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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That tectokarst is karst formed under the strong influence of tectonic disturbances. the term is indefinite and its use is not generally recommended [20]. synonyms: (french.) tectokarst; (german.) tektonischer karst; (greek.) tektonikon karst; (russian.) karst zon tektoniceskih razlomov; (spanish.) tectokarst; (turkish.) tektonik karst; (yugoslavian.) tektokrs, tektokras, tektokarst.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for fulvic acid (Keyword) returned 8 results for the whole karstbase:
Fluorescence wavelength and intensity variations of cave waters, 1999, Baker A, Genty D,
The fluorescence properties of groundwaters percolating into four cave systems have been monitored over the period 1997-1998. Fluorescence was excited between 220 and 400 nm and the emission measured from 300 to 500 nm using a fluorescence spectrophotometer. Three fluorescence centres were observed; one at the excitation-emission pair of 290-340:395-430 nm, (humic-like, probably fulvic acid), one at 265-280:300-370 nm (protein like) and a less defined region of high fluorescence at 230-280:310-420 nm (humic and/or protein like). The most consistent fluorescence intensity was observed in the excitation-emission pair of 290-340:395-430 nm, attributed to a fulvic acid source. Subtle differences (5%) in the fluorescence excitation and emission wavelength of this fluorescence peak in the groundwater were observed between the four sites, and the fluorescence intensity varied considerably ( x 60) between the four sites. Both the wavelength and the intensity variations in fluorescence are caused by the differences in the vegetation cover, soil type and humification. Data from the most intensely monitored site (Brown’s Folly Mine, England; 9 sample stations, 10-20 days frequency sampling) revealed no spatial variability in the 290-340:395-430 nm (fulvic acid) fluorescence; in contrast time-series analysis suggests that the seasonal variations do occur, with a decrease in the emission wavelength correlating with the first (autumn) peak in fluorescence intensity, and a decrease in the excitation wavelength correlating with a second (winter) fluorescence intensity peak. Results demonstrate the potential of utilising fluorescence wavelength variations in sourcing karst groundwaters, and as a possible palaeoenvironmental proxy of the overlying soil conditions if trapped within the cave speleothems

Seasonal variations in Sr, Mg and P in modern speleothems (Grotta di Ernesto, Italy), 2001, Huang Yiming, Fairchild Ian J. , Borsato Andrea, Frisia Silvia, Cassidy Nigel J. , Mcdermott Frank, Hawkesworth Chris J. ,
Sub-annual variations in trace element chemistry and luminescence have recently been demonstrated from speleothems and offer the potential of high-resolution palaeoclimatic proxies. However, no studies have yet examined microscopic trace element variations in relation to modern cave conditions. In this study, the spatial variations in trace element (Sr, Mg and P) concentrations in speleothems (a stalagmite and a soda straw stalactite) from the alpine Ernesto cave (temperature 6.60.1[deg]C) in a forested catchment in NE Italy have been studied using secondary ion mass spectrometry (SIMS) and compared with environmental parameters and waters in the modern cave. An annual lamination exists in the stalagmite and soda straw stalactite in the form of clear calcite with narrow visible layers, which are UV-fluorescent and interpreted to contain soil-derived humic/fulvic acids washed into the cave during autumn rains. Microanalyses were undertaken of seven annual laminae, probably deposited during the 1960s in the stalagmite, and seven laminae in the 1990s for the stalactite.The analysis results show that Sr consistently has a trough and P, a peak centred on the inclusion-rich layer. Mg shows mainly a negative covariation with Sr in laminae formed in the 1990s, but a positive covariation in the stalagmite formed in 1960s. The spatial scale of the main geochemical variations is the same as that of annual laminae of inclusion-poor and inclusion-rich couplets. Mass balance arguments are used to show that the P is inorganic in form and presumably occurs as individual phosphate ions within the calcite.Most drip waters show limited chemical variations, but a summer peak in trace elements in 1995 and a decrease in Mg/Ca in the following winter are notable. More pronounced covariations in Mg/Ca and Sr/Ca are shown by a site with highly variable drip rates where ratios increase at slow drip rates. The strongest seasonal variations are found in pool waters, where ratios increase reflecting significant Ca removal from the water into the calcite during the winter in response to seasonal PCO2 variations in cave air. Thus, the cave waters' compositions tend to reflect climate conditions, such that Mg/Ca and Sr/Ca are tentatively interpreted to be higher when climate conditions are dry.Combining results from the speleothems and cave water along with the behaviour of each trace species, Mg/Ca variations in the speleothems are considered to reflect their variation in the cave waters, whereas, Sr incorporation is also dependent on precipitation rate, in this case, mainly controlled by temporal variations in PCO2 in the cave (and conceivably, also by inhibitors such as phosphate). P adsorption (a fraction of which is subsequently incorporated within calcite) depends on aqueous phosphate concentration and water flux, both of which should increase during the autumn. Therefore, multiple trace element profiles in speleothems reflect multiple aspects of environment seasonality and conditions, and hence, a calibration against weather records is desirable to establish their palaeoclimatological meaning. The strong annual variation of trace elements, and particularly P, can provide chronological markers for high-resolution studies of other climate proxies, such as stable isotopes

