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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That annulus is the annular space between drill pipe and casing or between casing and the borehole wall [16].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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What is Karstbase?



Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
See all featured articles from other geoscience journals

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Your search for evaporites (Keyword) returned 133 results for the whole karstbase:
Showing 16 to 30 of 133
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Cathro Dl, Warren Jk, Williams Ge,
The Late Ordovician-Early Silurian Mallowa Salt of the Carribuddy Group, Canning Basin, north-west Australia, is the largest halite deposit known in Australia, attaining thicknesses of 800 m or more within an area of approximately 200 000 km2. Study of 675 m of drill core from BHP-Utah Minerals' Brooke No. 1 well in the Willara Sub-basin indicates that the Mallowa Salt accumulated within a saltern (dominantly subaqueous evaporite water body) that was subject to recurrent freshening, desiccation and exposure. Textures and bromine signatures imply a shallow water to ephemeral hypersaline environment typified by increasing salinity and shallowing into evaporitic mudflat conditions toward the top of halite-mudstone cycles (Type 2) and the less common dolomite/anhydrite-halite-mudstone cycles (Type 1). The borate mineral priceite occurs in the capping mudstones of some cycles, reinforcing the idea of an increasing continental influence toward the top of mudstone-capped halite cycles. The rock salt in both Type 1 and Type 2 cycles typically comprises a mosaic of large, randomly orientated, interlocking halite crystals that formed during early diagenesis. It only partially preserves a primary sedimentary fabric of vertically elongate crystals, some with remnant aligned chevrons. Intraformational hiati, halite karst tubes and solution pits attest to episodic dissolution. Stacked Type 2 cycles dominate; occasional major recharges of less saline, perhaps marine, waters in the same area produced Type 1 cycles. The envisaged saltern conditions were comparable in many ways to those prevailing during the deposition of halite cycles of the Permian Salado Formation in New Mexico and the Permian San Andres Formation of the Palo Duro Basin area in Texas. However, in the Canning Basin the cycles are characterized by a much lower proportion of anhydrite, implying perhaps a greater degree of continental restriction to the basin. The moderately high level of bromine in the Mallowa Salt (156.5 43.5 ppm Br for primary halite, 146.1 54.7 ppm Br for secondary halite) accords with evolved continental brines, although highly evaporative minerals such as polyhalite and magnesite are absent. The bromine levels suggest little or no dissolution/reprecipitation of primary halite and yet, paradoxically, there is little preservation of the primary depositional fabric. The preservation of early halite cements and replacement textures supports the idea of an early shutdown of brine flow paths, probably at burial depths of no more than a few metres, and the resultant preservation of primary bromine values in the secondary halite

Recherches nouvelles sur les karsts des gypses et des vaporites associes ; seconde partie : gomorphologie, hydrologie et impact anthropique, 1993,
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Nicod, J.
Surface features reflect not only the importance of cave collapse, but also the action of present and inherited zonal processes. The rates of geomorphological evolution are compared (main data in table 1). The particularities of hydrological flow are studied, as well as the dynamic of some karstic lakes, particularly the Banyoles Lake (Catalonia). The various processes generate numerous hazards enumerated in the paper and evident in urban and suburban areas and in the civil engineering works such as tunnels, dams, etc.

