in Europe. The total metal endowment of the deposit, including past production and remaining reserves, is 62 Mt of ore grading 8.7 percent Zn and 1.0 percent Pb. The epigenetic mineralization consists of sphalerite and galena, with lesser marcasite and trace pyrite with dolomite as gangue. Microprobe analyses of different generations of dolomite revealed nonstoichiometric compositions with various amounts of iron (up to 14 mol % of FeCO3). Replacement of host dolomite, open-space filling of fractures, and cementation of breccias derived from dissolution collapse are the principal types of ore occurrence. Detailed cross-section mapping indicates a stratigraphic and structural control on the deposit. A stratiform morphology is present in the western part of the orebody (Capa Sur), whereas mineralization in the eastern part is highly discordant but strata bound (Barrendera). Stratigraphic studies demonstrate that synsedimentary tectonic activity, related to the rifting of the North Atlantic (Bay of Biscay), was responsible for variation in sedimentation, presence of unconformities (including paleokarsts), local platform emergence and dolomitization along the N60 fault trend. In the Reocin area, two stages of dolomitization are recognized. The first stage is a pervasive dolomitization of the limestone country rocks that was controlled by faulting and locally affected the upper part of the Aptian and the complete Albian sequence. The second dolomitization event occurred after erosion and was controlled by karstic cavities. This later dolomitization was accompanied by ore deposition and, locally, filling of dolomite sands and clastic sediments in karstic cavities. The circulation of hydrothermal fluids responsible for sulfide deposition and the infilling of karst cavities were broadly contemporaneous, indicating a post-Albian age. Vitrinite reflectance data are consistent with previously measured fluid inclusion temperatures and indicate temperatures of ore deposition that were less than 100{degrees}C. Carbon and oxygen isotopic data from samples of regional limestone, host-rock dolostone and ore-stage dolomite suggest an early hydrothermal alteration of limestone to dolostone. This initial dolomitization was followed by a second period of dolomite formation produced by the mixing of basinal metal-rich fluids with local modified seawater. Both dolomitization events occurred under similar conditions from fluids exhibiting characteristics of basinal brines. The{delta} 34S values of sulfides are between -1.8 and .5 per mil, which is consistent with thermochemical sulfate reduction involving organic matter as the main source of reduced sulfur. Galena lead isotope compositions are among the most radiogenic values reported for Zn-Pb occurrences in Europe, and they are distinct from values reported for galena from other Basque-Cantabrian deposits. This suggests that a significant part of the lead was scavenged from the local underlying Asturian sediments. The stratigraphic and structural setting, timing of epigenetic mineralization, mineralogy, and isotopic geochemistry of sulfide and gangue minerals of the Reocin deposit are consistent with the features of most of Mississippi Valley-type ore deposits

'Canons' revisited and reviewed: Lester King's views of landscape evolution considered 50 years later, 2003, Twidale C. R. ,
Fifty years after its publication, Lester King's Canons of Landscape Evolution is reviewed and is considered in light of subsequent trends and actual developments. Some of his ideas, such as the role of scarp recession and the antiquity of some surfaces, remain current. His broad view of the world and his interest in major relief anticipated trends that are now fashionable. Some of his interpretations, however, and in particular his downgrading of the importance of structural factors and his linking of scarp retreat and pedimentation, have not stood the test of time. Other concepts, such as the etch or two-stage origin of forms, which were mooted but not fully appreciated in King's day, have come to the forefront, and technological advances in dating and survey, particularly of the ocean floors, have signaled new perspectives in landscape interpretation. Nevertheless, King's was a courageous attempt to provide guidelines for landscape study

Chalk engineering geology - Channel Tunnel Rail Link and North Downs Tunnel, 2003, Warren C. D. , Mortimore R. N. ,
Agreat part of the Channel Tunnel Rail Link (CTRL) is constructed through the Chalk and the ground investigation for the CTRL has yielded a mass of new information on allaspects of the Chalk. A precise bed by bed lithostratigraphy obtained from cored boreholes has aided engineering description, classification, decision making on design of machines and construction methods/specifications. Correlation of Chalk marker beds between boreholes drilled for the tunnels beneath London illustrated the influence of sub-Tertiary erosion and of faulting onpreservation of different stratigraphic levels in the Chalk. These different stratigraphic levels affect materials through which the tunnels will be constructed andconsequently tunnel vertical alignment or choice of construction method. The marker bed stratigraphy in the Thames Tunnel boreholes has enabled the same stratigraphic levels to be identified in local quarries and detailed analyses to be carried out for the design of Tunnel Boring Machines. Using individual marker beds, a detailed ground profile was constructed for the North Downs Tunnel which allowed fault zones to be predicted accurately and the different rock mass character of the Chalk formations to be delimited for numerical modelling, design zones and construction monitoring. The project also provided the opportunity to evaluate the CIRIA Chalk Grading scheme