Seasonal changes of fulvic acid, Ca and Mg concentrations of water samples collected above and in the Beke Cave of the Aggtelek karst system (Hungary), 2004, Tatar Eniko, Mihucz Victor G. , Zambo Laszlo, Gasparics Tibor, Zaray Gyula,
Magnesium and Ca concentration ratios, fulvic acid content, total dissolved inorganic carbon (DIC) and pH were determined in seepage water and drip water samples collected during one seasonal cycle between June 2000 and May 2001 above and in the Beke Cave of Aggtelek (Hungary). Seepage water samples were collected at 0.5 and 7 m below ground level from an observation point situated above the cave. Drip water was collected 40 m underground from a group of stalactites. The fulvic acid concentrations were determined by fluorescence spectrometry after pre-concentration on a XAD-8 chromatographic column. Calcium and Mg concentrations were measured by inductively coupled plasma atomic-emission spectrometry. DIC was determined with a CO2 - selective electrode. DIC values increased and the fulvic acid concentrations and Mg and Ca concentration ratios, generally, decreased with depth. The highest flux of fulvic acid was observed in spring. The fulvic acid flux increased by a factor of 2.6-3.6 and 1.4 for groundwater and drip water, respectively, compared with those registered in the winter samples. The variations in the Ca, Mg and fulvic acid concentrations of the seepage and drip water samples relate to the variable drip rate. The results revealed that there is a strong correlation between the daily average surface temperature, daily amount of precipitation and drip water rate registered in the cave

Study of soil leachates in doline above the Beke Cave, Hungary, 2004, Tatar E. , Mihucz V. G. , Tompa K. , Poppl L. , Zaray G. , Zambo L. ,
Fulvic acid, Ca and Mg concentrations as well as dissolved inorganic carbon (DIC), pH and electric conductivity values of soil solutions which resulted from injecting bidistilled water onto glass columns filled with different soils (black rendzina, brown rendzina, red clayey rendzina, red clay) characteristic of the Aggtelek karst system (NE Hungary), were determined. Identification and determination of fulvic acid were achieved by size exclusion chromatography (SEC) and adsorption chromatography, respectively, with fluorescent spectrometric detection. The Ca and Mg concentration of the samples was determined by applying an inductively coupled plasma atomic emission spectrometric (ICP-AES) method. DIC-expressed in CO2 concentration values-was determined by using a CO2 selective electrode. According to the SEC analysis, the apparent molecular weight of the fulvic acids of the samples were between 500 and 1600 Da. The fulvic acid concentration values of the percolated water samples decreased in function of the soils investigated as follows: black rendzina>brown rendzina>red clayey rendzina>red clay, which is in concordance with the organic matter content of these types of soils. The results obtained for fulvic acid, Ca and Mg concentrations as well as for DIC, pH and electric conductivity of the water samples collected from the column filled with red clay were in good agreement with those of a seepage water sample collected from an observation station built in red clay above the Beke Cave (Aggtelek). Since the artificially prepared red clay column was exposed to the same temperature and humidity conditions like red clay of the sampling site, this method seems to be suitable for modelling infiltration of fulvic acid and metals from red clay into seepage water under laboratory conditions. (C) 2003 Elsevier B.V. All rights reserved

