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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That pyrite is iron sulfide mineral (fes2) also known as iron pyrites and fool's gold. pyrite occurs in trace amounts in many sedimentary rocks. it may be locally common in dark carbonaceous limestone and in thin non-carbonate beds such as shales, coals and wayboards. pyrite may break down spontaneously, with or without bacterial mediation, to form sulfates, particularly sulphuric acid, that may be involved in early speleogensis [9].?

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for isotopic (Keyword) returned 276 results for the whole karstbase:
Showing 16 to 30 of 276
Apports des datations U/Th dans la karstogense de la Grande Moucherolle-Rochers de la Balme (Vercors), 1986, Delannoy J. J. , Holliger Ph.
234 U - 230 Th DATING OF SPELEOTHEMS AND KARSTOGENESIS OF THE "GRANDE MOUCHEROLLE-ROCHERS DE LA BALME" (VERCORS) - In this article, is presented a first geomorphological and speleological synthesis of the subalpine karst of the Grande Moucherolle (2285 m) - Rochers de Ia Balme. This area of Vercors (Alps), which has 8 caves deeper than 300m (Antre des Damns -720m; Clos de La Fure -580m...) is surely the most promising sector from a speleological point of view. Through the study of the glacio-karstic landforms and the distri-bution of the great caves, it seems that there is a real relation between these two parameters. In order to evaluate the contribution of quaternary glaciations in the genesis of caves, isotopic dating (234U-230Th) have been performed on underground carbonated deposits. After a presentation of the chronometric method 234U-230Th, the results are analysed according to their speleological environment. A paleogeographic reconstitution through the middle and recent Quaternary is proposed for the geosystem of the Grande Moucherolle - Rochers de la Balme.

A Stable Isotopic Investigation of Waters and Speleothems in Wind Cave, South Dakota: An Application of Isotope Paleothermometry, 1987, Millen Timothy M, Dickey Jr. D. Neil

Effect of climate changes on the precipitation patterns and isotopic composition of water in a climate transition zone: case of the eastern Mediterranean Sea area, 1987, Gat J. R. , Carmi I.

Strontium isotopic geochemistry of mississippi valley-type deposits, East Tennessee; implications for age and source of mineralizing brines, 1988, Kesler Stephen E. , Jones Lois M. , Ruiz Joaquin,

Isotopic constraints on the genesis of base-metal ores in southern and central Sardinia, 1989, Ludwig K. R. , Vollmer R. , Turi B. , Simmons K. R. , Perna G. ,

C-14 activity of dissolved inorganic carbon (DIC) in water and in recent tufa samples in several karst areas of Yugoslavia and Czechoslovakia was measured. Groundwater from 11 karst springs were measured for their isotopic content (C-14, H-3, C-13), chemical composition (HCO3, Ca2, Mg2) and physico-chemical properties (temperature, pH). Seasonal variations of the C-14 activity of DIC in two karst springs in Plitvice Lakes area, Yugoslavia, were measured systematically from 1979-1987. C-14 activity of recent tufa samples from several locations downstream were also measured. The activity of DIC in karst spring water in both countries ranged from 63-87 pMC, which is attributed to differences in geologic structure of the recharge area, topsoil thickness and composition. Grouping of C-14 activities of DIC ca (824)% is evident. Tritium activity at all the springs indicated short mean residence time (1-10 yr). Concentration of HCO3, Ca2 and Mg2 in spring water varied with geomorphology. C-14 activity of streamwater and recent tufa increased downstream from karst springs due to the exchange between atmospheric CO2 and DIC

