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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That pressure cell is a pressure measuring and transducing device [16].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for river-water (Keyword) returned 14 results for the whole karstbase:
Phreatische Fauna in Ljubljansko polje (Ljubljana-Ebene, Jugoslavien); ihre oekologische Verteilung und zoogeographische Beziehungen., 1981,
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Sket Boris, Velkovrh Franci
The phreatic basin of Ljubljansko polje (polje = plain, field) recharges its water supply mainly from the Sava river-bed and at a few other locations where connections with karstic subterranean waters might exist and only up to 15% from precipitation. An important zone of infiltration in the river-bed is the bottom and not the bank which is to a large extent watertight due to organic debris (rests of Sphaerotilus e.g.). The main water-body moves about 10 m/day, there are however some local jets with far higher speeds. Yearly amplitudes of water temperatures are high near the river but in the centre of the plain only a couple of centigrades. Oxygen saturation is in the open river-water 100%, dropping to 40-60% just 1 m into the phreatic. True stygopsammal animals are represented here only by a few species and specimen in spite of the fact, that the interstices in the gravel are mostly filled with finer sediments. Remarkable is also the scarcity of Nematodes and the near absence of Acarina (compare with Danielopol 1976). Only a few specimen of the river benthos (Chironomidae, Tipulidae, Leuctra supp., Baets spp.) penetrate the interstitial water (compare with Ruffo 1961, Danielopol 1976) and only Naididae are more frequent there. However, many epigean animals occur in interstitial waters in the periodically flooded gravel-banks; one can explain this with oscillations of the water level. Some epigean animals (creno- and troglophilic) are quite regularly represented in the phreatic near the river, but have not been found in the river-bed. The distribution of phreatic species within the studied water-body seems to be controlled mainly by the presence of food supplies and the consequent competition among species. The same is true for the speed of the water current and some other factors which are less easily defined. The characteristics of the substratum as well as O2-saturation and other characteristics of the water seem to have little influence on the fauna. The energetically (food-) rich neighbourhood of the river is inhabited by a number of species in quite dense populations while the central parts of the phreatic water body exhibit a great poverty of species and of specimen. However, some species live here, which don't occur in the presence of larger food supplies and of greater competition (Niphargus serbicus). The higher current speed seems to prevent settlement of some species (Cyclopoida, Proasellus deminutus) while some are bound to such habitats (Proasellus vulgaris). Some species exhibit a high degree of euryvalency inside the stygopsephale habitats (Niphargus longidactylus e.g.), while some are highly specialized. Some of them form dense populations (comparatively dense even in energetically poor places) while others exhibit even in most favourable conditions very low densities (Niphargus jovanovici multipennatus). The present fauna is zoogeographically very diverse. Some species are distributed throughout Europe; some reach from Central Europe to the borders of Dinaride Karst (Bogidiella albertimagni) and some even penetrate it (Trichodrilus pragensis, Acanthocyclops kiefer). Bogidiella semidenticulata. Niphargus pectinicauda, Hadziella deminuta seem to be limited to the higher reaches of the Sava River. All of the above mentioned animals live regularly in interstitial waters and only sporadically in karstic hypogean waters. Niphargus stygius is here the only animal of a certainly karstic provenience; inside the plain it is limited to a completely special habitat. It is very likely that the entire Proasellus-deminutusgroup has developed in interstitial waters of larger plains which are in contact with karstic areas; some species penetrated from the plains into the karst rather than the reverse. To the contrary (judging from the distribution of the genera) karstic waters seem to be the cradle of Hauffenia and Hadziella. Such a sharp delimitation between cave- and interstitial fauna resp. in this area is very noteworthy. Both faunas live here in abundance and in close contact. It is very probable that particularly high competition and specialization of both faunas, caused by their richness and diversity, prevent mixing of species.

