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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That outlet cave is a cave developed at the point of re-emergence of an underground karst watercourse [19].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for seasonal-variation (Keyword) returned 18 results for the whole karstbase:
Showing 1 to 15 of 18
COMPARISON OF THE C-14 ACTIVITY OF GROUNDWATER AND RECENT TUFA FROM KARST AREAS IN YUGOSLAVIA AND CZECHOSLOVAKIA, 1989, Horvatincic N. , Srdoc D. , Silar J. , Tvrdikova H. ,
C-14 activity of dissolved inorganic carbon (DIC) in water and in recent tufa samples in several karst areas of Yugoslavia and Czechoslovakia was measured. Groundwater from 11 karst springs were measured for their isotopic content (C-14, H-3, C-13), chemical composition (HCO3, Ca2, Mg2) and physico-chemical properties (temperature, pH). Seasonal variations of the C-14 activity of DIC in two karst springs in Plitvice Lakes area, Yugoslavia, were measured systematically from 1979-1987. C-14 activity of recent tufa samples from several locations downstream were also measured. The activity of DIC in karst spring water in both countries ranged from 63-87 pMC, which is attributed to differences in geologic structure of the recharge area, topsoil thickness and composition. Grouping of C-14 activities of DIC ca (824)% is evident. Tritium activity at all the springs indicated short mean residence time (1-10 yr). Concentration of HCO3, Ca2 and Mg2 in spring water varied with geomorphology. C-14 activity of streamwater and recent tufa increased downstream from karst springs due to the exchange between atmospheric CO2 and DIC

MINERALOGICAL AND SEDIMENTOLOGICAL INVESTIGATIONS OF A KARST FILLING IN THE COTENCHER CAVE (NEUCHATEL, JURA MOUNTAINS, SWITZERLAND), 1991, Adatte T, Rentzel P, Kubler B,
Mineralogical and sedimentological investigations were carried out on a karst filling located in the Cotencher cave (Neuchatel, Jura mountains, Switzerland). Radiometric and archeological dating give evidence for a rather incomplete record of the climatic history of the last glacial period. The major hiatus is situated in the younger Wurmian Pleniglacial age. Following the mineralogical and sedimentological results, it is possible to divide this profile in three parts. Late glacial and holocene sediments are characterized by fine morainic material, redeposited due to karst activity. The middle part (C-14: > 40 Ky BP), directly located below this hiatus shows a typical mineralogical association with the appearance of kaolinite and the persistance of the amphibole. This association is thought to be of eolian origin, older than the one described on the Jura mountains actual soils. This eolian sediment component was deposited after the early Wurmian Pleniglacial period. on the soils in the vicinity of the cave, and resedimented into the cave during the Wurmian Interpleniglacial. The lower part of the sediment column is characterized by a mineralogical association of kaolinite, mixed-layers and mica. Especially high amounts of kaolinite, possibly derived from old, probably Eemian mature soils give evidence for relatively warm climate with strong seasonal variations

GROUNDWATER GEOCHEMISTRY OF THE CARBONATE KARST AQUIFER, SOUTH-CENTRAL KENTUCKY, USA, 1993, Hess J. W. , White W. B. ,
Analyses of 441 water samples from 15 sample sites, mainly springs and sinking creeks in the southcentral Kentucky karst, were used to determine hardness, P(CO2), and state of saturation with respect to calcite and dolomite. Most of the waters are undersaturated with respect to calcite and more undersaturated with respect to dolomite, in agreement with recent kinetic models. Time series data revealed chemical fluctuations on both weekly and seasonal time scales. Much of the short-term variation and some of the seasonal variation in the hardness and saturation index parameters can be accounted for by dilution effects from storm and seasonal runoff. Seasonal cycles in CO2 partial pressure arise from a dependence of soil CO2 on temperature and the growing season. Waters from different locations in the aquifer system are chemically distinct and fit into the concept of a hydrochemical facies

