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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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That annual mean is the mean value taken over all events that have occurred during a year such as precipitation, river stages, watertable levels [16].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Speleogenesis: Evolution of Karst Aquifers., 2000,
The aim of this book is to present advances made in recent decades in our understanding of the formation of dissolutional caves, and to illustrate the role of cave genetic ( speleogenetic ) processes in the development of karst aquifers. From the perspective of hydrogeology, karst ground water flow is a distinct kind of fluid circulation system, one that is capable of self-organization and self-development due to its capacity to dissolve significant amounts of the host rock and transport them out of the system. Fluid circulation in soluble rocks becomes more efficiently organized by creating, enlarging and modifying patterns of cave conduits, the process of speleogenesis. We can assert that karst ground water flow is a function of speleogenesis and vice versa . The advances in cave science are poorly appreciated in what may be termed ?mainstream hydrogeology?, which retains a child-like faith in flow models developed in the sand box. Many karst students also will not be aware of all emerging concepts of cave origin because discussions of them are scattered through journals and books in different disciplines and languages, including publications with small circulation. An understanding of principles of speleogenesis and its most important controls is indispensable for proper comprehension of the evolution of the karst system in general and of karst aquifers in particular. We hope this book will be useful for both karst and cave scientists, and for general hydrogeologists dealing with karst terranes. This book is a pioneer attempt by an international group of cave scientists to summarize modern knowledge about cave origin in various settings, and to examine the variety of approaches that have been adopted. Selected contributions from 44 authors in 15 nations are combined in an integrated volume, prepared between 1994 and 1998 as an initiative of the Commission of Karst Hydrogeology and Speleogenesis, International Speleological Union. Despite a desire to produce an integrated book, rather than a mere collection of papers, the editors' policy has not been directed toward unifying all views. Along with some well-established theories and approaches, the book contains new concepts and ideas emerging in recent years. We hope that this approach will stimulate further development and exchange of ideas in cave studies and karst hydrogeology. Following this Introduction, (Part 1), the book is organized in seven different parts, each with sub-chapters. Part 2 gives a history of speleogenetic studies, tracing the development of the most important ideas from previous centuries (Shaw, Chapter 2.1) through the early modern period in the first half of this century (Lowe, Chapter 2.2) to the threshold of modern times (W.White, Chapter 2.3). The present state of the art is best illustrated by the entire content of this book. Part 3 overviews the principal geologic and hydrogeologic variables that either control or significantly influence the differing styles of cave development that are found. In Chapter 3.1 Klimchouk and Ford introduce an evolutionary approach to the typology of karst settings, which is a taken as a base line for the book. Extrinsic factors and intrinsic mechanisms of cave development change regularly and substantially during the general cycle of geological evolution of a soluble rock and , more specifically, within the hydrogeologic cycle. The evolutionary typology of karst presented in this chapter considers the entire life cycle of a soluble formation, from deposition (syngenetic karst) through deep burial, to exposure and denudation. It helps to differentiate between karst types which may concurrently represent different stages of karst development, and is also a means of adequately classifying speleogenetic settings. The different types of karst are marked by characteristic associations of the structural prerequisites for groundwater flow and speleogenesis, flow regime, recharge mode and recharge/discharge configurations, groundwater chemistry and degree of inheritance from earlier conditions. Consequently, these associations make a convenient basis to view both the factors that control cave genesis and the particular types of caves. Lithological and structural controls of speleogenesis are reviewed in general terms in Chapters 3.2 (Klimchouk and Ford). Lowe in Chapter 3.3 discusses the role of stratigraphic elements and the speleo-inception concept. Palmer in Chapter 3.4 overviews the hydrogeologic controls of cave patterns and demonstrates that hydrogeologic factors, the recharge mode and type of flow in particular, impose the most powerful controls on the formation of the gross geometry of cave systems. Hence, analysis of cave patterns is especially useful in the reconstruction of environments from paleokarst and in the prediction and interpretation of groundwater flow patterns and contaminant migration. Any opportunity to relate cave patterns to the nature of their host aquifers will assist in these applied studies as well. Osborne (Chapter 3.7) examines the significance of paleokarst in speleogenesis. More specific issues are treated by Klimchouk (The nature of epikarst and its role in vadose speleogenesis, Chapter 3.5) and by V.Dublyansky and Y.Dublyansky (The role of condensation processes, Chapter 3.6). Part 4 outlines the fundamental physics and chemistry of the speleogenetic processes (Chapter 4.1) and presents a variety of different approaches to modeling cave conduit development (Chapter 4.2). In Chapter 4.1, the chemical reactions during the dissolution of the common soluble minerals, calcite, gypsum, salt and quartz, are discussed with the basic physical and chemical mechanisms that determine their dissolution rates. As limestone is the most common karst rock and its dissolution is the most complex in many respects, it receives the greatest attention. Dreybrodt (Section 4.1.1) and Dreybrodt and Eisenlohr (Section 4.1.2) provide advanced discussion and report the most recent experimental data, which are used to obtain realistic dissolution rates for a variety of hydrogeologic conditions and as input for modeling the evolution of conduits. Although direct comparisons between theoretical or analytical dissolution rates and those derived from field measurements is difficult, a very useful comparison is provided by W.White (Section 4.1.3). The bulk removal of carbonate rock from karst drainage basins can be evaluated either by direct measurement of rock surface retreat or by mass balance within known drainage basins. All of these approaches make sense and give roughly accurate results that are consistent with theoretical expectations. It is well recognized today that the earliest, incipient, phases of speleogenesis are crucial in building up the pattern of conduits that evolve into explorable cave systems. It is difficult to establish the major controls on these initial stages by purely analytical or intuitive methods, so that modeling becomes particularly important. Various approaches are presented in Chapter 4.2. Ford, Ewers and Lauritzen present the results of systematic study of the propagation of conduits between input and output points in an anisotropic fissure, using a variety of hardware and software models, in series representing the "single input", "multiple inputs in one rank", and "multiple inputs in multiple ranks" cases (Section 4.2.1). The results indicate important details of the competitive development of proto-conduits and help to explain branching cave patterns. In the competition between inputs, some principal tubes in near ranks first link ("breakthrough") to an output boundary. This re-orients the flowfields of failed nearby competitors, which then extend to join the principal via their closest secondaries. The process extends outwards and to the rear, linking up all inputs in a "cascading system". The exploding growth of computer capability during the last two decades has greatly enhanced possibilities for digital modeling of early conduit development. Investigating the growth of a single conduit is a logical first step in understanding the evolution of caves, realized here by Dreybrodt and Gabrov?ek in the form of a simple mathematical model (Section 4.2.2) and by Palmer by numerical finite-difference modeling (Section 4.2.3). The models show that positive feedback loops operate; widening a fracture causes increasing flow through it, therefore dissolution rates increase along it and so on, until finally a dramatic increase of flow rates permits a dramatic enhancement of the widening. This breakthrough event terminates the initial stage of conduit evolution. From then on the water is able to pass through the entire conduit while maintaining sufficient undersaturation to preserve low-order kinetics, so the growth rate is very rapid, at least from a geological standpoint -- usually about 0.001-0.1 cm/yr. The initiation ("breakthrough") time depends critically on the length and the initial width of the fracture and, for the majority of realistic cases, it covers a time range from a few thousand years to ten million years in limestones. The modeling results give a clear explanation of the operation of selectivity in cave genesis. In a typical unconfined karst aquifer there is a great range of enlargement rates along the competing flow routes, and only a few conduits will grow to enterable size. The modeling also provides one starting point (others are discussed in Chapter 5.2) to explain uniform maze patterns, which will be favored by enlargement of all openings at comparable rates where the discharge/length ratio is great enough. Single-conduit modeling has the virtue of revealing how the cave-forming variables relate to each other in the simplest possible way. Although it is more difficult to extend this approach to two dimensions, many have done so (e.g. Groves & Howard, 1994; Howard & Groves, 1995; in this volume ? Ford, Ewers and Lauritzen, Section 4.2.1; Dreybrodt and Siemers, Section 4.2.4, and Sauter and Liedl, Section 4.2.5). The modeling performed by Dreybrodt and Siemers shows that the main principles of breakthrough derived from one-dimensional models remain valid. The evolution of karst aquifers has been modeled for a variety of different geological settings, including also variation in lithology with respect to the dissolution kinetics. Sauter and Liedl simulate the development of conduits at a catchment scale for fissured carbonate rocks with rather large initial openings (about 1 mm). The approach is based upon hydraulic coupling of a pipe network to matrix continuum in order to represent the well-known duality of karst aquifer flow systems. It is also shown how understanding of the genesis of karst aquifers and modeling of their development can assist in characterization of the conduit system, which dominates flow and transport in karst aquifers. An important point that has emerged from cave studies of the last three decades is that no single speleogenetic model applies to all geologic and hydrologic settings. Given that settings may also change systematically during the evolutionary geological cycles outlined above (Chapter 3.1), an evolutionary approach is called for. This is attempted in Part 5, which is organized to give extended accounts of speleogenesis in the three most important settings that we recognize: coastal and oceanic (Chapter 5.1), deep-seated and confined (Chapter 5.2) and unconfined (Chapter 5.3). Each Chapter begins with a review of modern ideas on cave development in the setting, followed by representative case studies. The latter include new accounts of some "classic" caves as well as descriptions of other, little-known cave systems and areas. Readers may determine for themselves how well the real field examples fit the general models presented in the introductory sections. Mylroie and Carew in Chapter 5.1 summarize specific features of cave and karst development in young rocks in coastal and island settings that result from the chemical interactions between fresh and salt waters, and the effects of fluctuating sea level during the Quaternary. The case studies include a review of syngenetic karst in coastal dune limestones, Australia (S.White, 5.1.1) and an example of speleogenesis on tectonically active carbonate islands (Gunn and Lowe, 5.1.2). Klimchouk in Chapter 5.2 reviews conditions and mechanisms of speleogenesis in deep-seated and confined settings, one of the most controversial but exciting topics in modern cave research. Conventional karst/speleogenetic theories are concerned chiefly with shallow, unconfined geologic settings, supposing that the karstification found there is intimately related to surface conditions of input and output, with the dissolution being driven by downward meteoric water recharge. The possibility of hypogenic karstification in deeper environments has been neglected for a long time, and the quite numerous instances of karst features found at significant depths have usually been interpreted as buried paleokarst. However, the last decade has seen a growing recognition of the variety and importance of hypogene dissolution processes and of speleogenesis under confined settings which often precedes unconfined development (Hill, 1987, 1995; Klimchouk, 1994, 1996, 1997; Lowe, 1992; Lowe & Gunn, 1995; Mazzullo & Harris, 1991, 1992; Palmer, 1991, 1995; Smart & Whitaker, 1991; Worthington, 1991, 1994; Worthington & Ford, 1995). Confined (artesian) settings were commonly ignored as sites for cave origin because the classic concept of artesian flow implies long lateral travel distances for groundwater within a soluble unit, resulting in a low capacity to generate caves in the confined area. However, the recognition of non-classical features in artesian flow, namely the occurrence of cross-formation hydraulic communication within artesian basins, the concepts of transverse speleogenesis and of the inversion of hydrogeologic function of beds in a sequence, allows for a revision of the theory of artesian speleogenesis and of views on the origin of many caves. It is proposed that artesian speleogenesis is immensely important to speleo-inception and also accounts for the development of some of the largest known caves in the world. Typical conditions of recharge, the flow pattern through the soluble rocks, and groundwater aggressiveness favor uniform, rather than competing, development of conduits, resulting in maze caves where the structural prerequisites exist. Cross-formational flow favors