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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That krab is see carabiner.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for chlorofluorocarbons (Keyword) returned 8 results for the whole karstbase:
CHEMICAL EVOLUTION OF GROUNDWATER NEAR A SINKHOLE LAKE, NORTHERN FLORIDA .1. FLOW PATTERNS, AGE OF GROUNDWATER, AND INFLUENCE OF LAKE WATER LEAKAGE, 1995, Katz B. G. , Lee T. M. , Plummer L. N. , Busenberg E. ,
Leakage from sinkhole lakes significantly influences recharge to the Upper Floridan aquifer in poorly confined sediments in northern Florida. Environmental isotopes (oxygen 18, deuterium, and tritium), chlorofluorocarbons (CFCs: CFC-11, CCl3F; CFC-12, CCl2F2; and CFC-113, C2Cl3F3), and solute tracers were used to investigate groundwater flow patterns near Lake Barco, a seepage lake in a mantled karst setting in northern Florida. Stable isotope data indicated that the groundwater downgradient from the lake contained 11-67% lake water leakage, with a limit of detection of lake water in groundwater of 4.3%. The mixing fractions of lake water leakage, which passed through organic-rich sediments in the lake bottom, were directly proportional to the observed methane concentrations and increased with depth in the groundwater flow system. In aerobic groundwater upgradient from Lake Barco, CFC-modeled recharge dates ranged from 1987 near the water table to the mid 1970s for water collected at a depth of 30 m below the water table. CFC-modeled recharge dates (based on CFC-12) for anaerobic groundwater downgradient from the lake ranged from the late 1950s to the mid 1970s and were consistent with tritium data. CFC-modeled recharge dates based on CFC-11 indicated preferential microbial degradation in anoxic waters. Vertical hydraulic conductivities, calculated using CFC-12 modeled recharge dates and Darcy's law, were 0.17, 0.033, and 0.019 mid for the surficial aquifer, intermediate confining unit, and lake sediments, respectively. These conductivities agreed closely with those used in the calibration of a three-dimensional groundwater flow model for transient and steady state flow conditions

Timescales for nitrate contamination of spring waters, northern Florida, USA, 2001, Katz B. G. , Bohlke J. K. , Hornsby H. D. ,
Residence times of groundwater, discharging from springs in the middle Suwannee River Basin, were estimated using chlorofluorocarbons (CFCs), tritium ((3) H), and tritium/helium-3 (H-3/He-3) age-dating methods to assess the chronology of nitrate contamination of spring waters in northern Florida. During base-flow conditions for the Suwannee River in 1997-1999, 17 water samples were collected from 12 first, second, and third magnitude springs discharging groundwater from the Upper Floridan aquifer. Extending age-dating techniques, using transient tracers to spring waters in complex karst systems, required an assessment of several models [piston-flow (PFM), exponential mixing (EMM), and binary-mixing (BMM)] to account for different distributions of groundwater age. Multi-tracer analyses of four springs yielded generally concordant PFM ages of around 20 2 years from CFC- 12, CFC- 113, H-3, and He-3. with evidence of partial CFC- 11 degradation. The EMM gave a reasonable fit to CFC- 113, CFC- 12. and H-3 data, but did not reproduce the observed He-3 concentrations or H-3/He-3 ratios, nor did a combination PFM-EMM. The BMM could reproduce most of the multi-tracer data set only if both endmembers had H-3 concentrations not much different front modern values. CFC analyses of 14 additional springs yielded apparent PFM ages from about 10 to 20 years from CFC- 113, with evidence of partial CFC- 11 degradation and variable CFC-12 contamination. While it is not conclusive, with respect to the age distribution within each spring, the data indicate that the average residence times were in the order of 10-20 years and were roughly proportional to spring magnitude. Applying similar models to recharge and discharge of nitrate based on historical nitrogen loading data yielded contrasting trends for Suwanee County and Lafayette County. In Suwance County, spring nitrate trends and nitrogen isotope data were consistent with a peak in fertilizer input in the 1970s and a relatively high overall ratio of artificial fertilizer/manure whereas in Lafayette County, spring nitrate trends and nitrogen isotope data were consistent with a more monotonic increase in fertilizer input and relatively low overall ratio of artificial fertilizer/manure. The combined results of this study indicate that the nitrate concentrations of springs in the Suwannee River basin have responded to increased nitrogen loads from various sources in the watersheds over the last few decades, however, the responses have been subdued and delayed because the average residence time of groundwater discharging from springs are in the order of decades. (C) 2001 Published by Elsevier Science B.V