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Rouchy J. M. , Groessens E. , Laumondais A. ,
Within the Franco-Belgian segment of the Hercynian orogen, two thick Dinantian anhydritic formations are known, respectively in the Saint-Ghislain (765 m) and Epinoy 1 (904 m) wells. Nevertheless, occurrences of widespread extended breccias and of numerous pseudomorphs of gypsum/anhydrite in stratigraphically equivalent carbonate deposits (boreholes and outcrops), suggest a larger extent of the evaporitic conditions (fig. 1, 2). The present distribution of evaporites is controlled by palaeogeographical differentiation and post-depositional parameters such as tectonics and dissolution. These latter have dissected the deposits formerly present in all the structural units. By using depositional, diagenetic and deformational characters of these formations, the article provides a model for the reconstruction of a dislocated evaporitic basin. This segment of the Hercynian chain is schematically composed of two main units (fig. 1, 3) : (1) the autochthonous or parautochthonous deposits of the Namur synclinorium, (2) the Dinant nappe thrusted northward over the synclinorium of Namur. The major thrust surface is underlined by a complex fault bundle (faille du Midi) seismically recognized over more than 100 km. A complex system of thrust slices occurs at the Hercynian front. Except for local Cretaceous deposits, most of the studied area has been submitted to a long period of denudation since the Permian. Sedimentary, faunistic and geochemical data argue for a marine origin of the brines which have generated the evaporites interbedded with marine limestones. Sedimentary structures. - The thick evaporitic formations are composed of calcium-sulfates without any clear evidence of the former presence of more soluble salts (with the exception of a possible carbonate-sulfate breccia in the upper part of the Saint-Ghislain formation). As in all the deeply buried evaporitic formations, the anhydrite is the main sulfate component which displays all the usual facies : pseudomorphs after gypsum (fig. 4A, B), nodular and mosaic (fig. 4C), laminated. The gypsum was probably an important component during the depositional phase despite the predominant nodular pattern of the anhydrite. Early diagenetic nodular anhydrite may have grown during temporary emersion of the carbonates (sabkha environments), but this mechanism cannot explain the formation of the whole anhydrite. So, most of the anhydrite structures result from burial-controlled gypsum --> anhydrite conversion and from mechanical deformations. Moreover, a complex set of diagenetic processes leads to various authigenic minerals (celestite, fluorite, albite, native sulfur, quartz and fibrous silica) and to multistaged carbonate <> sulfate replacements (calcite and dolomite after sulfate, replacive anhydrite as idiomorphic poeciloblasts, veinlets, domino-like or stairstep monocrystals...). These mineral transformations observed ill boreholes and in outcrops have diversely been controlled during the complex evolution of the series as : depositional and diagenetic pore-fluid composition, pressure and temperature changes with burial, bacterial and thermochemical sulfate reduction, deep circulations favored by mechanical brecciation, mechanical stresses, role of groundwater during exhumation of the series. Deformational structures. - A great variety of deformational structures as rotational elongation, stretching, lamination, isoclinal microfolding, augen-like and mylonitic structures are generated by compressive tectonic stresses (fig. 4D to J). The similarities between tectonic-generated structures and sedimentary (lamination) or diagenetic (pseudo-nodules) features could lead lo misinterpretations. The calcareous interbeds have undergone brittle deformation the style and the importance of which depend of their relative thickness. Stretching, boudins, microfolds and augen structures F, H. I) affect the thin layers while thicker beds may be broken as large fractured blocks dragged within flown anhydrite leading to a mylonitic-like structure (fig, 4G). In such an inhomogeneous formation made of interlayered ductile (anhydrite) and brittle (carbonate) beds, the style and the intensity of the deformation vary with respect to the relative thickness of each of these components. Such deformational features of anhydrite may have an ubiquitous significance and can result either from compressive constraints or geostatic movements (halokinesis). Nevertheless, some data evidence a relation with regional tangential stresses: (1) increase of the deformation toward the bottom of the Saint-Ghislain Formation which is marked by a deep karst suggesting the presence of a mechanical discontinuity used as a drain for dissolving solutions (fig. 3, 4); (2) structural setting (reversed series, internal slidings) of the Epinoy 1 formation under the Midi thrust. However, tectonic stresses also induce flowing deformations which have contributed to cause their present discontinuity. It can be assumed that the evaporites played an active role for the buckling of the regional structure as detachment or gliding layers and more specifically for the genesis of duplex structures. Breccia genesis. - Great breccia horizons are widely distributed in outcrops as well as in the subsurface throughout the greater part of the Dinant and Namur units (fig. 2). The wide distribution of pseudomorphosed sulfates in outcrops and the stratigraphical correlation between breccia and Saint-Ghislain evaporitic masses (fig. 2) suggest that some breccia (although not all) have been originated from collapse after evaporites solution. Although some breccia may result from synsedimentary dissolution, studied occurrences show that most of dissolution processes started after the Hercynian deformation and, in some cases, were active until recently : elements made of lithified and fractured limestones (Llandelies quarries) (fig. 5A), preservation of pseudomorphs of late replacive anhydrite (Yves-Gomezee) (fig. 5B, C), deep karst associated with breccia (Douvrain, Saint Ghislain, Ghlin boreholes) (fig. 3, 4, 5D)). Locally, the final brecciation may have been favored by a mechanical fragmentation which controlled water circulations (fig. 5E). As postulated by De Magnee et al. [19861, the dissolution started mostly after the Permian denudation and continued until now in relation with deep circulations and surface weathering (fig. 6). So, the above-mentioned occurrences of the breccia are logically explained by collapse after dissolution of calcium-sulfates interbeds of significant thickness (the presence of salt is not yet demonstrated), but other Visean breccia may have a different origin (fig. 5F). So, these data prove the extension of thick evaporitic beds in all the structural units including the Dinant nappe, before dissolution and deformation. Implications. - Distribution of Visean evaporites in northern France and Belgium is inherited from a complicated paleogeographic, tectonic and post-tectonic history which has strongly modified their former facies, thicknesses and limits (fig. IA, 6). Diversified environments of deposition controlled by both a palaeogeographical differentiation and water level fluctuations led to the deposition of subaqueous (gypsum) or interstitial (gypsum, anhydrite) crystallization. Nevertheless, most of the anhydrite structures can be interpreted as resulting from burial conversion of gypsum to anhydrite rather than a generalized early diagenesis in sabkha-like conditions. Deformation of anhydrite caused by Hercynian tangential stresses and subsequent flow mechanisms, have completed the destruction of depositional and diagenetic features. The tectonic deformations allow us to consider the role of the evaporites in the Hercynian deformations. The evaporites supplied detachment and gliding planes as suggested for the base of the Saint-Ghislain Formation and demonstrated by the structural setting of Epinoy 1 evaporites in reverse position and in a multi-system of thrust-slices below the Midi overthrust (fig. 7). So, although the area in which evaporation and precipitation took place cannot be exactly delineated in geographic extent, all the data evidence that the isolated thick anhydritic deposits represent relics of more widespread evaporites extending more or less throughout the different structural units of this Hercynian segment (fig. 1B). Their present discontinuity results from the combination of a depositional differentiation, mechanical deformations and/or dissolution