a variety of dissolution mechanisms that commonly involve mixing. Hydrogeochemical mechanisms of speleogenesis are particularly diverse and potent where carbonate and sulfate beds alternate and within or adjacent to hydrocarbon-bearing sedimentary basins. Hypogene speleogenesis occurs in rocks of varied lithology and can involve a variety of dissolution mechanisms that operate under different physical constraints but create similar cave features. Case studies include the great gypsum mazes of the Western Ukraine (Klimchouk, Section 5.2.1), great maze caves in limestones in Black Hills, South Dakota (Palmer, Section 5.2.2) and Siberia (Filippov, Section 5.2.3), karstification in the Redwall aquifer, Arizona (Huntoon, Section 5.2.4), hydrothermal caves in Hungary (Y.Dublyansky, Section 5.2.6), and sulfuric acid speleogenesis (Lowe, Bottrell and Gunn, Section 5.2.7, and Hill, Section 5.2.8). Y.Dublyansky summarizes the peculiar features of hydrothermal speleogenesis (Section 5.2.5), and V.Dublyansky describes an outstanding example of a hydrothermal cavity, in fact the largest ever recorded by volume, in the Rhodope Mountains (Section 5.2.9). Recognition of the scale and importance of deep-seated speleogenesis and of the hydraulic continuity and cross-formational communications between aquifers in artesian basins is indispensable for the correct interpretation of evolution of karst aquifers, speleogenetic processes and associated phenomena, regional karst water-resource evaluations, and the genesis of certain karst-related mineral deposits. These and other theoretical and practical implications still have to be developed and evaluated, which offers a wide field for further research efforts. Ford in Chapter 5.3 reviews theory of speleogenesis that occurs where normal meteoric waters sink underground through the epikarst or dolines and stream sinks, etc. and circulate in the limestone or other soluble rocks without any major artesian confinement. These are termed common caves (Ford & Williams, 1989) because they probably account for 90% or more of the explored and mapped dissolutional caves that are longer than a few hundred meters. This estimate reflects the bias in exploration; caves formed in unconfined settings and genetically related to surface recharge are the most readily accessible and hence form the bulk of documented caves. Common caves display chiefly the branchwork forms where the dissolutional conduits occupy only a tiny proportion of the total length or area of penetrable fissures that is available to the groundwaters. The rules that govern the selection of the successful linkages that will be enlarged into the branchwork pattern are supported in the models presented in Chapter 4.2. In the long section caves may be divided into deep phreatic, multi-loop, mixed loop and water table, and ideal water table types, with drawdown vadose caves or invasion vadose caves above them. Many large systems display a mixture of the types. The concepts of plan pattern construction, phreatic, water table or vadose state, and multi-phase development of common caves are illustrated in the case studies that follow the introduction. They are organized broadly to begin with examples of comparatively simple deep phreatic and multi-loop systems (El Abra, Mexico, Ford, Section 5.3.1 and Castleguard Cave, Canada, Ford, Lauritzen and Worthington, Section 5.3.2), proceeding to large and complex multi-phase systems such as the North of Thun System, Switzerland (Jeannin, Bitterly and Hauselmann, Section 5.3.3) and Mammoth Cave, Kentucky (Palmer, Section 5.3.8), to representatives of mixed vadose and phreatic development in mountainous regions (the Alps, Audra, Section 5.3.4; the Pyrenees, Fernandez, Calaforra and Rossi, Section 5.3.5; Mexico, Hose, Section 5.3.6) and where there is strong lithologic or structural control (Folded Appalachians, W.White, Section 5.3.7; gypsum caves in the South of Spain, Calaforra and Pulido-Bosch, Section 5.3.10). Two special topics are considered by W.White in Section 5.3.9 (Speleogenesis of vertical shafts in the eastern US) and Palmer (Maze origin by diffuse recharge through overlying formation). The set concludes with two instances of nearly ideal water table cave development (in Belize and Hungary, Ford, Section 5.3.12), and a review of the latest models of speleogenesis from the region where modern karst studies in the West began, the Classical Karst of Slovenia and Trieste (?u?ter?ic, Section 5.3.13). In Parts 2-5 attention is directed primarily on how the gross geometry of a cave system is established. Part 6 switches focus to the forms at meso- and micro- scales, which can be created during enlargement of the cave. Lauritzen and Lundberg in Chapter 6.1 summarize the great variety of erosional forms ( speleogenetic facies ) that can be created by a wide range of speleogenetic agents operating in the phreatic or vadose zones. Some forms of cave passages have been subject to intensive research and may be interpreted by means of simple physical and chemical principles, but many others are polygenetic and hence difficult to decipher with certainty. However, in addition to the analysis of cave patterns (see Chapter 3.4), each morphological element is a potential tool that can aid our inferences on the origin of caves and on major characteristics of respective past hydrogeological settings. In Chapter 6.2 E.White and W.White review breakdown morphology in caves, generalizing that the processes are most active during the enlargement and decay phases of cave development. Early in the process breakdown occurs when the flow regime shifts from pipe-full conditions to open channel conditions (i.e. when the roof first loses buoyant support) and later in the process breakdown becomes part of the overall degradation of the karst system. The chapter addresses the mechanism of breakdown formation, the geological triggers that initiate breakdown, and the role that breakdown plays in the development of caves. As the great majority of both theoretical considerations and case studies in this book deal with speleogenesis in carbonate rocks, it is useful to provide a special forum to examine dissolution cave genesis in other rocks. This is the goal of Part 7. Klimchouk (7.1) provides a review of speleogenesis in gypsum. This appears to be a useful playground for testing the validity and limitations of certain general speleogenetic concepts. Differences in solution kinetics between gypsum and calcite impose some limitations and peculiar features on the early evolution of conduits in gypsum. These peculiarities appear to be an extreme and more obvious illustration of some rules of speleogenetic development devised from conceptual and digital modeling of early conduit growth in limestones. For instance, it is shown (e.g. Palmer, 1984, 1991; Dreybrodt, 1996; see also Chapter 3.4 and Section 4.2.2) that initiation of early, narrow and long pathways does not seem feasible under linear dissolution rate laws (n=1) due to exponential decrease of the dissolution rates. Although the dissolution kinetics of gypsum are not well known close to equilibrium it is generally assumed that they are controlled entirely by diffusion and therefore linear. If dissolution of gypsum is solely diffusion-controlled, with no change in the kinetic order, conduit initiation could not occur in phreatic settings or by lateral flow through gypsum from distant recharge areas in artesian settings. Hence, the fact that maze caves are common in gypsum in artesian conditions (see Section 5.2.1) gives strong support to a general model of "transverse" artesian speleogenesis where gypsum beds are underlain by, or sandwiched between, insoluble or low-solubility aquifers (Chapter 5.2), and suggests that it may be applicable to cave development in carbonates. In unconfined settings, speleogenesis in gypsum occurs along fissures wide enough to support undersaturated flow throughout their length. Linear or crudely branching caves overwhelmingly predominate, which rapidly adjust to the contemporary geomorphic setting and to the maximum available recharge. Also, if considerable conduit porosity has been created in deep-seated settings, it provides ready paths for more intense groundwater circulation and further cave development when uplift brings the gypsum into the shallow subsurface. Speleogenesis in salt, reviewed in general and exemplified by the Monte Sedom case in Israel (Frumkin, Chapter 7.2), has been documented only in open, unconfined settings, where it provides a model for simple vadose cave development. Chapter 7.3 deals with speleogenesis in quartzites, illustrated by case studies from southeastern Minas Gerais, Brasil (Correa Neto, 7.3.1) and South Africa (Martini, 7.3.2). The process involves initial chemical weathering of the quartzite to create zones of friable rocks (sanding, or arenisation) which then are removed by piping, with further conduit enlargement due to mechanical erosion by flowing water. Part 8 combines the theoretical with some applied aspects of speleogenetic studies. Worthington, Ford and Beddows (8.1) show the important implications of what might be termed "speleogenetic wisdom" when studying ground water behaviour in karst. They examine some standard hydrogeological concepts in the light of knowledge of caves and their patterns, considering a range of case studies to identify the characteristic enhancement of porosity and permeability due to speleogenesis that occurs in carbonate rocks. The chapter focuses on unconfined carbonate aquifers as these are the most studied from the speleological perspective and most important for water supplies. Four aquifers, differing in rock type, recharge type (allogenic and autogenic), and age (Paleozoic, Mesozoic and Cenozoic), are described in detail to demonstrate the extent of dissolutional enhancement of porosity and permeability. It is shown that all four cases are similar in hydraulic function, despite the fact that some of them were previously characterized as different end members of a "karst ? non-karst" spectrum. Enhancement of porosity by dissolution is relatively minor: enhancement of permeability is considerable because dissolution has created dendritic networks of channels able to convey 94% or more of all flow in the aquifer, with fractures providing a small proportion and the matrix a negligible amount. These conclusions may be viewed as a warning to hydrogeologists working in carbonate terranes: probably the majority of unconfined aquifers function in a similar manner. Sampling is a major problem in their analysis because boreholes (the conventional exploration tool in hydrogeology) are unlikely to intersect the major channels that are conveying most of the flow and any contaminants in it. It is estimated, using examples of comprehensively mapped caves, that the probability of a borehole intersecting a conduit ranges from 1 in 50 to 1 in 1000 or more. Boreholes simply cannot be relied upon to detect the presence of caves or to ?characterise? the hydrologic functioning of cavernous aquifers. Wherever comprehensive evidence has been collected in unconfined carbonate aquifers (cave mapping plus boreholes plus lab analysis of core samples) it suggests that dissolution inexorably results in a similar structure, with channel networks providing most of the permeability of the aquifer, yet occupying a very minor fraction of its volume (Worthington, Ford and Beddows). Lowe (Chapter 8.2) focuses on developments in understanding the vital role played by karstic porosity, (broadly viewed as being the product of speleogenesis), in the migration of mineralizing fluids (or hydrocarbons) and in their deposition (or storage), and comments on the potential role of new speleogenetic concepts in developing greater understanding in the future. Although some early workers were clearly aware of actual evidence for some kind of relationship, and others noted its theoretical likelihood, it has been ignored by many until relatively recent times. This shortfall has gradually been redressed; new understanding of the extent and variety of karst processes is ensuring that new relationships are being recognized and new interpretations and models are being derived. The chapter does not pretend to give a comprehensive account of the topic but clearly demonstrates the wide applicability of speleogenetic knowledge to issues in economic geology. In Chapter 8.3 Aley provides an overview of the water and land-use problems that occur in areas with conduit aquifers. He stresses that sound land management must be premised on an understanding that karst is a three-dimensional landscape where the surface and subsurface are intimately and integrally connected. Failure to recognize that activity at the surface affects the subsurface, and the converse, has long been the root cause of many of the problems of water and land use in karst regions. Karst areas have unique natural resource problems, whose management can have major economic consequences. Although there is an extensive literature on the nature of particular problems, resource protection and hazard minimization strategies in karst, it rarely displays an advanced understanding of the processes of the conduit formation and their characteristics yet these will always be involved. This book does not pretend to be a definitive text on speleogenesis. However, it is hoped that readers will find it to be a valuable reference source, that it will stimulate new ideas and approaches to develop and resolve some of the remaining problems, and that it will promote an appreciation of the importance of speleogenetic studies in karst hydrogeology and applied environmental sciences. Acknowledgements: We sincerely thank all contributors for their willing cooperation in the long and difficult process of preparing this book, for their participation in developing its logic and methodology and their cheerful response to numerous requests. We thank all colleagues who discussed the work with us and encouraged it in many ways, even though not contributing to its content as authors. We are particularly grateful to Margaret Palmer for invaluable help in editing the English in many contributions, to Nataly Yablokova for her help in performing many technical tasks and to Elizabeth White who prepared comprehensive index. Our thanks are due to Dr. David Drew, Dr. Philip LaMoreaux, Dr. George Moore and Prof. Marian Pulina for reviewing the manuscript and producing constructive notes and comments on improvement of the final product. The organizational costs and correspondence related to the preparation of the book were partially sponsored by the National Speleological Society, the publisher. We thank David McClurg, the Chair of the NSS Special Publication Committee, for his extensive technical and organizational support in the preparation and publishing processes.