Sr isotope study of vein and cave calcites from southern Israel, 1990, Avigour A, Magaritz M, Issar A, Dodson Mh,
The strontium isotope compositions of secondary calcites from the Negev, southern Israel, were compared to those of the marine carbonate host rocks, which range in age from Triassic to Eocene, in order to understand fluid source and migration through fracture systems in dominantly carbonate strata. The Sr isotopes of these calcite clusters are divided into two groups: (1) calcites with 87Sr/86Sr values greater than those of the host carbonates; and (2) calcites with 87Sr/86Sr values close to the values of the host carbonate. 1. (1) These secondary calcites were found on the main tectonic lines of the Negev (faults and fold axes) and are enriched in 87Sr (87Sr/86Sr = 0.707709-0.709151) relative to the marine carbonate country rocks (87Sr/86Sr = 0.707251-0.70755, with one exception). These calcites are associated or crossed by thin veins filled by Fe- and Mn-oxides.2. (2) Secondary calcites with 87Sr/86Sr values close to those of the marine carbonate country rocks (0.7073-0.7077) are found in karstic caves and veins, and are located in sites which are not on the major faults and fold axes. These calcites are not crossed by Fe- and Mn-oxides.The isotopic results indicate that the solutions from which the secondary minerals of the first group precipitated were not in isotopic equilibrium with the marine host rocks. The possible source of the precipitating solutions can be either surface rain descending through the fault system or ascending groundwaters from the deep Nubian aquifer (Paleozoic to Early Cretaceous in age). In both cases there would be a limited interaction with the host sandstone rock which usually is depleted in Sr. The similarity of the 87Sr/86Sr values to those of the host rocks in the second group suggests that the main source of Sr in these calcite crystals was from the dissolution of the marine carbonate country rocks by rain- and flood waters

The stable isotopic ratios of drip water, pool water and water vapor collected in remote areas of Carlsbad Cavern, New Mexico, were used to develop a conceptual model of the hydrologic conditions of the cave pools. When considered in terms of open and closed pool systems, the data indicate that the pools in Carlsbad Cavern appear to leak more water than they evaporate. The pools in Carlsbad Cavern range between -43 and -31% in delta-D, -7.4 and -5.9% in delta-O-18, and have EC-values of 365-710 mu-S cm(-1). The water vapor is consistently 80-82% more depleted in D than associated pool water and appears to be under direct isotopic control by the pools. Most of the drip water ranges between -51 and -44% in delta-D, between -8.0 and -6.9% in delta-O-18, and have EC-values of 310-350 mu-S cm(-1), regardless of location of collection in the cave. Drip water collected on popcorn formations (which in this case are formed by evaporation of wall seep) have stable isotopic compositions similar to local pool water; however, they have EC-value of up to 1060 mu-S cm(-1). In addition, a small, closed pool near the Lake of the Clouds has stable isotopic compositions similar to those of the Lake and elevated EC-values of up to 9500 mu-S cm(-1). The degree of stable isotopic enrichment that evaporating waters can obtain in the Cavern is limited by exchange with the water vapor which, in turn, appears to be controlled by the pools

Stable isotopic composition of the hydrothermal fluids responsible for the Nanisivik Zn-Pb deposits, Northwest Territories, Canada, 1991, Ghazban F. , Schwarcz H. P. , Ford D. C.

Petrography of the Lower Ordovician Ellenburger Group, both in deeply-buried subsurface cores and in outcrops which have never been deeply buried, documents five generations of dolomite, three generations of microquartz chert, and one generation of megaquartz. Regional periods of karstification serve to subdivide the dolomite into 'early-stage', which predates pre-Middle Ordovician karstification, and 'late-stage', which postdates pre-Middle Ordovician karstification and predates pre-Permian karstification. Approximately 10% of the dolomite in the Ellenburger Group is 'late-stage'. The earliest generation of late-stage dolomite, Dolomite-L1, is interpreted as a precursor to regional Dolomite-L2. L1 has been replaced by L2 and has similar trace element, O, C, and Sr isotopic signatures, and similar cathodoluminescence and backscattered electron images. It is possible to differentiate L1 from L2 only where cross-cutting relationships with chert are observed. Replacement Dolomite-L2 is associated with the grainstone, subarkose, and mixed carbonate-siliciclastic facies, and with karst breccias. The distribution of L2 is related to porosity and permeability which focused the flow of reactive fluids within the Ellenburger. Fluid inclusion data from megaquartz, interpreted to be cogenetic with Dolomite-L2, yield a mean temperature of homogenization of 85 6-degrees-C. On the basis of temperature/delta-O-18-water plots, temperatures of dolomitization ranged from approximately 60 to 110-degrees-C. Given estimates of maximum burial of the Ellenburger Group, these temperatures cannot be due to burial alone and are interpreted to be the result of migration of hot fluids into the area. A contour map of delta-O-18 from replacement Dolomite-L2 suggests a regional trend consistent with derivation of fluids from the Ouachita Orogenic Belt. The timing and direction of fluid migration associated with the Ouachita Orogeny are consistent with the timing and distribution of late-stage dolomite. Post-dating Dolomite-L2 are two generations of dolomite cement (C1 and C2) that are most abundant in karst breccias and are also associated with fractures, subarkoses and grainstones. Sr-87/Sr-86 data from L2, C1, and C2 suggest rock-buffering relative to Sr within Dolomite-L2 (and a retention of a Lower Ordovician seawater signature), while cements C1 and C2 became increasingly radiogenic. It is hypothesized that reactive fluids were Pennsylvanian pore fluids derived from basinal siliciclastics. The precipitating fluid evolved relative to Sr-87/Sr-86 from an initial Pennsylvanian seawater signature to radiogenic values; this evolution is due to increasing temperature and a concomitant evolution in pore-water geochemistry in the dominantly siliciclastic Pennsylvanian section. A possible source of Mg for late-stage dolomite is interpreted to be from the dissolution of early-stage dolomite by reactive basinal fluids