Geochemistry and water dynamics: Application to short time-scale flood phenomena in a small Mediterranean catchment .1. Alkalis, alkali-earths and Sr isotopes, 1997,
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Benothman D, Luck Jm, Tournoud Mg,
We report major, trace elements and Sr isotope data for water samples taken regularly during a four-day-long September flood of a Mediterranean river, the Vene (Herault, S. France). The objective is to combine all these data into a dynamic model that describes the origin(s) and movements of waters and their loads. This river drains the runoff from a small, mainly carbonate, partly karstified watershed with Miocene and Jurassic lithologies. The watershed is also impacted by both agricultural and urban activities. Both the dissolved and the particulate loads were analyzed. Concentrations of the dissolved components show major remobilization of almost all elements during the first few hours of the flood (water treatment plants and aerosol scavenging), followed by a sharp concentration decrease. Some major species return to their previous summer values (Ca, HCO3) while others reach low 'background' levels (Na, K, Cl, SO4). Some trace elements (Rb, Sr, Cs) show similar behaviour but (Ba) appears somewhat unaffected. Trace element concentrations and ratios define two main periods (three in the suspended particulate matter). Ratios do not allow distinguishing between the three main sources for the dissolved load in the first period (Miocene, Jurassic, water treatment plants), but clearly show the Jurassic karst influence later on. The Sr-87/Sr-86 Of the suspended particulate matter is more variable and more radiogenic than in the dissolved phase. Variations in concentration ratios and Sr isotope composition in particulates indicate the large and variable contribution of Miocene silicates with some carbonate. However, there is a need for another component with [Rb]/[Sr] higher than bedrocks, internal or external to the watershed, possibly due to differential erosion. Dissolved Ca and Mg fluxes during the flood were calculated at 0.26 ton and 0.029 ton/km(2), respectively. Even though the carbonate nature of the watershed restricts variability in Sr isotope composition in the dissolved load, we distinguish several endmembers: seawater(approximate to marine rain), Miocene marls, Jurassic limestones, water treatment plants (and possibly another attributable to fertilizers). Combined with major and trace element variational Sr isotope fluctuations indicate time-varying proportions of different water endmembers at the outflow and suggest a general dynamic model. Based on PCA (principal component analysis), a 3D representation allows to visualize the geochemical evolution of the Vene waters. In particular, Sr isotopes clearly indicate that the inflow of karstic waters during the flood was not continuous but occurred as a series of marked oscillations between flowing waters with chemical signature of Miocene lithologies and increasing flushes of deeper waters that interacted with Jurassic lithologies. (C) 1997 Elsevier Science B.V

River water intrusion to the unconfined Floridan Aquifer, 1998,
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Kincaid Todd R. ,
Rapid infiltration of river water into unconfined parts of the Floridan aquifer represents a significant component of subsequent ground-water discharge in regions where the aquifer is dissected by surface streams. A two-year investigation of the Devil's Ear cave system, an extensive saturated conduit network in the Floridan aquifer which underlies a 1.5-km reach of the Santa Fe River in north-central Florida, revealed that there is an appreciable and rapid exchange of water between the river and the underlying Floridan aquifer. Natural tracers Radon-222 ( 222 Rn) and delta 18 O were used to quantify these exchanges. Cave diving was employed to collect 50 water samples which were analyzed for tracer content and to observe water clarity conditions within the saturated karst conduits as far as 1.2 km from the cave entrance. 222 Rn concentrations measured in the cave system revealed three distinct zones where river water is rapidly intruded into the Floridan aquifer. A two-component mixing model was used to quantify the intruded river water that was found to account for as much as 62 percent of the discharge at Devil's Ear spring. Observations of diminished water clarity in the cave system following large precipitation events in the highland provinces of the Santa Fe River basin indicate that river water intrusion to the aquifer can occur in as little as one or two days. The results of this investigation imply that, in regions such as the western Santa Fe River basin, there can be no clear distinction between ground and surface waters and intruded river water provides a significant vehicle for contamination of the unconfined Floridan aquifer

