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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for theoretical predictions (Keyword) returned 4 results for the whole karstbase:

Recent flowstone growth rates: field measurements and comparison to theoretical results, 1995, Baker A. , Smart Pl. ,
The model of calcite precipitation kinetics of D. Buhmann and W. Dreybrodt, based on the rate laws of L.N. Plummer et al., is used to predict cave flowstone growth rates. These theoretically modelled growth rates are compared to actual growth rates of recent samples found in cave and mine sites in southwest England. A good agreement is found between modelled and actual growth rates within the 95% confidence level of the determinations, although in general modelled growth rates overestimate actual growth rate by between 2.4 and 4.7 times. Several reasons for this overestimation are discussed, including uncertainties arising from the experimental data of L.N. Plummer et al., seasonal shut-off of water flow onto the flowstones and significant variations in the growth rate determining parameters during the period of flowstone growth. For one flowstone an underestimation of growth rate is observed and is explained by the presence of rimstone pools which pond water on the sample surface

The kinetics of the reaction CO2?>H? as one of the rate limiting steps for the dissolution of calcite in the system H2O-CO2-CaCO3, 1996, Dreybrodt W, Lauckner J, Liu Zh, Svensson U, Buhmann D,
Dissolution of CaCO3 in the system H2O-CO2-CaCO3 is controlled by three rate-determining processes: The kinetics of dissolution at the mineral surface, mass transport by diffusion, and the slow kinetics of the reaction H2O CO2 = H HCO3-. A theoretical model of Buhmann and Dreybrodt (1985a,b) predicts that the dissolution rates depend critically on the ratio V/A of the volume V of the solution and the surface area A of the reacting mineral. Experimental data verifying these predictions for stagnant solutions have been already obtained in the range 0.01 cm < V/A < 0.1 cm. We have performed measurements of dissolution rates in a porous medium of sized CaCO3 particles for V/A in the range of 2 . 10(-4) cm and 0.01 cm in a system closed with respect to CO2 using solutions pre-equilibrated with an initial partial pressure of CO2 of 1 . 10(-2) and 5 . 10(-2) atm. The results are in satisfactory agreement with the theoretical predictions and show that especially for V/A < 10(-3) cm dissolution is controlled entirely by conversion of CO2 into H and HCO3-, whereas in the range from 10(-3) cm up to 10(-1) cm both CO2-conversion and molecular diffusion are the rate controlling processes. This is corroborated by performing dissolution experiments using 0.6 mu molar solutions of carbonic anhydrase, an enzyme enhancing the CO2-conversion rates by several orders of magnitude. In these experiments CO2 conversion is no longer rate limiting and consequently the dissolution rates of CaCO3 increase significantly. We have also performed batch experiments at various initial pressures of CO2 by stirring sized calcite particles in a solution with V/A = 0.6 cm and V/A = 0.038 cm. These data also clearly show the influence of CO2-conversion on the dissolution rates. In all experiments inhibition of dissolution occurs close to equilibrium. Therefore, the theoretical predictions are valid for concentrations c less than or equal to 0.9 c(eq). Summarising we find good agreement between experimental and theoretically predicted dissolution rates. Therefore, the theoretical model can be used with confidence to find reliable dissolution rates from the chemical composition of a solution for a wide field of geological applications

Precipitation kinetics of calcite in the system CaCO3-H2O-CO2: The conversion to CO2 by the slow process H?->CO2? as a rate limiting step, 1997, Dreybrodt W, Eisenlohr L, Madry B, Ringer S,
Precipitation rates of CaCO3 from supersaturated solutions in the H2O - CO2 - CaCO3 system are controlled by three rate-determining processes: the kinetics of precipitation at the mineral surface, mass transport of the reaction species involved to and from the mineral surface, and the slow kinetics of the overall reaction HCO3- H --> CO2 H2O. A theoretical model by Buhmann and Dreybrodt (1985a,b) taking these processes into account predicts that, due to the slow kinetics of this reaction, precipitation rates to the surface of CaCO3 minerals depend critically on the ratio V/A of the volume V of the solution to the surface area A of the mineral in contact with it, for both laminar and turbulent flow. We have performed measurements of precipitation rates in a porous medium of sized particles of marble, limestone, and synthetic calcite, with V/A ratios ranging from 3.10(-4) to 1.2-10(-2) cm at 10 degrees C. Calcite was precipitated from supersaturated solutions with [Ca2] approximate to 4 mmol/L and an initial P-CO2 of 5.10(-3) or 1.10(-3) atm, respectively, using experimental conditions which prevented exchange of CO2 with the atmosphere, i.e., closed system. The results are in qualitative agreement with the theoretical predictions. Agreement with the observed data, however, is obtained by modifying the rate law of Plummer et al. (1978) to take into account surface-controlled inhibition effects. Experiments with supersaturated solutions containing carbonic anhydrase, an enzyme which enhances the conversion of HCO3- into CO2, yield rates increased by a factor of up to 15. This provides for the first time unambiguous experimental evidence that this reaction is rate limiting. We have also measured precipitation rates in batch experiments, stirring sized mineral particles in a solution with V/A ranging from 0.03 to 0.75 cm. These experiments also give clear evidence on the importance of the conversion of HCO3- into CO2 as rate limiting step. Taken together our experiments provide evidence that the theoretical model of Buhmann and Dreybrodt (1985a,b) can be used to predict reliable rates from the composition of CaHCO3- solutions with low ionic strength in many geologically relevant situations. Copyright (C) 1997 Elsevier Science Ltd

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