Silicification of evaporites in Permian (Guadalupian) back-reef carbonates of the Delaware Basin, west Texas and New Mexico, 1993,
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Ulmerscholle D. S. , Scholle A. , Brady P. V.

Rapports entre la karstification _primditerranenne et la crise de salinit messinienne, lexemple du karst lombard (Italie), 1994,
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Bini, A.
The Mediterraean dessiccation theory suggests that during the Messinian the Mediterranean sea lad almost completely dried up did a thick succession of evaporites was laid down Due to dessiccation the erosional base level through the whole Mediterranean area was lowered, with the consequent development of long and deep fluviatile canyons (e.g. Nile, Rhne, Var, etc). This lowering strongly affected karst evolution This paper concerns the karst in Lombardy, around the southalpine lakes. The old evolutionary models, predating dessiccation theory, assume that the lacustine valleys were scoured by the quaternary glaciers. ln this case the karst should have been characterized by some features, like for example the altitudinal cave distribution as a consequence of the valley lowering after each glaciation. Seismic experiments through the lakes and their tributaries have shown that these valleys are deep fluviatile canyons. The study of caves has demonstrated that the caves themselves predate the entrenchment of the valleys and the glaciations. During the latter the caves were filled up and emptied several times, without any modifications of their inner morphology, including stalactites. Moreover the U/Th age determinations indicate that a great number of concretions are older than 350 ky, and that a few are older than 1.5 Ma. As a conse-quence, a general model of karst evolution can be proposed. The former karstic drainage system developed after the Oligo-Miocene emersion. Paleogeography obviously diffe-red from the present day landscape but the main valley had already been scoured. During the Messinian the dramatic lowering of base level determined major changes in karstic evolution and a reorganisation of the karst drainage system that was consequently lowered considerably. The Pliocene transgression determined a new karst evolution, after which a great number of caves were located well below the sea level base. This evolution occurred during hot and wet climate period, with seasonal high flows and relevant discharges of the karstic rivers The great caves of the Lombardian karst developed within the climatic stage.