Changes in the isotopic and chemical composition of ground water resulting from a recharge pulse from a sinking stream, 1998,
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Katz B. G. , Catches J. S. , Bullen T. D. , Michel R. L. ,
The Little River, an ephemeral stream that drains a watershed of approximately ss km(2) in northern Florida, disappears into a series of sinkholes along the Cody Scarp and flows directly into the carbonate Upper Floridan aquifer, the source of water supply in northern Florida. The changes in the geochemistry of ground water caused by a major recharge pulse from the sinking stream were investigated using chemical and isotopic tracers and mass-balance modeling techniques, Nine monitoring wells were installed open to the uppermost part of the aquifer in areas near the sinks where numerous subterranean karst solution features were identified using ground penetrating radar. During high-flow conditions in the Little River, the chemistry of water in some of the monitoring wells changed, reflecting the mixing of river water with ground water. Rapid recharge of river water into some parts of the aquifer during high-flow conditions was indicated by enriched values of delta O-18 and delta deuterium (-1.67 to -3.17 per mil and -9.2 to -15.6 per mil, respectively), elevated concentrations of tannic acid, higher (more radiogenic) Sr-87/Sr-86 ratios, and lower concentrations of Rn-222, silica, and alkalinity compared to low-how conditions. The proportion of river water that mixed with ground water ranged from 0.10 to 0.67 based on binary mixing models using the tracers O-18, deuterium, tannic acid, silica, Rn-222, and Sr-87/Sr-86. On the basis of mass-balance modeling during steady-state how conditions, the dominant processes controlling carbon cycling in ground water are the dissolution of calcite and dolomite in aquifer material, and aerobic degradation of organic matter. (C) 1998 Elsevier Science B.V. All rights reserved

Oxidation of organic matter in a karstic hydrologic unit supplied through stream sinks (Loiret, France), 1998,
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Alberic P, Lepiller M,
The aim of this paper is to appraise the ability of the oxidation of riverine organic matter in the control of limestone dissolution, in a karst network. Biogeochemical processes during infiltration of river water into an alluvial aquifer have already been described for an average flow velocity of 4-5 m d(-1) (Jacobs, L. A., von Gunten, H. R., Keil, R, and Kuslys, M. (1988) Geochemical changes along a river-groundwater infiltration flow path: Glattfelden, Switzerland. Geochim. Cosmochim. Acta 52, 2693-2706; Von Gunten, H. R., Karametaxas, G., Krahenbuhl, U., Kuslys, M., Giovanoli R., Hoehn E. and Keil R. (1991) Seasonal biogeochemical cycles in riverborne groundwater. Geochim. Cosmochim. Acta 55, 3597-3609; Bourg, A. C. M. and Bertin, C. (1993) Quantitative appraisal of biogeochemical chemical processes during the infiltration of river water into an alluvial aquifer. Environ. Sci. Technol. 27, 661-666). Karstic drainage networks, such as in the River Loire-Val d'Orleans hydrologic system (Fig. 1), make possible flow velocities up to 200 m h(-1 a) and provide convenient access to different water samples several tens of km apart, at both extremities of the hydrologic unit (Chery, J.