Exchange of water between conduits and matrix in the Floridan aquifer, 2001, Martin J. B. , Dean R. W. ,
Flow through carbonate aquifers may be dominated by conduits where they are present, by intergranular or fracture porosity where conduits are missing, or may occur in conduits and matrix porosity where both are well developed. In the latter case, the exchange of water between conduits and matrix could have important implications for water management and hydrodynamic modeling. An extensive conduit system has been mapped by dye trace studies and cave diving exploration at the Santa Fe Sink/Rise system located in largely unaltered rocks of the Floridan aquifer of north-central Florida. In this area, the Santa Fe River flows underground at the River Sink and returns to the surface similar to 5 km to the south at a first magnitude spring called the River Rise. Limited data show that discharge is greater by 27-96% at the River Rise than at the Sink and that the downstream increase in discharge is inversely related to discharge of the river. Natural SO42- concentrations indicate that similar to 25% of the water discharging from the Rise originates from the Sink during low flow. Conversely, SO42- and other solute concentrations indicate that most of the water discharging from the Rise originates from the Sink during floods. Ar similar to 40% decrease in Na () and Cl (-) concentrations over a 5 1/2-month period at a down-gradient water supply well may reflect flow of dilute flood water from the conduits into and through the matrix at rates estimated to be between 9 and 65 m/day, Calcium concentrations remain constant through time at the well, although flood waters have similar to 90% lower Ca (2) concentrations than ground water, perhaps reflecting dissolution of the matrix rocks. This apparent exchange of water between matrix and conduits is important for regional ground water quality and dissolution reactions, (C) 2001 Published by Elsevier Science B.V