SURFACE OZONE EXPOSURES MEASURED IN FINLAND, 1994, Laurila T. , Lattila H. ,
The occurrence of ozone concentrations and exposure indices related to the adverse effects of ozone upon vegetation are reported for four Finnish background stations. In Finland, ozone concentrations are often near the background tropospheric values of cn. 30 ppb. Very high concentrations are not observed. The maximum 1-h average in this data set was 79 ppb. The exposure parameter, which accumulates growing season 1-h average concentrations above a 40 ppb base-line in daylight hours, gave clearly different exposure sums for the stations. These values varied between 4000 and 8500 ppb-h in the southern archipelago, 3000-6500 ppb-h in the southern coastal region, 2000-4000 ppb-h in central parts of the country, and 400-1000 ppb-h in the northern parts of the country. The date of the start of the vegetative season is important in high northern latitudes, because the spring maximum of ozone concentrations is relatively intense compared to the summer maximum. In northern Scandinavia, ozone exposures are particularly sensitive to the date of the start of the growing season. The long daylight period in northern Scandinavia is less important in this respect, since during the growing season ozone concentrations are usually below 40 ppb during the morning and evening hours. A good correlation was found between growing season average concentrations of the sum of gaseous HNO3 and particulate NO3-, and on ozone exposure index which accumulates concentrations above a 40 ppb base-line, confirming the anthropogenic origin of the elevated ozone exposures

The nutritional status of healthy and declining stands of Banksia integrifolia on the Yanakie Isthmus, Victoria, 1997, Bennett Lt, Attiwill Pm,
Banksia integrifolia L.f. has been in decline an calcareous sands of the Yanakie Isthmus, southern Victoria, since early 1980. Early studies indicated that the decline is associated with a particular soil condition possibly a nutritional imbalance involving Fe. However, in foliage samples collected from the three main soil types of the Isthmus, declining trees had similar concentrations of Fe but lower concentrations of Ca than healthy trees. Comparisons were made of seasonal variation in concentrations of macro- and micro-nutrients in foliage and litterfall from healthy trees (to minimise secondary changes associated with decline) within healthy and declining sites on the same soil type. On average, litterfall and the nutrient content of litterfall was greatest within the canopy area of B. integrifolia of the healthy stand. Banksias of the healthy stand also had greater concentrations of N, P, K and Na in fully-expanded leaves, resorbed greater proportions of phloem-mobile nutrients from senescent leaves and accumulated more Ca in senescent leaves. However, there was no evidence of nutritional imbalance in healthy trees within declining stands. It is argued that the lower foliar Ca in declining trees on three soil types and lower nutritional status of healthy trees within declining stands were due to lower productivity and lower water use and were therefore a result or an indication of decline rather than a cause

Multivariate analysis of chemical-physical parameters to characterize and discriminate karstic waters, 1998, Barbieri P, Adami G, Reisenhofer E,
In the Karst near Trieste two contiguous, apparently similar, springs were sampled during autumnal and spring periods. Twelve chemical-physical parameters were monitored, with the purpose of determining the composition and verifying seasonal variations of the waters. The methodological approach for characterizing and discriminating karstic freshwaters, based on a multivariate analysis of the analytical data, as PCA (Principal Component Analysis) or EDA (Linear Discriminant Analysis), is alternative to intrusive methods based on chemical, radioactive or biological tracers. A discriminant model was proposed for these karstic waters, verifying the significance of the variables