-L. (1983) Etude hydrochimique d'un aquifere karstique alimente par perte de cours d'eau (la Loire): Le systeme des calcaires de Beauce sous le val d'Orleans. These, Universite d'Orleans; Livrozet, E. (1984) Influence des apports de la Loire sur la qualite bacteriologique et chimique de l'aquifere karstique du val d'Orleans. These, Universite d'Orleans). Recharge of the karstic aquifer occurs principally from influent waters from stream sinks, either through coarse alluvial deposits or directly from outcrops of the regional limestone bedrock (Calcaires de Beauce). Recharge by seepage waters From the local catchment basin is small (Zunino, C., Bonnet, M. and Lelong, F. (1980) Le Val d'Orleans: un exemple d'aquifere a alimentation laterale. C. R. somm. Soc. Geol. Fr. 5, 195-199; Gonzalez R. (1992) Etude de l'organisation et evaluation des echanges entre la Loire moyenne et l'aquifere des calcaires de Beauce. These, Universite d'Orleans) and negligible in summer. This karstic hydrologic: system is the largest in France in terms of flow (tens to hundreds of m(3)/s) and provides the main water resource of the city of Orleans. Chemical compositions of influent waters (River Loire) and effluent waters (spring of the river Loiret) were compared, in particular during floods in summer 1992 and 1993 (Figs 2-4). Variation of chloride in the River Loire during the stream rise can be used as an environmental tracer of the underground flow (Fig. 2). Short transit times of about 3 days are detectable (Fig, 2) which are consistent with earlier estimations obtained with chemical tracers (Ref. in Chery, J.-L. (1983) These, Universite d'Orleans). Depending on the hydrological regime of the river, organic carbon discharge ranges between 3-7 and 2-13 mg/l for dissolved and particulate matter respectively (Fig. 3). Eutrophic characteristics and high algal biomasses are found in the River Loire during low water (Lair, N. and Sargos, D. (1993) A 10 year study at four sites of the middle course of the River Loire. I - Patterns of change in hydrological, physical and chemical variables in relation to algal biomass. Hudroecol. Appl. 5, 1-27) together with more organic carbon rich suspended particulate matter than during floods (30-40 C-org % dry weight versus 5-10%). Amounts of total organic carbon and dissolved oxygen (Fig. 3) dramatically decrease during the underground transport, whereas conversely, dissolved calcium, alkalinity and inorganic carbon increase (Fig. 4). Anoxia of outflows map start in April. Dissolution of calcium carbonates along the influent path outweighs closed system calcite equilibrium of inflow river waters (Table 3). The impact of organic matter oxidation on calcite dissolution may be traced by variations of alkalinity and total carbonates in water. Following, Jacobs, L. A., von Gunten, H. R., Keil, R. and Kuslys, M. (1988) Geochemical changes along a river-groundwater infiltration flow path: Glattfelden, Switzerland. Geochim. Cosmochim. Acta 52, 2693-2706), results are shown graphically (Fig. 5). Extent of reactions is controlled by the consumption of dissolved O-2 and nitrate for organic matter oxidation and by the release of Ca2 for calcite dissolution (Table 2). The karstic network is considered to behave like a biological reactor not exchanging with the atmosphere, with steady inhabitant microbial communities (Mariotti A., Landreau A, and Simon B. (1988) N-15 isotope biogeochemisrry and natural denitrification process in groundwater: Application to the chalk aquifer of northern France. Geochim. Cosmochim. Acta 52, 1869-1878; Gounot, A.-M. (1991) Ecologie microbienne des eaux ei des sediments souterrains. Hydrogeologie, 239-248). Thus, energy requirements only are considered, not carbon assimilation. Moreover, there is no necessity to invoke any delay for nitrification enhancement, as observed elsewhere, after waste water discharge into the river (Chesterikoff, A., Garban, B., Billen, G. and Poulin, M. (1992) Inorganic nitrogen dynamics in the River Seine downstream from Paris (France). Biogeochem. 17, 147-164). Main microbial processes are assumed to be aerobic respiration, nitrification and denitrification. Reactions with iron and manganese, real but not quantitatively important, were neglected. Sulphate reduction and methane formation, certainly not active, were not considered. Denitrification, which is suggested by low nitrate and ammonium concentrations and anoxia in the outflow, is known to be rapid enough to be achieved in a short time (Dupain, S. (1992) Denitrification biologique heterotrophe appliquee au traitement des eaux d'alimentation: Conditions de fonclionnement et mise au point d'un procede. These, Universite Claude Bernard, Lyon). Reaction are somewhat arbitrary but conform to general acceptance (Morel, M. M. and Hering, J. G. (1993) Principles and Applications of Aquatic Chemistry. Wiley, New York). Anaerobic ammonium oxidation (Mulder A., van de Graaf, A. A., Robertson, L: A. and Kuenen, J. G. (1995) Anaerobic ammonium oxidation discovered in a denitrifying fluidized bed reactor. FEMS Microbiol. Ecol. 