Results from the Big Spring basin water quality monitoring and demonstration projects, Iowa, USA, 2001, Rowden R. D. , Liu H. B. , Libra R. D. ,
Agricultural practices, hydrology, and water quality of the 267-km(2) Big Spring groundwater drainage basin in Clayton County, Iowa, have been monitored since 1981. Land use is agricultural; nitrate-nitrogen (-N) and herbicides are the resulting contaminants in groundwater and surface water. Ordovician Galena Group carbonate rocks comprise the main aquifer in the basin. Recharge to this karstic aquifer is by infiltration, augmented by sinkhole-captured runoff. Groundwater is discharged at Big Spring, where quantity and quality of the discharge are monitored. Monitoring has shown a threefold increase in groundwater nitrate-N concentrations from the 1960s to the early 1980s. The nitrate-N discharged from the basin typically is equivalent to over one-third of the nitrogen fertilizer applied, with larger losses during wetter years. Atrazine is present in groundwater all year; however, contaminant concentrations in the groundwater respond directly to recharge events, and unique chemical signatures of infiltration versus runoff recharge are detectable in the discharge from Big Spring. Education and demonstration efforts have reduced nitrogen fertilizer application rates by one-third since 1981. Relating declines in nitrate and pesticide concentrations to inputs of nitrogen fertilizer and pesticides at Big Spring is problematic. Annual recharge has varied five-fold during monitoring, overshadowing any water-quality improvements resulting from incrementally decreased inputs