Palaeowaters in European coastal aquifers -- the goals and main conclusions of the PALAEAUX project, 2001, Edmunds Wm,
The PALAEAUX project has brought together up-to-date geochemical, isotopic and hydrogeological information on coastal groundwaters across Europe in a transect from the Baltic to the Canary Islands. These data have been interpreted in relation to past climatic and environmental conditions, as well as extending and challenging concepts about the evolution of groundwater near the present day coastlines. Groundwater movement beyond the present coastline as well as emplacement on shore to greater depths (up to 500 m) than allowed by the present-day flow regime has occurred, hence offshore freshwater reserves are inferred in some coastal areas. The main attributes of palaeowaters, in terms of water quality, are their high bacterial purity, total mineralization that is often less than that of modern waters and being demonstrably free of anthropogenic chemicals. However, in the Mediterranean coastal areas, lower recharge leads to higher salinity conditions in both palaeo- and modern waters. Freshwater of high quality originating from different climatic conditions to the present day, when the sea level was much lower, is found at depth beneath the present-day coastline in several countries. Recharge is shown to have been more or less continuous during the past 100 ka, even beneath the ice, as demonstrated by groundwaters from Estonia, having {delta}O values of c. -22%o. However, elsewhere (UK and Belgium) an age gap can be recognized indicating that no recharge took place at the time of the last glacial maximum. Devensian recharge temperatures (soil air temperatures) were some 6{degrees}C colder across Europe than at the present day. The development of aquifers in Europe during the past 50-100 a, by abstraction from boreholes, has generally disturbed flow systems that have evolved over varying geological timescales, especially those derived from the Late Pleistocene and Holocene. Hydrogeophysical logging has demonstrated time and quality stratified aquifers resulting in mixed waters being produced on pumping. A range of specific indicators, including 3H, 3H/3He, 85Kr, chlorofluoro-carbons and pollutants, have been used to recognize the extent to which waters from the modern (industrial) era have penetrated into the aquifers, often replacing the natural palaeogroundwaters. In the coastal regions, many problems for management are identified, including issues relating to quantity and quality of water, seasonal demand, pollution risks and ecosystem damage, requiring a new look at legislation

LUMPED: a Visual Basic code of lumped-parameter models for mean residence time analyses of groundwater systems, 2003, Ozyurt N. Nur, Bayari C. Serdar
A Microsoft Visual Basic 6.0 (Microsoft Corporation, 1987?1998) code of 15 lumped-parameter models is presented for the analysis of mean residence time in aquifers. Groundwater flow systems obeying plug and exponential flow models and their combinations of parallel or serial connection can be simulated by these steady-state models which may include complications such as bypass flow and dead volume. Each model accepts tritium, krypton-85, chlorofluorocarbons (CFC-11, CFC-12 and CFC-113) and sulfur hexafluoride (SF6) as environmental tracer. Retardation of gas tracers in the unsaturated zone and their degradation in the flow system may also be accounted for. The executable code has been tested to run under Windows 95 or higher operating systems. The results of comparisons between other comparable codes are discussed and the limitations are indicated.

LUMPED Unsteady: a Visual Basic code of unsteady-state lumped-parameter models for mean residence time analyses of groundwater systems, 2005, Ozyurt N. Nur , Bayari C. Serdar
A Microsoft Visual Basic 6.0 (Microsoft Corporation, 1987?1998) code of 9 lumped-parameter models of unsteady flow is presented for the analysis of mean residence time in aquifers. Groundwater flow systems obeying plug and well-mixed flow models and their combinations in parallel or serial connection can be simulated by the code. Models can use tritium, tritiugenic He-3, oxygen-18, deuterium, krypton-85, chlorofluorocarbons (CFC-11, CFC-12 and CFC-113) and sulfur hexafluoride (SF6) as the environmental tracers. The executable code runs under all 32-bit Windows operating systems. Details of the code are explained and its limitations are indicated.