16, 177-184). although possible, was not considered. In fact, C/N ratio of the reactive organic matter has only mild repercussions on the results; i.e. in the same range as the analytical errors for alkalinity and total carbonates. The objective was simply to roughly confront characteristics of outflowing waters and the calculation. Respective roles of aerobes and denitrifiers, for instance, are not certain. Several periods during low water or floods were selected with various ranges for calcium dissolution or nitrate and oxygen concentrations. The result is that in most cases simulation and data are in reasonable accordance (Fig. 5). Amounts of organic matter in River Loire are generally sufficient to sustain the process (Table 3. Particulate organic matter is probably the most reactive. The balance of oxidation of organic matter indicates that about 65 mu g C-org/l.h are oxidized during the transport without much variation with the river regime or organic discharge. It is concluded that limestone dissolution is directly dependent on organic matter oxidation, but variation occurs (7-29 mg CuCO3/l) with the level of bases that can be neutralized in the River Loire water. (C) 1998 Elsevier Science Ltd. All rights reserved

Geology and evolution of lakes in north-central Florida, 1999,
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Kindinger J. L. , Davis J. B. , Flocks J. G. ,
Fluid exchange between surficial waters and groundwater in karst environments, and the processes that control exchange, are of critical concern to water management districts and planners, High-resolution seismic data were collected from 30 lakes of north-central Florida. In each case study, lake structure and geomorphology were controlled by solution and/or mechanical processes. Processes that control lake development are twofold: (1) karstification or dissolution of the underlying limestone, and (2) the collapse, subsidence, or slumping of overburden to form sinkholes. Initial lake formation is directly related to the karst topography of the underlying host limestone. Case studies have shown that lakes can be divided by geomorphic types into progressive developmental phases: (1) active subsidence or collapse phase (young); (2) transitional phase (middle age); (3) baselevel phase (mature); and (4) polje (drowned prairie) - broad flat-bottom that have one or all phases of sinkhole. Using these criteria, Florida lakes can be classified by size, fill, subsurface features, and geomorphology

Hydrochemical evidence for mixing of river water and groundwater during high-flow conditions, lower Suwannee River basin, Florida, USA, 1999,
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Crandall Ca, Katz Bg, Hirten Jj,
Karstic aquifers are highly susceptible to rapid infiltration of river water, particularly during periods of high flow. Following a period of sustained rainfall in the Suwannee River basin, Florida, USA, the stage of the Suwannee River rose from 3.0 to 5.88 m above mean sea level in April 1996 and discharge peaked at 360 m(3)/s. During these high-now conditions, water from the Suwannee River migrated directly into the karstic Upper Floridan aquifer, the main source of water supply for the area. Changes in the chemical composition of groundwater were quantified using naturally occurring geochemical tracers and mass-balance modeling techniques. Mixing of river water with groundwater was indicated by a decrease in the concentrations of calcium, silica, and Rn-222; and by an increase in dissolved organic carbon (DOC), tannic acid, and chloride, compared to low-flow conditions in water from a nearby monitoring well, Wingate Sink, and Little River Springs. The proportion (fraction) of river water in groundwater ranged from 0.13 to 0.65 at Wingate Sink and from 0.5 to 0.99 at well W-17258, based on binary mixing models using various tracers. The effectiveness of a natural tracer in quantifying mixing of river water and groundwater was related to differences in tracer concentration of the two end members and how conservatively the tracer reacted in the mixed water. Solutes with similar concentrations in the two end-member waters (Na, Mg, K, Cl, SO4, SiO2) were not as effective tracers for quantifying mixing of river water and groundwater as those with larger differences in end-member concentrations (Ca, tannic acid, DOC, Rn-222, HCO3)

Natural water softening processes by waterfall effects in karst areas, 2000,