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Kendall C. G. S. , Sadd J. L. , Alsharhan A. ,
Marine carbonate cements, which are superficially like travertines from meteoric caves, are coating and binding some intertidal sedimentary rock surfaces occurring in coastal Abu Dhabi, the United Arab Emirates, (UAE). Near Jebel Dhana these surficial cements can be up to 3 cm thick and envelope beach rock surfaces and fossils. They are also present both as thin coats and a fracture-fill cement in the intertidal hard grounds associated with the Khor Al Bazam algal flats. The thickness, microscopic characteristics, and morphology of the marine cement coatings from Jebel Dhana indicates incremental deposition of aragonite in conjunction with traces of sulfate minerals. Most of these cement coatings are micritic, but the layers which encrust the hard grounds from the algae flat of the Khor al Bazam have a more radial and fibrous micro-structure and are composed solely of aragonite. The stable isotopic composition of coatings from Jebel Dhana (delta(18)O = .35, delta(13)C = .00) falls within the compositional range for modem marine non skeletal aragonite and suggests that the marine travertine-like cements precipitate from the agitated slightly hypersaline Arabian Gulf sea water during repeated cycles of exposure, evaporation and immersion. Similar cement coatings and microfabrics are present in the tepee structured and brecciated sediments of the Guadalupe Mountains (Permian) and the Italian Alps (Triassic), in Holocene algal head cements from the Great Salt Lace, and in similar Tertiary algal heads in the Green River Formation of the western US. The petrographic similarity of these ancient ''flow stone'' like cements with Recent hypersaline marine cement coatings suggests that high rates of carbonate cementation and hypersaline conditions contribute to tepee formation and cavity fill

Synsedimentary collapse of portions of the lower Blomidon Formation (Late Triassic), Fundy rift basin, Nova Scotia, 1995,
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Ackermann Rv, Schlische Pw, Olsen Pe,
A chaotic mudstone unit within the lower Blomidon Formation (Late Triassic) has been traced for 35 km in the Mesozoic Fundy rift basin of Nova Scotia. This unit is characterized by highly disrupted bedding that is commonly cut by small (<0.5 m) domino-style synsedimentary normal faults, downward movement of material, geopetal structures, variable thickness, and an irregular, partially faulted contact with the overlying unit. The chaotic unit is locally overlain by a fluvial sandstone, which is overlain conformably by mudstone. Although the thickness of the sandstone is highly variable, the overlying mudstone unit exhibits only gentle regional dip. The sandstone unit exhibits numerous soft-sediment deformation features, including dewatering structures, convoluted bedding, kink bands, and convergent fault fans. The frequency and intensity of these features increase dramatically above low points at the base of the sandstone unit. These stratigraphic relations suggest buried interstratal karst, the subsurface dissolution of evaporites bounded by insoluble sediments. We infer that the chaotic unit was formed by subsidence and collapse resulting from the dissolution of an evaporite bed or evaporite-rich unit by groundwater, producing dewatering and synsedimentary deformation structures in the overlying sandstone unit, which infilled surface depressions resulting from collapse. In coeval Moroccan rift basins, facies similar to the Blomidon Formation are associated with halite and gypsum beds. The regional extent of the chaotic unit indicates a marked period of desiccation of a playa lake of the appropriate water chemistry. The sedimentary features described here may be useful for inferring the former existence of evaporites or evaporite-rich units in predominantly elastic terrestrial environments

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Mylroie J. E. , Carew J. L. ,
The exposed carbonates of the Bahamas consist of late Quaternary limestones that were deposited during glacio-eustatic highstands of sea level. Each highstand event produced transgressive-phase, stillstand-phase, and regressive-phase units. Because of slow platform subsidence, Pleistocene carbonates deposited on highstands prior to the last interglacial (oxygen isotope substage 5e, circa 125,000 years ago) are represented solely by eolianites. The Owl's Hole Formation comprises these eolianites, which are generally fossiliferous pelsparites. The deposits of the last interglacial form the Grotto Beach Formation, and contain a complete sequence of subtidal intertidal and eolian carbonates. These deposits are predominantly oolitic. Holocene deposits are represented by the Rice Bay Formation, which consists of intertidal and eolian pelsparites deposited during the transgressive-phase and stillstand-phase of the current sea-level highstand. The three formations are separated from one another by well-developed terra-rossa paleosols or other erosion surfaces that formed predominantly during intervening sea-level lowstands. The karst landforms of San Salvador consist of karren, depressions, caves, and blue holes. Karren are small-scale dissolutional etchings on exposed and soil-covered bedrock that grade downward into the epikarst, the system of tubes and holes that drain the bedrock surface. Depressions are constructional features, such as swales between eolian ridges, but they have been dissolutionally maintained. Pit caves are vertical voids in the vadose zone that link the epikarst to the water table. Flank margin caves are horizontal voids that formed in the distal margin of a past fresh-water lens; whereas banana holes are horizontal voids that developed at the top of a past fresh-water lens, landward of the lens margin. Lake drains are conduits that connect some flooded depressions to the sea. Blue holes are flooded vertical shafts, of polygenetic origin, that may lead into caves systems at depth. The paleokarst of San Salvador is represented by flank margin caves and banana holes formed in a past fresh-water lens elevated by the last interglacial sea-level highstand, and by epikarst buried under paleosols formed during sea-level lowstands. Both carbonate deposition and its subsequent karstification is controlled by glacio-eustatic sea-level position. On San Salvador, the geographic isolation of the island, its small size, and the rapidity of past sea level changes have placed major constraints on the production of the paleokarst