Determining the source of stream contamination in a karst water system, southwest Virginia, USA, 2001, Younos T. , Kaurish F. W. , Brown T. , De Leon R. ,
Karst terrane provides a linkage between surface water and ground water regimes by means of caves, sinkholes and swallets, and sinking streams, and facilitates the inter-watershed transfer of water and contaminants through these subsurface systems. The goal of this study was to develop procedures to identify the sources of degradation of a creek situated in a complex karst-water system. The study approach consisted of using dye tracing technique to determine subsurface flow paths through the karst system, a water-sampling network to identify and characterize pollution sources within the surface watershed and subsurface flow regime, and evaluation of analytical data for several water quality parameters. The results of this study provide an interesting perspective of water and contaminant movement in karst-water systems and pinpoint the sources of stream contamination for a case study site in southwest Virginia where two springs supply water to a contaminated freshwater stream

Contaminant transport in karst aquifers., 2001, Vesper D. J. , Loop C. M. , White W. B.
Contaminants are easily injected into karst aquifers through sinking streams, sinkholes, or through open fractures and shafts in the carbonate rock. Transport of the contaminants through the aquifer is by a variety of mechanisms depending on the physical and chemical properties of the contaminant. Contaminants consist of (1) water soluble compounds, both organic and inorganic, (2) slightly soluble organic compounds, less dense than water (LNAPLs), (3) slightly soluble organic compounds, more dense than water (DNAPLs), (4) pathogens, (5) metals, and (6) trash. Water soluble compounds (e.g. nitrates, cyanides, carboxylic acids, phenols) move with the water. But rather than forming a plume spreading from the input point, the contaminated water forms linear stringers migrating down the conduit system toward the discharge point. LNAPLs (e.g. petroleum hydrocarbons) float on the water table and can migrate down the water table gradient to cave streams where they tend to pond behind obstructions. DNAPLs (e.g. chlorinated hydrocarbons), in contrast, sink to the bottom of the aquifer. In the conduit system, DNAPLs pond in low spots at the bottom of the conduit and infiltrate sediment piles. Transport of both LNAPL and DNAPL is dependent on storm flow which can force LNAPL through the system as plug flow and can move DNAPLs by mobilizing the sediment piles. Pathogens (viruses, bacteria, parasites) are transported through the karstic drainage system because of the absence of filtration and retain their activity for long distances. Metals (e.g. chromium, nickel, cadmium, mercury, and lead) tend to precipitate as hydroxides and carbonates in the neutral pH, carbonate rich water of the karst aquifer. Metal transport is mainly as particulates and as metal adsorbed onto small particulates such as clays and colloids. Metal transport is also episodic. Metals migrate down the flow path under flow conditions that take small particulates into suspension. Trash is carried into karst aquifers through sinkholes and sinking streams. It is, in effect, a form of clastic sediment, and can be carried deep into the conduit system where it can act as a source term for other contaminants leached from the trash.