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Zhang D. D. , Peart M. , Zhang Y. J. , Zhu A. , Cheng X. ,
The reduction of water hardness, which occurs at waterfalls on rivers in karst areas, is considered to be a result of the waterfall effects. These consist of aeration, jet-flow and low-pressure effects. Waterfall effects bring about two physical changes in river water: an increase in the air-water interface and turbulence. A series of experiments was designed and implemented in order to investigate whether these effects and associated physical changes may cause a reduction of water hardness. From an experiment involving the enlargement of interface area, the plot of air-water interface areas against conductivity revealed that the higher the air-water interface, the more rapidly conductance declines (and Ca2 is precipitated). A bubble producer was designed and used to simulate bubbles that are produced by aeration and low-pressure effects and a faster decline of water hardness was observed at the location with bubbles in this experiment. When a supersaturated solution was passed through a jet-stream producer, a rapid reduction of water hardness and an increase of pH appeared. Field measurements were used to support the laboratory experiments. Work on the Ya He River and at the Dishuiyan Waterfalls revealed that places with aeration had the quickest hardness reduction and the highest average rate of calcite deposition

Influence of contaminated Vistula River water on the groundwater entering the Zakrzowek limestone quarry, Cracow region, Poland, 2000,
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Motyka J. , Postawa A. ,
Chemical composition of water inflows in the Zakrzowek quarry, developed in fractured and karstified Upper Jurassic limestones, is controlled by infiltration of polluted water from the Vistula River and by infiltrating meteoric water. The river water TDS value is 2.5 g/dm(3). The quarry waters have 0.6-2.0 g/dm(3) TDS. Highly mineralised waters belong to Cl-Na type. With decreasing TDS the percentage of sulphates, calcium, magnesium and hydrocarbonates increases. This seems to result from various processes including dilution of polluted river water, leaching of aquifer rocks, and ion exchange. The transfer time of river water to the quarry is about 100-120 days. Concentration of contaminants contained in the river water declines during the migration through limestones to the quarry

Timescales for nitrate contamination of spring waters, northern Florida, USA, 2001,
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Katz B. G. , Bohlke J. K. , Hornsby H. D. ,
Residence times of groundwater, discharging from springs in the middle Suwannee River Basin, were estimated using chlorofluorocarbons (CFCs), tritium ((3) H), and tritium/helium-3 (H-3/He-3) age-dating methods to assess the chronology of nitrate contamination of spring waters in northern Florida. During base-flow conditions for the Suwannee River in 1997-1999, 17 water samples were collected from 12 first, second, and third magnitude springs discharging groundwater from the Upper Floridan aquifer. Extending age-dating techniques, using transient tracers to spring waters in complex karst systems, required an assessment of several models [piston-flow (PFM), exponential mixing (EMM), and binary-mixing (BMM)] to account for different distributions of groundwater age. Multi-tracer analyses of four springs yielded generally concordant PFM ages of around 20 2 years from CFC- 12, CFC- 113, H-3, and He-3. with evidence of partial CFC- 11 degradation. The EMM gave a reasonable fit to CFC- 113, CFC- 12. and H-3 data, but did not reproduce the observed He-3 concentrations or H-3/He-3 ratios, nor did a combination PFM-EMM. The BMM could reproduce most of the multi-tracer data set only if both endmembers had H-3 concentrations not much different front modern values. CFC analyses of 14 additional springs yielded apparent PFM ages from about 10 to 20 years from CFC- 113, with evidence of partial CFC- 11 degradation and variable CFC-12 contamination. While it is not conclusive, with respect to the age distribution within each spring, the data indicate that the average residence times were in the order of 10-20 years and were roughly proportional to spring magnitude. Applying similar models to recharge and discharge of nitrate based on historical nitrogen loading data yielded contrasting trends for