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Mylroie J. E. , Carew J. L. , Moore A. I. ,
Blue holes are karst features that were initially described from Bahamian islands and banks, which have been documented for over 100 years. They are water-fined vertical openings in the carbonate rock that exhibit complex morphologies, ecologies, and water chemistries. Their deep blue color, for which they are named, is the result of their great depth, and they may lead to cave systems below sea level Blue holes are polygenetic in origin, having formed: by drowning of dissolutional sinkholes and shafts developed in the vadose zone; by phreatic dissolution along an ascending halocline; by progradational collapse upward from deep dissolution voids produced in the phreatic zone; or by fracture of the bank: margin. Blue holes are the cumulative result of carbonate deposition and dissolution cycles which have been controlled by Quaternary glacioeustatic fluctuations of sea-level. Blue holes have been widely studied during the past 30 years, and they have provided information regarding karst processes, global climate change, marine ecology, and carbonate geochemistry. The literature contains a wealth of references regarding blue holes that are at times misleading, and often confusing. To standardize use of the term blue hob, and to familiarize the scientific community with their nature, we herein define them as follows: ''Blue holes are subsurface voids that are developed in carbonate banks and islands; are open to the earth's surface; contain tidally-influenced waters of fresh, marine, or mixed chemistry; extend below sea level for a majority of their depth; and may provide access to submerged cave passages.'' Blue holes are found in two settings: ocean holes open directly into the present marine environment and usually contain marine water with tidal now; inland blue holes are isolated by present topography from surface marine conditions, and open directly onto the land surface or into an isolated pond or lake, and contain tidally-influenced water of a variety of chemistries from fresh to marine

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Palmer A. N. , Palmer M. V. ,
The Kaskaskia paleokarst, part of the Mississippian-Pennsylvanian unconformity in North America, is typified by sinkholes, fissures, and dissolution caves at and near the top of the Kaskaskia Sequence (Madison Limestone and equivalents) and is covered by basal Absaroka siliciclastics (Chesterian to Morrowan). In the Rocky Mountains and Black Hills of the northwestern U. S. A. it postdates earlier features produced by sulfate-carbonate interactions, including breccias, dissolution voids, bedrock alteration, and mineralization. Both the paleokarst and earlier features have been intersected by post-Laramide caves. Ore deposits, aquifers, and petroleum reservoirs in the region are also concentrated along both the paleokarst horizons and earlier sulfate-related features. Each phase of karst modified and preferentially followed the zones of porosity and structural weakness left by earlier phases, producing an interrelated complex of now-relict features. All should be considered together to explain the present aspect of the paleokarst

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White W. B. , White E. L. ,
The signature of karst terrain is a suite of characteristic landforms: caves, closed depressions, deranged surface drainage, and sculptured bedrock surfaces. Identification of karst, in reality, is accomplished by an ill-defined mix of morphological, sedimentological, and bedrock-geology evidence. The purely morphological signature depends on an examination of population statistics and the scaling laws for the various landforms. Caves are fragments of active and paleo conduit drainage systems. The distribution of cave lengths is a power function with a fractional (fractal) exponent. The number of closed depressions of given depth or diameter falls off exponentially with increasing size. Blind valley areas relate to stream length and stream order by power laws. Some features of bedrock sculpturing occur at fu;ed scale. Pinnacle karren, however, appear to be scale invariant over seven orders of magnitude of scale range