Using Multiple Chemical Indicators to Assess Sources of Nitrate and Age of Groundwater in a Karstic Spring Basin, 2005, Katz Brian, Copeland Rick, Greenhalgh Tom, Ceryak Ron, Zwanka Warren,
Human health and ecological concerns have arisen due to a steady increase in nitrate-N concentrations during the past 40 years in Fannin Springs (0.3-4.7 mg/L), a regional discharge point with an average flow of >2.8 m3/second (>100 ft3/second) for water from the karstic Upper Floridan aquifer (UFA). Multiple chemical indicators (major dissolved species, 15N and 18O of nitrate, dissolved gases, 78 pesticides and degradates, and 67 organic compounds typically found in domestic and industrial wastewater) and transient tracers (3H/3He, chlorofluorocarbons [CFCs], sulfur hexafluoride [SF6]) were analyzed in water samples from nine wells along three transects and in spring water to assess groundwater age and potential contaminant sources. Land use is predominantly agricultural (52 percent) and forest (31 percent) in the 320 km2 (124 mi2) spring basin, which was delineated from a potentiometric-surface map of the UFA using high-resolution water-level data. Nitrate-N concentrations were highly variable in the oxic UFA and ranged from <0.02 to 4.7 mg/L. {delta}15N-NO3 values (3.4-9.9 per mil) indicated that nitrate contamination originated from inorganic sources (synthetic fertilizer) and organic sources (manure spreading or waste disposal). Higher nitrate concentrations and the younger age of spring water relative to water from upgradient wells indicate better communication with N sources at the surface. Apparent ages of groundwater correlated positively with well depth (P < 0.05) and were younger in water from wells nearer to the spring (<8 years) compared with other wells (10-50 years). Most transient tracer concentrations were consistent with binary mixing curves representing mixtures of water recharged during the past 10 years and older water (recharged before 1940). Young water mixing fractions ranged from 0.07 to 0.90. Trace levels of herbicides found in groundwater and spring water were indicative of applications for vegetative control in agricultural and other land-use types

Steady- and unsteady-state lumped parameter modelling of tritium and chlorofluorocarbons transport: hypothetical analyses and application to an alpine karst aquifer, 2005, Ozyurt N. N. , Bayari C. S. ,
Determination of a groundwater's mean residence time with the aid of environmental tracers is common in hydrogeology. Many of the lumped parameter (LP) applications used for this purpose have been based on steady-state models. However, the results may be misleading if a steady LP model is used to simulate the environmental tracer transport in an unsteady aquifer. To test this hypothesis, the results of steady and unsteady versions of several LP models were evaluated theoretically and in an alpine karst aquifer case by using tritium, oxygen-18 and chlorofluorocarbons (CFCs). The results reveal that the mean residence times obtained may be significantly different between the steady and unsteady versions of the same model. For the karst aquifer investigated, a serially connected exponential and a plug flow model were run under unsteady conditions. It is shown that outflux calibration with an unsteady model provides a firm basis in evaluating the results of models. An outflux-calibrated unsteady model predicted reasonably the observed series of water isotopes. The calibrated model's CFCs output overpredicts the observed concentrations, probably because of the time lag in the unsaturated zone of the alpine karst aquifer. Copyright (c) 2005 John Wiley & Sons, Ltd

Translating CFC-based piston ages into probability density functions of ground-water age in karst, 2006, Long Andrew J. , Putnam Larry D. ,
SummaryTemporal age distributions are equivalent to probability density functions (PDFs) of transit time. The type and shape of a PDF provides important information related to ground-water mixing at the well or spring and the complex nature of flow networks in karst aquifers. Chlorofluorocarbon (CFC) concentrations measured for samples from 12 locations in the karstic Madison aquifer were used to evaluate the suitability of various PDF types for this aquifer. Parameters of PDFs could not be estimated within acceptable confidence intervals for any of the individual sites. Therefore, metrics derived from CFC-based apparent ages were used to evaluate results of PDF modeling in a more general approach. The ranges of these metrics were established as criteria against which families of PDFs could be evaluated for their applicability to different parts of the aquifer. Seven PDF types, including five unimodal and two bimodal models, were evaluated. Model results indicate that unimodal models may be applicable to areas close to conduits that have younger piston (i.e., apparent) ages and that bimodal models probably are applicable to areas farther from conduits that have older piston ages. The two components of a bimodal PDF are interpreted as representing conduit and diffuse flow, and transit times of as much as two decades may separate these PDF components. Areas near conduits may be dominated by conduit flow, whereas areas farther from conduits having bimodal distributions probably have good hydraulic connection to both diffuse and conduit flow

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