Exchange of Matrix and Conduit Water with Examples from the Floridan Aquifer, 2001, Martin J. D. , Screaton E. J.

Rapid infiltration of surface water and contaminants occurs in karst aquifers because of extensive conduit development, but contamination of ground water supplies requires loss of conduit water to the matrix. This process is also important for ground water management and for dissolution and diagenetic reactions. Many factors control exchange between conduits and matrix including the head gradient between matrix and conduits, the permeability of the matrix, the gradients of the regional water table and the conduits, and the relative elevation of the conduits and regional water table. The Floridan Aquifer, which is characterized by high matrix porosity and permeability, provides several examples. 


KARSTIC: a sensitivity method for carbonate aquifers in karst terrain, 2002, Davis Ad, Long Aj, Wireman M,
Groundwater in karstic aquifers can be dangerously sensitive to contamination. Many cities in the western USA rely on karstic carbonate aquifers for municipal water supplies. For example, Rapid City, South Dakota, pumps more than half of its drinking water from wells in the Madison Limestone. This work examined the sensitivity of karstic aquifers to surface contamination in mountainous terrain. Where karstic carbonate aquifers are exposed at their outcrop areas, they are particularly susceptible to the introduction of contamination through diffuse recharge or through point recharge at swallow holes along streams. Residential developments in mountainous regions of the western USA are encroaching on the recharge areas of karstic aquifers. Many of these residential developments are served by onsite wastewater disposal systems such as septic tanks and drain fields, with the attendant danger of introduction of pathogens from malfunctioning treatment systems above fractured limestone which offers little filtering. Where streams disappear into karstic aquifers at swallow holes, microbial contaminants such as Giardia or Cryptosporidium are a concern, as well as potential spills, leaks, or accidents along roads near these streams. The KARSTIC method developed and modified in this work puts greater emphasis on karst features than previous sensitivity procedures such as the US Environmental Protection Agency's DRASTIC method. The modified method gives increased attention to highly sensitive areas of karstic carbonate aquifers by weighting the synergistic effects of fracturing, karst development, and swallow holes of recharging streams. In a field application, hydrogeologic maps of a watershed in the Black Hills, USA, were digitized into a geographic information system. The resulting sensitivity map and report can be used by planners, managers, and the public as a screening tool for assessing groundwater sensitivity in regions which include karstic aquifers

Soil gas screening for chlorinated solvents at three contaminated karst sites in Tennessee, 2002, Wolfe W. J. , Williams S. D. ,
Soil gas was sampled using active sampling techniques and passive collectors at three sites in Tennessee to evaluate the effectiveness of these techniques for locating chlorinated solvent sources and flowpaths in karst aquifers. Actively collected Soil gas samples were analyzed in the field with a portable gas chromatograph, and the passive soil gas collectors were analyzed in the lab with gas chromatography/mass spectrometry. Results of the sampling indicate that the effectiveness of both techniques is highly dependent on the distribution of the contaminants in the subsurface, the geomorphic and hydrogeologic characteristics of the site, and, in one case, on seasonal conditions. Both active and passive techniques identified areas of elevated subsurface chlorinated solvent concentrations at a landfill site where contamination remains concentrated in the regolith. Neither technique detected chlorinated solvents known to be moving in the bedrock at a manufacturing site characterized by thick regolith and an absence of surficial karst features. Passive soil gas sampling had varied success detecting flowpaths for chloroform in the bedrock at a train derailment site characterized by shallow regolith and abundant surficial karst features. At the train derailment site, delineation of the contaminant flowpath through passive soil gas sampling was stronger and more detailed under winter conditions than summer

Contaminant transport in karst aquifers, 2003, Vesper D. J. , Loop C. M. , White W. B.

Contaminants are easily injected into karst aquifers through sinking streams, sinkholes, or through open fractures and shafts in the carbonate rock. Transport of the contaminants through the aquifer is by a variety of mechanisms depending on the physical and chemical properties of the contaminant. Contaminants consist of (1) water soluble compounds, both organic and inorganic, (2) slightly soluble organic compounds, less dense than water (LNAPLs), (3) slightly soluble organic compounds, more dense than water (DNAPLs), (4) pathogens, (5) metals, and (6) trash. Water soluble compounds (e.g. nitrates, cyanides, carboxylic acids, phenols) move with the water. But rather than forming a plume spreading from the input point, the contaminated water forms linear stringers migrating down the conduit system toward the discharge point. LNAPLs (e.g. petroleum hydrocarbons) float on the water table and can migrate down the water table gradient to cave streams where they tend to pond behind obstructions. DNAPLs (e.g. chlorinated hydrocarbons), in contrast, sink to the bottom of the aquifer. In the conduit system, DNAPLs pond in low spots at the bottom of the conduit and infiltrate sediment piles. Transport of both LNAPL and DNAPL is dependent on storm flow which can force LNAPL through the system as plug flow and can move DNAPLs by mobilizing the sediment piles. Pathogens (viruses, bacteria, parasites) are transported through the karstic drainage system because of the absence of filtration and retain their activity for long distances. Metals (e.g. chromium, nickel, cadmium, mercury, and lead) tend to precipitate as hydroxides and carbonates in the neutral pH, carbonate rich water of the karst aquifer. Metal transport is mainly as particulates and as metal adsorbed onto small particulates such as clays and colloids. Metal transport is also episodic. Metals migrate down the flow path under flow conditions that take small particulates into suspension. Trash is carried into karst aquifers through sinkholes and sinking streams. It is, in effect, a form of clastic sediment, and can be carried deep into the conduit system where it can act as a source term for other contaminants leached from the trash