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Schaad W. ,
Rauhwackes (cornieules or cargneules) are breccias with a caicareous matrix and mainly dolomitic components that weather to form cavernous rocks. They are very often associated with tectonic contacts, e.g. detachment horizons. The origin of rauhwackes is still controversial, but has been attributed to the weathering and alteration of dolomite-bearing evaporites, the tectonisation of dolomites or other processes. New data based on field investigations show that the karstification of evaporites leads to the formation of rauhwackes. Two end member evaporitic protoliths can be distinguished: dolomite-bearing gypsum and gypsum-bearing dolomite. The karstification of the different protoliths leads to the formation of structurally distinct rauhwackes. Dolomite-bearing gypsum is associated with unstructured, often polymictic rauhwackes which reflect the shape of the karst cavities and which are interpreted as karst sediments. Gypsum-bearing dolomite occurs with stratiformal rauhwackes with fitting dolomite fragments that are arranged in layers. These rauhwackes can be regarded as collapse breccias. All investigated rauhwackes seem to have been formed after the alpine deformations and are probably of Quaternary age. In certain cases, the karstification of the evaporites and the formation of rauhwackes may have been favoured by fluvial or fluvioglacial processes at the surface. Therefore, these rauhwackes have nothing to do with alpine tectonics. Rather, it was the evaporitic protoliths of the rauhwackes that acted as detachment horizons and incompetent layers during folding

Karst Geomorphology and Hydrogeology of the Northeastern Mackenzie Mountains, District of Mackenzie, N.W.T., PhD Thesis, 1995,
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Hamilton, James P.

This thesis describes the geomorphology and hydrogeology of karst systems in portions of the northeastern Canyon Ranges of the Mackenzie Mountains and the Norman Range of the Franklin Mountains. N.W.T. In the region, mean annual temperatures are -6 to -8°C, total annual precipitation is 325 to 500 mm, and permafrost has a widespread to continuous distribution. The area was glaciated in the Late Wisconsinan by the Laurentide Ice Sheet.
The Canyon Ranges and Norman Range are composed of a sequence of faulted and folded miogeoclinal sedimentary rocks that span the Proterozoic to Eocene. The geology is reviewed with an emphasis on strata that display karst. Included are several dolomite and limestone formations, two of which are interbedded with evaporites in the subsurface. The principal groundwater aquifer is the Lower Devonian Bear Rock Formation. In subcrop, the Bear Rock Formation is dolomite and anhydrite, outcrops are massive calcareous solution breccias. This is the primary karst rock.
The regional distribution and range of karst landforms and drainage systems are described. Detailed mapping is presented from four field sites. These data were collected from aerial photography and ground surveys. The karst has examples of pavement, single and compound dolines, subsidence troughs, polje, sinking streams and lakes. and spring deposits. The main types of depressions are subsidence and collapse dolines. Doline density is highest on the Bear Rock Formation. Surficial karst is absent of less frequent in the zone of continuous permafrost or outside the glacial limit.
At the field sites, water samples were collected at recharge and discharge locations. Samples were analyzed for a full range of ionic constituents and many for natural isotopes. In addition, several springs were monitored continuously for discharge, temperature, and conductivity. Dye tracing established linkages between recharge and discharge at some sites. These data are summarized for each site, as is the role of permafrost in site hydrology.
The relationships between geological structure, topography, ,and groundwater systems are described. Conduit aquifers are present in both dolomite and limestone. These systems are characterized by discharge waters of low hardness and dissolved ion content. Aquifers in the Bear Rock Formation have a fixed flow regime and often have highly mineralized discharge. At the principal field site. there was a time lag of 40 to 60 days between infiltration and discharge in this unit. At a second site, flow through times were on the order of years. Variability in these systems is attributed to bedrock properties and boundary conditions.
Preliminary rates of denudation are calculated from the available hydrochemical data. Total solutional denudation at the primary field site is approximately 45 m³ kmˉ² aˉ¹ (mm kaˉ¹). The majority is attributed to the subsurface dissolution of halite and anhydrite. The predominance of subsurface dissolution is linked to the high frequency of collapse and subsidence dolines and depressions.
The karst features and drainage systems of the northern Mackenzie Mountains date to the Tertiary. Glaciation has had a stimulative effect on karst development through the subglacial degradation of permafrost and the altering of boundary conditions by canyon incision.