Sequence Biostratigraphy of Prograding Clinoforms, Northern Carnarvon Basin, Western Australia: A Proxy for Variations in Oligocene to Pliocene Global Sea Level?, 2004, Moss Graham D. , Cathro Donna L. , Austin James A. Jr. ,
Sequence biostratigraphic analyses from five industry wells in the Northern Carnarvon Basin (NCB), Western Australia, are tied to seismic stratigraphic interpretations from a set of 3D and 2D seismic data. Distribution patterns of [~]286 benthic and 73 planktonic foraminiferal taxa in sidewall cores and ditch cuttings from Eocene to Pliocene intervals are documented and supplemented with observations of other fossil groups (e.g., fragments of ostracodes, bryozoans, corals, and mollusks) and lithological components such as calcite cement and quartz sand. Preservation of foraminiferal assemblages is extremely variable in latest Eocene to Pliocene stratigraphy, depending upon the location of wells and the interval investigated. Nonetheless, consistent, detectable faunal signals correlate between wells and with prominent seismic horizons and sequences. The late Oligocene to middle Miocene is characterized by deeper-water benthic assemblages dominated by infaunal taxa and a high planktonic abundance. Stratigraphic events in the middle Miocene, including turnover in benthic foraminifera, are interpreted to record a regional flooding event (equivalent to cycle Tejas B (TB) 2.3) at the beginning of the mid-Miocene climatic optimum ([~]16-14.5 Ma). Following this event, seismically defined geomorphic features include karstification on the shelf and incision on the clinoform front. All wells show a major transition to shallow-water, warm conditions on the shelf in the middle and late Miocene, with benthic assemblages dominated by larger foraminifera. This transition appears higher in more-basinward wells and appears to be a result of progradation. Geomorphic features in the late middle Miocene ([~]12 Ma) identified from 3D seismic analyses show an intensification of earlier gully formation, resulting in the development of submarine canyons. Detailed analyses of faunal patterns also provide evidence of higher-frequency sea-level fluctuations (0.5-3 Ma), not detected in the seismic stratigraphic patterns

Solution-collapse breccias of the Minkinqellet and Wordiekammen Formations, Central Spitsbergen, Svalbard: a large gypsum palaeokarst system, 2005, Eliassen A, Talbot Mr,
Large volumes of carbonate breccia occur in the late syn-rift and early post-rift deposits of the Billefjorden Trough, Central Spitsbergen. Breccias are developed throughout the Moscovian Minkinfjellet Formation and in basal parts of the Kazimovian Wordiekammen Formation. Breccias can be divided into two categories: (i) thick, cross-cutting breccia-bodies up to 200 m. thick that are associated with breccia pipes and large V-structures, and (ii) horizontal stratabound breccia beds interbedded with undeformed carbonate and siliciclastic rocks. The thick breccias occur in the central part of the basin, whereas the stratabound breccia beds have a much wider areal extent towards the basin margins. The breccias were formed by gravitational collapse into cavities formed by dissolution of gypsum and anhydrite beds in the Minkinfjellet Formation. Several dissolution fronts have been discovered, demonstrating the genetic relationship between dissolution of gypsum and brecciation. Textures and structures typical of collapse breccias such as inverse grading, a sharp flat base, breccia pipes (collapse dolines) and V-structures (cave roof collapse) are also observed. The breccias are cemented by calcite cements of pre-compaction, shallow burial origin. Primary fluid inclusions in the calcite are dominantly single phase containing fresh water (final melting points are ca 0 degrees C), suggesting that breccia diagenesis occurred in meteoric waters. Cathodoluminescence (CL) zoning of the cements shows a consistent pattern of three cement stages, but the abundance of each stage varies stratigraphically and laterally. delta(18)O values of breccia cements are more negative relative to marine limestones and meteoric cements developed in unbrecciated Minkinfjellet limestones. There is a clear relationship between delta(18)O values and the abundance of the different cement generations detected by CL. Paragenetically, later cements have lower delta(18)O values recording increased temperatures during their precipitation. Carbon isotope values of the cements are primarily rock-buffered although a weak trend towards more negative values with increasing burial depth is observed. The timing of gypsum dissolution and brecciation was most likely related to major intervals of exposure of the carbonate platform during Gzhelian and/or Asselian/Sakmarian times. These intervals of exposure occurred shortly after deposition of the brecciated units and before deep burial of the sediments

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