Rapid biotic molecular transformation of fulvic acids in a karst aquifer, 2007, Einsiedla Florian , Hertkornb Norbert, Wolfa Manfred, Frommbergerb Moritz, Schmittkopplinb Philippe, Kochc Boris P.

HYDROGEOLOGICAL FUNCTIONING OF A KARST AQUIFER DEDUCED FROM HYDROCHEMICAL COMPONENTS AND NATURAL ORGANIC TRACERS PRESENT IN SPRING WATERS. THE CASE OF YEDRA SPRING (SOUTHERN SPAIN), 2010, Mudarra M. , Andreo B.
The major chemical parameters, TOC and natural fluorescence of yedra spring, Malaga province, southern Spain were monitored from April 2008 to March 2009. The electrical conductivity and the concentrations of most major ions decreased following recharge periods. The TOC and NO3, representing tracers from the soil that infiltrate through the unsaturated zone, were found to vary inversely with the Mg2+ content, which is a natural indicator of groundwater residence time. Furthermore, a strong, direct relation was found between TOC and the natural fluorescence associated with humic and fulvic acids. Both parameters respond similarly to rainfall events, exhibiting significant increases during recharge followed by reductions during recession. This relation means that TOC mainly originates from organic acids. The results document rapid infiltration processes with a lag of less than one day following rainfall, which is typical of a karst aquifer with conduit flow, rapid drainage and limited natural regulation. The combined use of conventional hydrochemical parameters and natural organic tracers facilitates aquifer characterization and validates the vulnerability to contamination.

Organic matter of fossil origin in the amberine speleothems from El Soplao Cave (Cantabria, Northern Spain), 2012, Gzquez Fernando, Jose Maria Calaforra, Fernando Rull, Paolo Forti, And Antonio Garcacasco.

Unusual amberine-coloured speleothems were recently found in El Soplao Cave (Cantabria, Spain). Chromophore elements such as Fe, Mn, Cd, Co or Ti were not present in significant quantities. Rather, our data show that their colour comes from leachates of fossilized organic material hosted in the carbonaceous Urgonian facies of the host rock. These leachates are related to the Cretaceous amber deposit that has been recently discovered in the vicinity of El Soplao Cave. The presence of humic and fulvic acids of fossil origin were confirmed by IR and Raman spectroscopic analysis of the carbonaceous strata and the speleothems. In addition, the mineralogy of the amberine speleothems was studied. Alternating bands made of calcite and aragonite reveal that periods of humidity and aridity occurred within the cave during the speleothem genesis.


Speleothems: General Overview, 2012, White, William B.

Speleothems are secondary mineral deposits formed in caves by flowing, dripping, or seeping water. The most commonly occurring minerals are calcite, aragonite, and gypsum although many other minerals have been found in speleothems. The shapes of speleothems are determined by a competition between the dynamics of the water and the crystal growth habits of the constituent minerals. Stalactites, stalagmites, flowstone, and other speleothems deposited from dripping for flowing water take shapes dictated by the details of the flow behavior. Helictites, anthodites, and gypsum flowers formed from seeping water and various pool deposits take shapes dictated by the habit of crystal growth. Tan, orange, and brown colors common to calcite speleothems and also their luminescence under ultraviolet light is due to inclusion of humic and fulvic acid from overlying soils. Speleothems are also found in lava tubes.


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