Gypsum karst of the Baltic republics., 1996,
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Narbutas Vytautas, Paukstys Bernardas
The Baltic Republics of Estonia, Latvia and Lithuania have karst areas developed in both carbonate and gypsiferous rocks. In the north, within the Republic of Estonia, Ordovician and Silurian limestones and dolomites crop out, or are covered by glacial Quaternary sediments. To the south, in Latvia and Lithuania, gypsum karst is actively developing in evaporites of Late Devonian (Frasnian) age. Although gypsum and mixed sulphate-carbonate karst only occupy small areas in the Baltic countries, they have important engineering and geo-ecological consequences. Due to the rapid dissolution of gypsum, the evolution of gypsum karst causes not only geological hazards such as subsidence, but it also has a highly adverse effect on groundwater quality. The karst territory of the Baltic states lies along the western side of the area, called the Great Devonian Field that form part of the Russian Plain. Within southern Latvia and northern Lithuania there is an area, exceeding 1000 sq. km, where mature gypsum karst occurs at the land surface and in the subsurface. This karst area is referred to here as the Gypsum Karst Region of the Baltic States. Here the surface karst forms include sinkholes, karst shafts, land subsidence, lakes and dolines. In Lithuania the maximum density of sinkholes is 200 per sq. km; in Latvia they reach 138 units per sq. km. Caves, enlarged dissolution voids and cavities are uncommon in both areas.

Evaporites, brines and base metals: What is an evaporite? Defining the rock matrix, 1996,
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Warren J. K. ,
This paper, the first of three reviews on the evaporite-base-metal association, defines the characteristic features of evaporites in surface and subsurface settings. An evaporite is a rock that was originally precipitated from a saturated surface or near-surface brine in hydrological systems driven by solar evaporation. Evaporite minerals, especially the sulfates such as anhydrite and gypsum, are commonly found near base-metal deposits. Primary evaporites are defined as those salts formed directly via solar evaporation of hypersaline waters at the earth's surface. They include beds of evaporitic carbonates (laminites, pisolites, tepees, stromatolites and other organic rich sediment), bottom nucleated salts (e.g. chevron halite and swallow-tail gypsum crusts), and mechanically reworked salts (such as rafts, cumulates, cross-bedded gypsarenites, turbidites, gypsolites and halolites). Secondary evaporites encompass the diagenetically altered evaporite salts, such as sabkha anhydrites, syndepositional halite and gypsum karst, anhydritic gypsum ghosts, and more enigmatic burial associations such as mosaic halite and limpid dolomite, and nodular anhydrite formed during deep burial. The latter group, the burial salts, were precipitated under the higher temperatures of burial and form subsurface cements and replacements often in a non-evaporite matrix. Typically they formed from subsurface brines derived by dissolution of an adjacent evaporitic bed. Because of their proximity to 'true' evaporite beds, most authors consider them a form of 'true' evaporite. Under the classification of this paper they are a burial form of secondary evaporites. Tertiary evaporites form in the subsurface from saturated brines created by partial bed dissolution during re-entry into the zone of active phreatic circulation. The process is often driven by basin uplift and erosion. They include fibrous halite and gypsum often in shale hosts, as well as alabastrine gypsum and porphyroblastic gypsum crystals in an anhydritic host. In addition to these 'true' evaporites, there is another group of salts composed of CaSO4 or halite. These are the hydrothermal salts. Hydrothermal salts, especially hydrothermal anhydrite, form by the subsurface cooling or mixing of CaSO4- saturated hydrothermal waters or by the ejection of hot hydrothermal water into a standing body of seawater or brine. Hydrothermal salts are poorly studied but often intimately intermixed with sulfides in areas of base-metal accumulations such as the Kuroko ores in Japan or the exhalative brine deeps in the Red Sea. In ancient sediments and metasediments, especially in hydrothermally influenced active rifts and compressional belts, the distinction of this group of salts from 'true' evaporites is difficult and at times impossible. After a discussion of hydrologies and 'the evaporite that was' in the second review, modes and associations of the hydrothermal salts will be discussed more fully in the third review

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