KarstBase a bibliography database in karst and cave science.
Featured articles from Cave & Karst Science Journals
Characterization of minothems at Libiola (NW Italy): morphological, mineralogical, and geochemical study, Carbone Cristina; Dinelli Enrico; De Waele Jo
Chemistry and Karst, White, William B.
The karst paradigm: changes, trends and perspectives, Klimchouk, Alexander
Long-term erosion rate measurements in gypsum caves of Sorbas (SE Spain) by the Micro-Erosion Meter method, Sanna, Laura; De Waele, Jo; Calaforra, José Maria; Forti, Paolo
The use of damaged speleothems and in situ fault displacement monitoring to characterise active tectonic structures: an example from Zapadni Cave, Czech Republic , Briestensky, Milos; Stemberk, Josef; Rowberry, Matt D.;
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for hydrochemical behavior (Keyword) returned 3 results for the whole karstbase:
Inverse modeling of mass transfer characterizes the dynamic processes affecting the function of karst systems and can be used to identify karst properties. An inverse model is proposed to calculate unit hydrographs as well as impulse response of fluxes from rainfall-runoff or rainfall-flux data, the purpose of which is hydrograph separation. Contrary to what hydrologists have been doing for years, hydrograph separation is carried out by using transfer functions in their entirety, which enables accurate separation of fluxes, as was explained in the companion paper [Pinault et al., this issue]. The unit hydrograph as well as impulse response of fluxes is decomposed into a quick and a slow component, and, consequently, the effective rainfall is decomposed into two parts, one contributing to the quick flow (or flux) and the other contributing to the slow flow generation. This approach is applied to seven French karstic aquifers located on the Larzac plateau in the Grands Causses area (in the south of France). Both hydrodynamical and hydrogeochemical data have been recorded from these springs over several hydrological cycles. For modeling purposes, karst properties can be represented by the impulse responses of flow and flux of dissolved species. The heterogeneity of aquifers is translated to time-modulated flow and transport at the outlet. Monitoring these fluxes enables the evaluation of slow and quick components in the hydrograph. The quick component refers to the 'flush flow' effect and results from fast infiltration in the karst conduit network when connection is established between the infiltration and phreatic zones, inducing an increase in water head. This component reflects flood events where flow behavior is nonlinear and is described by a very short transfer function, which increases and decreases according to water head. The slow component consists of slow and fast infiltration, underground runoff, storage in annex-to-drain systems, and discharge from the saturated zone. These components can be further subdivided by measuring chemical responses at the karst outlet. Using Such natural tracers enables the slow component of the unit hydrograph to be separated into preevent water, i.e., water of the reservoir and event water, i.e., water whose origin can be related to a particular rainfall event. These measurements can be used to determine the rate of water renewal. Since the preevent water hydrograph is produced by stored water when pushed by a rainfall event and the event water hydrograph reflects rainwater transfer, separating the two components can yield insights into the characteristics of karst aquifers, the modes of infiltration, and the mechanisms involved in karstification, as well as the degree of organization of the aquifer
Linear transfer functions have been extensively used in hydrological studies. Generally, we support this conclusion: rainfall-runoff models based on the convolution between rainfall rates and a nonparametric transfer function (NTF) are not successful at simulating karst spring discharges during long recession periods. The tails of identified transfer functions have irregular shapes and they are not accurate physical representation of the transport through a karst system. Irregularities are the result of unavoidable errors in input and output time series and simplifications made by considering the system as linear and time invariant. This paper deals with a new form of the transfer functions for karst aquifers, the so-called composite transfer function (CTF). The CTF simulates discharges by two transfer functions adapted for the quick flow and the slow flow hydrograph component modeling. NTF is responsible for the quick flow component. The slow flow component is modeled by a parametric transfer function that is an instantaneous unit hydrograph mathematically formulated and defined from a conceptual model. By using the CTF, the irregular shape of the tail of the identified transfer function can be avoided, and the simulation of long recession periods as well as the simulation of a complete hydrograph becomes more successful. The NTF, the Nash model, the Zoch model and other similar conceptual models can be considered separately as simplified forms of the CTF. The rainfall-runoff model based on the convolution between rainfall rates and the CTF was tested on the Jadro Spring in Croatia. The results of the application are compared with the results obtained by applying NTFs independently. (C) 2003 Elsevier Science B.V. All rights reserved
[1] A methodological approach using inverse modeling was used to characterize the functioning of the deep and shallow reservoirs of the Thau karst aquifer system. Three springs were monitored at the convergence of rising saline water diluted with shallow groundwater in karst conduits and unmixed shallow groundwater that behaves as confined groundwater. In such a method, impulse responses of flow and fluxes are combined in order to separate hydrographs. The model explains the salinity and hydraulic head variations of the submarine and inland springs. It confirms and improves the conceptual model of this groundwater system in which mixing of saline and subsurface waters occurs. The different forces driving the upward flowing mixed water into the drainage axis and faults were studied in order to elucidate the springs' functioning. A comparative study of spring functioning is proposed, which clearly shows the very high sensitivity of the groundwater system to changes in recharge and discharge conditions
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