Drip flow variations under a stalactite of the Pere Noel cave (Belgium). Evidence of seasonal variations and air pressure constraints, 1998, Genty D, Deflandre G,
The study of drip rate and seepage water electrical conductivity (hereafter called conductivity) under one stalactite in the Pere Noel cave (Belgium), with data produced from an automatic station since 1991, demonstrates several previously unobserved features: (1) measurement of drop volume shows that, for 94% of the time series, drop volume is constant (= 0.14 ml), but when discharge exceeds 48.2 drips min(-1), drop volume decreases, probably because of secondary drop formation; (2) the interannual drip rate variation is correlated to the annual water excess and its correlant, rainfall (R-2 = 0.98; exponential model); this result introduces a new improvement in the understanding of the previously investigated relationships between stalagmite annual laminae thickness and mean annual rainfall; (3) the drip rate shows a well marked seasonality: it increases abruptly in late fall or early winter and decreases slowly during spring, summer and fall. Increased discharge is accompanied by an increase in conductivity, which suggests that the flushed water is more mineralized and was stored in the karst aquifer for several months; (4) superimposed on these seasonal variations, there are two kinds of flow regimes which are driven by the atmospheric pressure: (i) a 'wiggles regime', whose duration is 1-7 days in length and which is inversely proportional to the air pressure wiggles; it is explained by either a ''shut-off faucet'' process due to the rock formation stress, or to a change in the two-phases flow component proportions (air/water); (ii) an 'unstable regime' characterized by abrupt switches (<2 h) or oscillations with variable periodicities, from a few minutes to a few hours. These occur when the drip rate reaches a threshold (i.e. 240 drops 10 min(-1)); the chaotic behaviour of this phenomenon is discussed. (C) 1998 Elsevier Science B.V. All rights reserved

Searching for a 3-way model of spatial and seasonal variations in the chemical composition of karstic freshwaters, 1999, Barbieri P, Adami G, Reisenhofer E,
A procedure is described for the search of a three,way;principal components model, characterizing a data set concerning the spatial and temporal distribution of the physico-chemical parameters which govern the composition of waters collected from springs, ponds and;rivers of the Karst of Trieste. Ten physico-chemical parameters were determined-for eleven sampling sites and eleven sampling times. A:graphic method was applied in order to find the number of components in each of the three ways of the model, explaining a relatively high quantity of variation of the. data, with a limited number of components, i.e. with descriptive parsimony, and generating interpretable factors. The examination of 125 possible Tucker3 models, having from 1 to 5 components in each of the ways, allowed us to identify the model having two components in each of the three ways as the one satisfying the desired criteria. The chance of reducing to a simpler PARAFAC model has been successfully explored,and two trilinear components were then computed. The first one is mainly related to a spatial factor conditioning the considered waters, while the second is related to a seasonal factor

Fluorescence wavelength and intensity variations of cave waters, 1999, Baker A, Genty D,
The fluorescence properties of groundwaters percolating into four cave systems have been monitored over the period 1997-1998. Fluorescence was excited between 220 and 400 nm and the emission measured from 300 to 500 nm using a fluorescence spectrophotometer. Three fluorescence centres were observed; one at the excitation-emission pair of 290-340:395-430 nm, (humic-like, probably fulvic acid), one at 265-280:300-370 nm (protein like) and a less defined region of high fluorescence at 230-280:310-420 nm (humic and/or protein like). The most consistent fluorescence intensity was observed in the excitation-emission pair of 290-340:395-430 nm, attributed to a fulvic acid source. Subtle differences (5%) in the fluorescence excitation and emission wavelength of this fluorescence peak in the groundwater were observed between the four sites, and the fluorescence intensity varied considerably ( x 60) between the four sites. Both the wavelength and the intensity variations in fluorescence are caused by the differences in the vegetation cover, soil type and humification. Data from the most intensely monitored site (Brown’s Folly Mine, England; 9 sample stations, 10-20 days frequency sampling) revealed no spatial variability in the 290-340:395-430 nm (fulvic acid) fluorescence; in contrast time-series analysis suggests that the seasonal variations do occur, with a decrease in the emission wavelength correlating with the first (autumn) peak in fluorescence intensity, and a decrease in the excitation wavelength correlating with a second (winter) fluorescence intensity peak. Results demonstrate the potential of utilising fluorescence wavelength variations in sourcing karst groundwaters, and as a possible palaeoenvironmental proxy of the overlying soil conditions if trapped within the cave speleothems