Surface and subsurface environmental degradation in the karst of Apulia (southern Italy), 2003, Parise M. , Pascali V. ,
Karst environments are highly vulnerable to a variety of degradation and pollution problems. Geology (fractured carbonate rocks), morphology (presence of a network of cavities produced by karst processes), and hydrogeology (rapid concentrated flow through fractures and conduits) of karst carbonates strongly favour the movement of contaminants towards the water table. In particular, poor quality of subsurface water can derive from polluting substances flowing at the surface, and/or by direct immission of liquid and solid waste into the water table through the systems of conduits and joints in the rock mass. As a consequence, water quality can deteriorate severely, which implies very high economic and social costs in order to clean the polluted sites and restore the original situation. In some cases, such as when the original karst morphology is changed because of anthropogenic interventions, the variations created in the landscape are not recoverable, and a loss of sites of naturalistic interest has to be registered. High vulnerability of a typical karst region of the Mediterranean area is illustrated in this paper by describing some case studies from Apulia, southern Italy. The Apulia region, where karst processes have had a prominent role in the development of the present landscape, is mostly underlain by intensely karstified limestone. Two cases of pollution due to solid waste into karst cavities (Grave di S. Leonardo in the Gargano Promontory and Grave Pelosello in the Murge plateau), landscape transformation in the Minervino Murge area, and degradation of Gravina Monsignore, a typical karst valley in southeastern Murge, are described in the paper. In two out of four cases, degradation of the sites was discovered thanks to activity from local speleologists, who also acted as promoters for cleaning and safeguarding the polluted sites. These examples underline well the mismanagement of karst territories (in particular, the common practice to dump refuse into sinkholes and caves), the pollution of limestone aquifers, and the effects that such pollution in karst areas might have in terms of the risk to public health

Evaluation of a peat filtration system for treating highway runoff in a karst setting, 2003, Zhou W. F. , Beck B. F. , Green T. S. ,
The deleterious character of highway runoff, especially following long periods without precipitation, has been well documented in the literature. It transports hydrocarbons, heavy metals, and other contaminants from highways, contributing to the pollution of surface water and groundwater. Groundwater is particularly vulnerable in karst areas where highway runoff is transferred quickly into subsurface conduit networks through open sinkholes and/or sinking streams. The difficulties in remediating contaminated karst aquifers make it crucial for karst aquifers to receive only uncontaminated water. A peat filtration system was constructed at the I-40/I-640 interchange in eastern Knoxville, Tennessee, USA, to remove highway runoff contaminants prior to being transported into karst aquifers.- Recent field tests indicate that the system can significantly decrease the concentrations of analyzed constituents including PAHs (polyaromatic hydrocarbons), popper, and zinc. However, the removal efficiency depends on the concentration of the contaminants in the runoff. Long-term monitoring is required to determine the true effectiveness of the designed filtration system and its reliability

A conceptual model of flow and transport in a karst aquifer based on spatial and temporal variations of natural tracers, 2003, Perrin, Jerome

Karst aquifers represent an important groundwater resource world-wide. They are highly vulnerable to contamination due to fast transport through the system and limited attenuation of contaminants. The two main hydrogeological approaches developed for studying flow and transport are: inference of the
system structure from karst spring hydrographs and chemographs; numerical modelling of flow and transport using a theoretical distribution of flow and transport field parameters. These two approaches lack of validation by detailed field measurements and observations. The main objective of this thesis is to “fill the gap” existing between field and model data. Observations of flow and transport parameters at several locations within the system were used to develop a conceptual model. This model was then compared to the existing models.
The main field test site is the Milandre karst aquifer, located in the Swiss tabular Jura. Natural tracers (major ions, oxygen-18, specific conductance) and discharge were measured on the underground river, its main tributaries, percolation waters, and the main spring. These data were collected on a long-term basis in order to assess the spatial variability of the parameters, and on a short time scale (i.e. flood events) in order to investigate the dynamic processes. Complementary sites (Brandt and Grand Bochat) were used for more observations at the base of the epikarst.
The proposed conceptual model considers four sub-systems: the soil zone, the epikarst, the unsaturated zone, and the phreatic zone. Each has its own specificity with respect to flow and transport. The soil zone controls the actual infiltration into the system. It contributes efficiently to groundwater storage. It mixes quickly stored water with fresh infiltrated water. Its thickness determines land-use: thick soils are generally cultivated whereas thin soils are under forested areas. The solutes concentration of soil waters depends on land-use for pollution-related parameters (nitrate, chloride, sulfate, potassium, sodium). Moreover the soil zone is the main source of CO2 which controls the limestone dissolution-related parameters. The epikarst zone contributes largely to groundwater storage. It distributes groundwater into vadose flow through conduits, and base flow through low permeability volumes (LPV) in the unsaturated zone. It is the sub-system where dissolution-related parameters are mostly acquired.
The unsaturated zone is seen as a transmissive zone connecting the epikarst to the horizontal conduit network of the phreatic zone. In case of flood events, some dissolution still occurs in this sub-system.
The phreatic zone is the partly flooded conduit network draining groundwater to the spring. It collects waters issued from the unsaturated zone, mixes the tributaries, and drain the water towards the discharge area. The role of phreatic storage appears to be limited for both hydraulics and transport.
Tributary mixing is a prominent process that shapes spring chemographs during flood events. In steady-state conditions, base flow is mainly sustained by the epikarst reservoir. Tracer concentrations are stable as the chemical equilibrium is already reached in the epikarst. Waters issued from the different tributaries mix in the conduit network, and the spring chemistry is the result of this mixing.
During flood events, transient flow induces non-linear mixing of the tributaries. The respective contributions of the tributaries change throughout the flood, and the spring chemographs vary accordingly. In case of important recharge, waters issued from other sources than the epikarst participate to the flood. First, soil water reaches the phreatic zone. Its characteristics are a dampened isotopic signal, and ionic concentrations differing from those of the epikarst. Second, fresh water directly issued from rainfall, may reach the phreatic zone. Its characteristics are a varying isotopic signal, and diluted ionic concentrations. The mixing components participating to the flood are controlled by the actual infiltration volume (or height). The limestone dissolution process is effective for the fresh and soil components of flow. However mixing processes play a more important role than dissolution for shaping the spring chemographs.
From a practical point of view, the project confirmed the prominent role of the soil zone and the epikarst on the solute transport in karst systems. This was already integrated in karst vulnerability mapping methods recently developed (EPIK, PI, VULK).