Suwanee County and Lafayette County. In Suwance County, spring nitrate trends and nitrogen isotope data were consistent with a peak in fertilizer input in the 1970s and a relatively high overall ratio of artificial fertilizer/manure whereas in Lafayette County, spring nitrate trends and nitrogen isotope data were consistent with a more monotonic increase in fertilizer input and relatively low overall ratio of artificial fertilizer/manure. The combined results of this study indicate that the nitrate concentrations of springs in the Suwannee River basin have responded to increased nitrogen loads from various sources in the watersheds over the last few decades, however, the responses have been subdued and delayed because the average residence time of groundwater discharging from springs are in the order of decades. (C) 2001 Published by Elsevier Science B.V

Physical Mechanisms of River Waterfall Tufa (Travertine) Formation, 2001,
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Zhang David Dian, Zhang Yingjun, Zhu An, Cheng Xing,
Waterfall tufa is widely distributed around the world, especially in tropical and subtropical karst areas. In these areas river water is generally supersaturated with respect to calcite, and the precipitation occurs mainly at waterfall and cascade sites. Development of waterfall tufa has been described as simply being the result of water turbulence. We believe, however, that three physical effects can lead to tufa deposition at waterfall sites: aeration, jet-flow, and low-pressure effects. The three physical effects are induced by two basic changes in the water: an accelerated flow velocity, and enlargement of the air-water interface area. These two changes increase the rate of CO2 outgassing and the SIc, so that a high degree of supersaturation is achieved, which then induces calcite precipitation. These 'waterfall effects' have been simulated in laboratory and field experiments, and each of them can accelerate, or trigger, calcite precipitation. Field measurements of river water chemistry also show that tufa deposition occurred only at waterfall sites. In these experiments and observations, waterfall effects play the most important role in triggering and accelerating CO2 outgassing rates. Field and laboratory observations indicate that plants and evaporation also play important roles in tufa formation. Growth of algae and mosses on tufa surfaces can provide substrates for calcite nucleation and can trap detrital calcite, accelerating tufa deposition. However, the prerequisite for such deposition at waterfall sites is a high degree of supersaturation in river water, which is mainly caused by waterfall effects. Evaporation can lead to supersaturation in sprays and thin water films at a waterfall site and cause the precipitation of dissolved CaCO3, but the amount of such deposition is relatively small

Isotopic compositions of strontium in river water of Guizhou karst areas, China, 2001,
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Han G. L. , Liu C. Q. ,
We have carried out a study on the variation of strontium isotope composition of river waters, Wujiang and Yuangjiang River, in karst areas of Guizhou Province, China. The results obtained permit us to characterize the geochemistry of the river draining karst terrain and obtain a better understanding of main controls of catchment geology, chemical weathering of different rocks, and evaluate impact of human activities on the environment. The isotopic ratios of dissolved Sr in all rivers are between Sr-87/Sr-86 = 0.7077 and 0.7110, totally lower than the weighted average of Sr-87/Sr-86 = 0.7119 for the world large rivers. The Wujiang River waters have Sr concentrations from 1.0 to 6.1 mu mol/L, while the Yuanjiang River waters have much lower Sr concentrations ranging from 0.28 to 1.3 mu mol/L. Most of the river waters from the Wujiang river are characterized by low Ca/Sr and Mg/Sr, and Sr-87/Sr-86 ratios, in which a majority of river waters are of Sr-87/Sr-86 ratios lower than the average Sr isotope ratio (Sr-87/Sr-86 = 0.709) of present seawater. The higher Sr-87/Sr-86 ratios are observed in the river waters in the lower reach of the Wujiang River, where the lithology is dominated by detrital rocks and dolomite. The water from Yuanjiang River show higher Ca/Sr, Mg/Sr and Sr-87/Sr-86 ratios due to weathering of silicates, as compared to the river waters from Wujiang river