Seasonal variations in Sr, Mg and P in modern speleothems (Grotta di Ernesto, Italy), 2001, Huang Yiming, Fairchild Ian J. , Borsato Andrea, Frisia Silvia, Cassidy Nigel J. , Mcdermott Frank, Hawkesworth Chris J. ,
Sub-annual variations in trace element chemistry and luminescence have recently been demonstrated from speleothems and offer the potential of high-resolution palaeoclimatic proxies. However, no studies have yet examined microscopic trace element variations in relation to modern cave conditions. In this study, the spatial variations in trace element (Sr, Mg and P) concentrations in speleothems (a stalagmite and a soda straw stalactite) from the alpine Ernesto cave (temperature 6.60.1[deg]C) in a forested catchment in NE Italy have been studied using secondary ion mass spectrometry (SIMS) and compared with environmental parameters and waters in the modern cave. An annual lamination exists in the stalagmite and soda straw stalactite in the form of clear calcite with narrow visible layers, which are UV-fluorescent and interpreted to contain soil-derived humic/fulvic acids washed into the cave during autumn rains. Microanalyses were undertaken of seven annual laminae, probably deposited during the 1960s in the stalagmite, and seven laminae in the 1990s for the stalactite.The analysis results show that Sr consistently has a trough and P, a peak centred on the inclusion-rich layer. Mg shows mainly a negative covariation with Sr in laminae formed in the 1990s, but a positive covariation in the stalagmite formed in 1960s. The spatial scale of the main geochemical variations is the same as that of annual laminae of inclusion-poor and inclusion-rich couplets. Mass balance arguments are used to show that the P is inorganic in form and presumably occurs as individual phosphate ions within the calcite.Most drip waters show limited chemical variations, but a summer peak in trace elements in 1995 and a decrease in Mg/Ca in the following winter are notable. More pronounced covariations in Mg/Ca and Sr/Ca are shown by a site with highly variable drip rates where ratios increase at slow drip rates. The strongest seasonal variations are found in pool waters, where ratios increase reflecting significant Ca removal from the water into the calcite during the winter in response to seasonal PCO2 variations in cave air. Thus, the cave waters' compositions tend to reflect climate conditions, such that Mg/Ca and Sr/Ca are tentatively interpreted to be higher when climate conditions are dry.Combining results from the speleothems and cave water along with the behaviour of each trace species, Mg/Ca variations in the speleothems are considered to reflect their variation in the cave waters, whereas, Sr incorporation is also dependent on precipitation rate, in this case, mainly controlled by temporal variations in PCO2 in the cave (and conceivably, also by inhibitors such as phosphate). P adsorption (a fraction of which is subsequently incorporated within calcite) depends on aqueous phosphate concentration and water flux, both of which should increase during the autumn. Therefore, multiple trace element profiles in speleothems reflect multiple aspects of environment seasonality and conditions, and hence, a calibration against weather records is desirable to establish their palaeoclimatological meaning. The strong annual variation of trace elements, and particularly P, can provide chronological markers for high-resolution studies of other climate proxies, such as stable isotopes

Forecasting of turbid floods in a coastal, chalk karstic drain using an artificial neural network, 2001, Beaudeau P, Leboulanger T, Lacroix M, Hanneton S, Wang Hq,
Water collected at the Yport (eastern Normandy, France) Drinking Water Supply well, situated on a karst cavity, is affected by surface runoff-related turbidity spikes that occur mainly in winter, In order to forecast turbidity, precipitation was measured at the center of the catchment basin over two years, while water level and turbidity were monitored at the web site. Application of the approach of Box and Jenkins (1976) leads to a linear model that can accurately predict major floods about eight hours in advance, providing an estimate of turbidity variation on the basis of precipitation and mater level variation over the previous 24 hours. However, this model is intrinsically unable to deal with (1) nonstationary changes in the time process caused by seasonal variations of in ground surface characteristics or tidal influence within the downstream past of the aquifer, and (2) nonlinear phenomena such as the threshold for the onset of runoff. This results in many false-positive signals of turbidity in summer. Here we present an alternative composite model combining a conceptual runoff submodel with a feedforward artificial neural network (ANN), This composite model allows us to deal with meaningful variables, the actioneffect of which on turbidity is complex, nonlinear, temporally variable and often poorly described. Predictions are markedly improved, i.e,, the variance of the target variable explained by 12-hour forward predictions increases from 28% to 74% and summer inaccuracies are considerably lowered. The ANN can adjust itself to new hydrological conditions, provided that on-line learning is maintained

