Groundwater quality was monitored in four Spanish caves using concentrations of nitrate, potassium, phosphorus and in some cases total organic carbon. Three of the caves are located in NW Spain and contain prehistoric cave paintings and hence have special conservation interest. Of these, two are open show caves (Tito Bustillo and Pindal Caves), while the other one (Herrerías Cave) is not managed for tours and is partially closed off to public access. The fourth cave (Las Maravillas Cave) is located in SW Spain and is opened to the public because of its geological features and natural beauty. In this paper, we compare two sampling methodologies used in the four caves. In Pindal and Herrerias Cave high temporal resolution is achieved with a dripwater collector that collects discrete samples every 48 hours. In Tito Bustillo and Las Maravillas Caves a higher spatial resolution is achieved (16 sampling points in each one), but with a frequency of sampling ranging from 15 days to 6 months. Wastewater and livestock waste appear to be the principal sources of contamination to cave waters. Caves with concentrated livestock (stables) or urban and residential wastewater systems directly situated above the cave exhibit the highest level of contamination detected in elevated concentrations of nitrogen species and in some cases depressed oxygen availability in waters.

Groundwater in karstic aquifers can be dangerously sensitive to contamination. In this paper, DRASTIC assessment was modified and applied, for the first time, to address the intrinsic vulnerability for karst aquifers. The theoretical weights of two of DRASTIC’s parameters (aquifer media and hydraulic conductivity) were modified through sensitivity analysis. Two tests of sensitivity analyses were carried out: the map removal and the single parameter sensitivity analyses. The modified assessment was applied for the karst aquifers underlying Ramallah District (Palestine) as a case study. The aquifer vulnerability map indicated that the case study area is under low, moderate and high vulnerability of groundwater to contamination. The vulnerability index can assist in the implementation of groundwater management strategies to prevent degradation of groundwater quality. The modified DRASTIC assessment has proven to be effective because it is relatively straightforward, use data that are commonly available or estimated and produces an end product that is easily interpreted.

The paper examines representative definitions of karst (21), and discusses some concepts that influenced the modern un­derstanding of the phenomenon. Several trends are discussed that took karst science beyond the limits of the traditional par­adigm of karst. Dramatic progress in studies of speleogenesis plays the most significant role in changes taking place in the general understanding of karst. Also important is an adoption of the broad perspective to karst evolution which goes beyond the contemporary geomorphologic epoch and encompasses the entire life of a geological formation. Speleogenesis is viewed as a dynamic hydrogeological process of self-organization of the permeability structure in soluble rocks, a mechanism of the specific evolution of the groundwater flow system. The result is that these systems acquire a new, "karstic", quality and more complex organization. Since almost all essential attributes of karst owe their origin to speleogenesis, the latter is considered as the primary mechanism of the formation of karst. Two fundamental types of speleogenesis, hypogene and epigene, differentiate mainly due to distinct hydrodynamic characteristics of the respective groundwater flow systems: (1) of layered aquifer systems and fracture-vein flow systems of varying depths and degrees of confinement, and (2) of hydrodynamically open, near-surface unconfined systems. Accordingly, two major genetic types of karst are distinguished: hypogene and epigene. They differ in many characteristics, notably in relationships with the surface, hydrogeological behaviour, groundwater quality, and the areas of practical importance and approaches to solving karst-related issues. Although views on essential attributes of karst have been clearly changing, this was not reflected in definitions of the notion which are in broad use in the earth-science literature. A refined approach is suggested to the notion of karst in which it is viewed as a groundwater (fluid) flow system of a specific kind, which has acquired its peculiar properties in the course of speleogenesis.