Analysis of the exchange of groundwater and river water by using Radon-222 in the middle Heihe Basin of northwestern China, 2004,
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Wu Y. , Wen X. , Zhang Y. ,

Natural and EDTA-complexed lanthanides used as a geochemical probe for aquifers: a case study of Orleans valley's alluvial and karstic aquifers, 2005,
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Borgne Fl, Treuil M, Joron Jl, Lepiller M,
The transit of chemical elements within the different parts of Orleans valley's aquifer is studied by two complementary methods. Those methods rely on the fractionation of lanthanides (Ln) during their migration in natural waters. The first method consists in studying natural lanthanides patterns within the watershed, at its entries and exits. The second one lies on multi-tracer experiments with Ln-EDTA complexes. This work is completed through an observation network consisting of 52 piezometers set on a sand and gravel quarry, and the natural entries and exits of the aquifer. Orleans valley's aquifer, which is made of an alluvial watershed lying on a karstic aquifer, is mainly fed by the Loire river via a large karstic network. At the entries of the aquifer (Loire river at Jargeau), the Ln concentrations in the dissolved fraction (< 0,22 {micro}m) vary with the flow of the river. During floods, Loire river waters display bulk continental crust-like Ln compositions with a slight enrichment in heavy Ln from Dy to Lu. When the Loire river flow becomes low level, the crust-normalised Ln patterns show a depletion in light Ln whereas Lu concentrations remain identical. The same evolution spatially occurs between the entries and exits of the karstic network. Spring waters are depleted in light Ln relative to the Loire river whereas heavy Ln (Yb, Lu) remain constant during transit. Furthermore, the depletion in light Ln increases with the distance between entries and exits. Tracer experiments using EDTA-complexed Ln within and between the alluvial and calcareous parts of the watershed have shown that complexed Ln are fractionated across all these geological strata. The recoveries of tracers always follow the order light Ln < heavy Ln. Moreover, both sediments analyses and filtering experiments at a porosity of 0,02 {micro}m show that, in the presence of EDTA, Ln adsorb onto sediments and colloids in the order light Ln > heavy Ln. On the other hand, the filtration of alluvial groundwater with high colloids content induces no significant Ln fractionation when the solution contains no strong chelating agent. Hence, the transit of natural and artificial Ln in Orleans valley aquifer can be explained by two complementary processes. (1) Decanting/filtering or, on the opposite, stirring of colloids. Those processes induce no important Ln fractionation. (2) Exchanges of Ln between solute complexes, colloids and sediments due to the presence of strong chelating agents. Those exchanges fractionate the Ln in the order of their stability constants. Considering the natural Ln fractionation that occurs in the Loire river and in the studied aquifer, the carbonates, the stability constants of which follow the order light Ln < heavy Ln, are the best candidates as natural strong chelating agents. From the hydrodynamic point of view, both tracer experiments and natural Ln concentrations show that the transfer of elements within the alluvial watershed is pulsed by the Loire river movements. During an ascent phase, the elements migrate away from and perpendicularly to the karstic channels direction. During the river descent, horizontal flows are quasi absent and migrations are mainly vertical from the alluvia down to the calcareous part of the aquifer. Due to those hydrodynamic characteristics, alluvia and non fissured limestone have a high dynamic confining capacity. Elements with high affinity for solid or colloidal phases (e.g. light Ln) have an increased confining capacity in the whole aquifer, by sorption and colloid filtration within the alluvia and at the alluvial-calcareous interface, and by colloid decanting within the karstic channels. Overall, this model combines two components. The first one, hydrodynamical, results from the repartition of the loads pulsed by river Loire through the karst. The second one physico-chemical, results from the element distribution mainly controlled by colloide/solute complexes exchange coefficients

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