http://doc.rero.ch/record/2604/files/these_PerrinJ.pdf


Linear model describing three components of flow in karst aquifers using O-18 data, 2004, Long A. J. , Putnam L. D. ,
The stable isotope of oxygen, 180, is used as a naturally occurring ground-water tracer. Time-series data for 5 180 are analyzed to model the distinct responses and relative proportions of the conduit, intermediate, and diffuse flow components in karst aquifers. This analysis also describes mathematically the dynamics of the transient fluid interchange between conduits and diffusive networks. Conduit and intermediate flow are described by linear-systems methods, whereas diffuse flow is described by mass-balance methods. An automated optimization process estimates parameters of lognormal, Pearson type III, and gamma distributions, which are used as transfer functions in linear-systems analysis. Diffuse flow and mixing parameters also are estimated by these optimization methods. Results indicate the relative proximity of a well to a main conduit flowpath and can help to predict the movement and residence times of potential contaminants. The three-component linear model is applied to five wells, which respond to changes in the isotopic composition of point recharge water from a sinking stream in the Madison aquifer in the Black Hills of South Dakota. Flow velocities as much as 540 m/d and system memories of as much as 71 years are estimated by this method. Also, the mean, median, and standard deviation of traveltimes; time to peak response; and the relative fraction of flow for each of the three components are determined for these wells. This analysis infers that flow may branch apart and rejoin as a result of an anastomotic (or channeled) karst network. Published by Elsevier B.V

Halloysite clay minerals -- a review, 2005, Joussein E. , Petit S. , Churchman J. , Theng B. , Righi D. , Delvaux B. ,
Halloysite clay minerals are ubiquitous in soils and weathered rocks where they occur in a variety of particle shapes and hydration states. Diversity also characterizes their chemical composition, cation exchange capacity and potassium selectivity. This review summarizes the extensive but scattered literature on halloysite, from its natural occurrence, through its crystal structure, chemical and morphological diversity, to its reactivity toward organic compounds, ions and salts, involving the various methods of differentiating halloysite from kaolinite. No unique test seems to be ideal to distinguish these 1:1 clay minerals, especially in soils. The occurrence of 2:1 phyllosilicate contaminants appears, so far, to provide the best explanation for the high charge and potassium selectivity of halloysite. Yet, hydration properties of the mineral probably play a major role in ion sorption. Clear trends seem to relate particle morphology and structural Fe. However, future work is required to understand the possible mechanisms linking chemical, morphological, hydration and charge properties of halloysite

Discriminating Sources and Flowpaths of Anthropogenic Nitrogen Discharges to Florida Springs, Streams and Lakes, 2005, Bacchus St, Barile Pj,
Surface discharges of anthropogenic nutrients historically have been the focus of Florida's water-quality regulations. Groundwater contributions to eutrophication of Florida's surface waters are a more recent focus. Florida's naturally oligotrophic springs, streams, and lakes are experiencing significant anthropogenic nutrient contamination resulting from groundwater discharges with elevated nitrate. Sources of nitrate contamination to these surface-water ecosystems include sewage effluent, industrial animal waste (concentrated animal feedlot operations) and inorganic fertilizers. In this study, stable nitrogen isotope ({delta}15N) analysis of freshwater macrophytes was combined with basic knowledge of watershed and springshed land use and aquifer characteristics to provide evidence of nitrogen contamination sources and groundwater flowpaths. Selected naturally oligotrophic ecosystems included springs and a spring-run stream within the Ocala National Forest (ONF) and springs, a blackwater stream, and a sinkhole lake on or adjacent to state lands. Elevated {delta}15N values ([~] 8 to 12{per thousand}) in ONF macrophytes indicated nitrogen contamination from sewage effluent. Underground injections of effluent and other wastes at ONF's Alexander and Juniper Springs Recreation Areas are the sole source of contaminants flowing through the sandy, surficial aquifer at those study areas. Samples from springs on state lands indicated nitrogen contamination from various sources via regional groundwater flowpaths. At Lake Placid's state lands, a dairy-waste lagoon was the groundwater source of nitrogen contamination via the sandy, surficial aquifer. Bulow Creek {delta}15N macrophyte values ([~] 5 to 8{per thousand}) suggested contamination from both cattle and septic tank leachate. Results indicated that uptake of anthropogenic nitrogen occurred in invasive alien and nuisance native macrophytes in the four freshwater ecosystem types evaluated

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