The C-13 and O-18 contents of cryogenic calcites formed by expulsion during the freezing of bicarbonate groundwaters are examined. Samples from karst caves within the permafrost region of northern Yukon, Canada, have deltaC-13-values as high as 17.0 parts per thousand, representing the most isotopically enriched freshwater carbonates yet reported. To account for such enrichments, calcium bicarbonate solutions were frozen and sublimated under controlled laboratory conditions. The rapid rate of reaction is shown to effectively preclude isotopic equilibration during bicarbonate dehydration, resulting in a kinetic partitioning of C-13 between CO2 and CaCO3. We find a value of 31.2 1.5 parts per thousand for 1000ln13alpha(KIE)(13alpha(KIE) = 1.032), which is considerably greater than the equilibrium fractionation factor (13epsilon(CaCO3-CO2)) of 10.3 parts per thousand at 0-degrees-C. This kinetic isotope effect (KIE) represents the ratio of the absolute reaction rate constants (13k(d)/12k(d)) for the two isotopic species during the dehydration of dissolved bicarbonate. Similar results for deltaO-18-values confirm that the reaction proceeds without isotope exchange. The KIE of O-18 is determined to be 1.006 for this reaction at 0-degrees-C. These data are compared with the KIE which occurs during the reverse reaction: CO2 hydroxylation by reaction with OH- in hyperalkaline waters

Origin of sulphur in minerals and fluids from Latium (Italy); isotopic constraints, 1992, Cavarretta G, Lombardi G,