Annual resolution analysis of a SW-France stalagmite by X-ray synchrotron microprobe analysis, 2003, Kuczumow A. , Genty D. , Chevallier P. , Nowak J. , Ro C. U. ,
A sample of stalagmite from Grotte de Villars, Dordogne, France was analyzed by the use of X-ray synchrotron microprobe in LURE, Orsay, France. Together with the signal of Ca, the main element, much weaker but clear signals of Sr, Fe, Zn and Pb were registered. The X-ray scattered radiation was applied for recognition of the annual zones in the stalagmite structure in parallel with the gray scale morphology from the optical microscope. The elemental scans were superimposed on the optical image of the sample. It was established that places corresponding to dark locations on the annual rings were narrower, composed of less porous matter and had much greater contents of iron and zinc and elevated ratio of Sr/Ca. In the supplementary electron microprobe measurements, the elevated amounts of lighter elements, Si and Mg were found in the same locations. These results will allow a very accurate study of stalagmite elemental composition which is of first importance for paleoclimatic studies from speleothems. (C) 2003 Elsevier Science B.V. All rights reserved

Study of soil leachates in doline above the Beke Cave, Hungary, 2004, Tatar E. , Mihucz V. G. , Tompa K. , Poppl L. , Zaray G. , Zambo L. ,
Fulvic acid, Ca and Mg concentrations as well as dissolved inorganic carbon (DIC), pH and electric conductivity values of soil solutions which resulted from injecting bidistilled water onto glass columns filled with different soils (black rendzina, brown rendzina, red clayey rendzina, red clay) characteristic of the Aggtelek karst system (NE Hungary), were determined. Identification and determination of fulvic acid were achieved by size exclusion chromatography (SEC) and adsorption chromatography, respectively, with fluorescent spectrometric detection. The Ca and Mg concentration of the samples was determined by applying an inductively coupled plasma atomic emission spectrometric (ICP-AES) method. DIC-expressed in CO2 concentration values-was determined by using a CO2 selective electrode. According to the SEC analysis, the apparent molecular weight of the fulvic acids of the samples were between 500 and 1600 Da. The fulvic acid concentration values of the percolated water samples decreased in function of the soils investigated as follows: black rendzina>brown rendzina>red clayey rendzina>red clay, which is in concordance with the organic matter content of these types of soils. The results obtained for fulvic acid, Ca and Mg concentrations as well as for DIC, pH and electric conductivity of the water samples collected from the column filled with red clay were in good agreement with those of a seepage water sample collected from an observation station built in red clay above the Beke Cave (Aggtelek). Since the artificially prepared red clay column was exposed to the same temperature and humidity conditions like red clay of the sampling site, this method seems to be suitable for modelling infiltration of fulvic acid and metals from red clay into seepage water under laboratory conditions. (C) 2003 Elsevier B.V. All rights reserved

Analytical and numerical models to explain steady rates of spring flow, 2004, Swanson S. K. , Bahr J. M. ,
Flow from some springs in former glacial lakebeds of the Upper Midwest is extremely steady throughout the year and does not increase significantly after precipitation events or seasonal recharge. Analytical and simplified numerical models of spring systems were used to determine whether preferential ground water flow through high-permeability features in shallow sandstone aquifers could produce typical values of spring discharge and the unusually steady rates of spring flow. The analytical model is based on a one-dimensional solution for periodic ground water flow. Solutions to this model suggest that it is unlikely that a periodic forcing due to seasonal variations in areal recharge would propagate to springs in a setting where high-permeability features exist. The analytical model shows that the effective length of the aquifer, or the length of flowpaths to a spring, and the total transmissivity of the aquifer have the greatest potential to impact the nature of spring flow in this setting. The numerical models show that high-permeability features can influence the magnitude of spring flow and the results demonstrate that the lengths of ground water flowpaths increase when high-permeability features are explicitly modeled, thus decreasing the likelihood for temporal variations in spring flow

Utilising seasonal variations in hydrogeochemistry and excitation-emission fluorescence to develop a conceptual groundwater flow model with implications for subsidence hazards: an example from Co. Dur, 2005, Lamontblack J. , Baker A. , Younger P. L. , Cooper A. H. ,

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