The karst aquifer of the well-known Fontaine de Vaucluse has been recently studied, results have been got about delimitation of the system and its working. Geological data (lithology and structure) have allowed to delimit an 1115 Km2 intake area including Ventoux-Lure north facing range (1,909-1,826 m) and the Plateau which is prolonging it southwards (Fig. 1 and 2). The average altitude of the whole area, obtained by balancing elevation belt surfaces, is about 870 m. This elevation squares with results of tracing tests (Fig. 3), environmental physical, chemical and isotopic tracings, that allow to value a 850 m average altitude for the intake area (Fig. 4). The moisture balance has been computed from an altitude belts climatic model, using local rain an temperature gradients (Fig. 5 and Table II), because the weather network is not representative. So, rainfalls rise of about 55 mm per 100 m elevation and temperature decreases of about 0.5-degrees-C per 100 m. The consequence of these two antagonist phenomena is the quasi constant value of actual evapotranspiration on each altitude belt. With the Fig. 7 organigram, curves of effective rainfalls and infiltration coefficient versus elevation can be plotted (Fig. 6). This computation shows that 3/4 of the total and the whole of dry season effective rainfalls are provided by the part of the intake area situated above the average altitude: on the lowest belt, effective rainfalls are only 120 mm per year and increase to 1380 mm on the upper section (Fig. 8 and Table 1). The weighted effective rainfalls are about 570 mm per year for the whole intake area. Hydrodynamical and physico-chemical studies show, despite its large size, the weak inertia of the system, so proves its good karstification, that confirms for the whole system the pin-point speleological observations. The discharge of the spring, which average value is 21 m3.s-1 (only 18 for the last ten years), can exceed 100 m3.s-1 and the minimum has never been lower than 3.7 m3.s-1 (Fig. 9). When it rains on the intake area, the increase of the discharge is very sudden in a rainy period : one to four days. This short delay is due to seepage through epikarst and unsaturated zone. During dry periods, the spring reaction is deadened, due to storage in the unsaturated zone. The silica content distribution was plotted during several hydrokinematical phases (Fig. 10). It shows: an almost unimodal distribution for the 8 km2 fissured limestone aquifer of Groseau; a multimodal one for the 1115 km2 karst aquifer of Fontaine de Vaucluse. This proves that karstification is more important than size in the response of the system. Weak summer rainfalls do not influence the discharge, nevertheless they influence chemistry of the spring water, and so interrupts the water depletion phasis. Then, the decrease of discharge can continue after the end of the chemical depletion phasis, water which is overflowing after summer rainfalls (in a dry period) is influenced hy the chemistry of seepage water : on the graph of a principal components analysis, done on chemical variables. an hysteresis phenomenon can be seen (Fig. 11). A discriminant analysis (Fig. 12) confirms that these autumn waters, with high ratio seepage tracers, are not reserve waters from the saturated zone. The ratio of reserve water in the total discharge, is preponderant: 3/4 and 2/3 respectively of the yearly runoff volumes for 1981 and 1982 (Fig. 13), but an important part of these reserves can be stored in the unsaturated zone. This storage capacity can be valued by different means: transposing to Vaucluse (1115 km2) the volume measured on another karst system in the Pyrenees (13 km2); it gives about 100 million m2; using setting parameters of Bezes model (1976) on the same aquifer: it gives 113 million m3; using depletion curves, that show, for instance during the 1989 summer and autumn dry period, a 80 million m3 volume. In all cases, we get a value of about one hundred million m3 for the storage capacity of the unsaturated zone. With a 20 m range of fluctuation for the water table and with a 10(-2) specific yield, on a 500 to 1,000 km2 saturated zone, the zone of fluctuation can release about 10 to 20 million m3. Then, the volume of water stored in the whole saturated zone, with a 300 m minimum thickness (depth of the waterlogged pit of the Fontaine), a 500 km2 minimum surface and a 10(-3) specific yield, is about 150 million m3, including 27 million m3 stored in the channels. So, the unsaturated zone represents a significant part of the whole storage capacity and most of the yearly renewable reserves. Paradoxically, the biggest french spring is not tapped at all; as its intake area is neither a regional nor a national park, no general protection covers it : because of its good karstification, the vulnerability of the system is important. Good quality of water is attributable to the low population and human activities density on the intake area (4 A great part of the intake area is uncultivated (large forest and ''garrigues'' areas). Due to the lack of surface water and scantness of soils, agriculture is not intensive (lavender, thyme, sage and bulk wheat fields. meadowlands). On the mountainous zone, roads are salted in winter and snowmelt water can reach a significantly high chloride ratio than in a natural climatic functioning (for instance 25 mg.l-1 in Font d'Angiou where the ratio would have been 3 mg.l-1). As tourism is developing both on the mountain and on the plateau, the management of the highest intake area must be carefully held: its part is preponderant in the feeding of the system

Isotopic investigation of infiltration and unsaturated zone processes at Carlsbad Cavern, 1992, Chapman J. A. , Ingraham N. L. , Hess J. W.

Measurements of tritium and O-18 concentrations in precipitation and runoff were used to provide further insight into the groundwater storage properties of the Wimbachtal Valley, a catchment area of 33.4 km2, extending between 636 and 2713 m a.s.l. in the Berchtesgaden Alps. The catchment includes three aquifer types: a dominant porous aquifer; a fractured dolomite; a karstic limestone aquifer. Employing a simple hydrological model, information about mean transit times of environmental tracers is derived for the groundwater runoff component and several karst springs from the application of the exponential and dispersion flow models to the isotopic input and output data. The mean transit times calculated from a dispersion model with transit times of 4.1 years for O-18 and 4.2 years for tritium, which agree well, allow calculation of total (mobile stagnant) groundwater storage volume, which is equivalent to 6.6 m of water depth. Direct runoff appears negligible as in many other cases

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