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Enviroscan Ukrainian Institute of Speleology and Karstology


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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That katavothron is (greek.) a closed depression or swallow hole [10].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms


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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for chemistry (Keyword) returned 492 results for the whole karstbase:
Showing 16 to 30 of 492
Seminar on Karst Denudation - Responses in the Chemistry of Spring Waters in the Oxford region to some Climatic variables, 1972,
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Paterson K.

The effect of climate on the chemistry of carbonate groundwater, 1975,
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Drake J. J. , Wigley T. M. L.

Paleohydrology and Streamflow Simulation of three Karst Basins in Southeastern West Virginia, U.S.A., PhD Thesis, 1975,
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Coward, Julian Michael Henry

This study was undertaken to gain a better understanding of karst hydrology. To do this, the present day hydrology and the paleohydrology were determined in three karst basins. The basins chosen were the Swago, Locust and Spring Creek basins in Pocahontas and Greenbrier Counties, West Virginia. A number of conventional field techniques were used successfully in this study, including the following: current meter and dye dilution gauging; dye and lycopodium stream tracing; geological and cave mapping; the setting up of stage recorders; geochemistry; and limestone erosion measurements. The climate of the region was investigated to obtain realistic precipitation, temperature and potential evaporation data over the study basins.
It was found that the mean precipitation over two of the basins was 30% higher than recorded data in the valleys. The karst development of the basins was found to take place in four major stages. These were: A) initial surficial flow, B) strike controlled drainage, C) major piracies from one sub-basin to another, and D) shortening of the flow routes. The major controls on the karst development were found to be: A) the Taggard shale, B) the strike direction, which controlled early basin development, and C) the hydraulic gradient from the sink to rising, which controlled later basin development.
To better assess the quantitative hydrology, and to assist in determining the type of unexplorable flow paths, a watershed model was developed. This modelled the streamflow from known climatic inputs using a number of measured or optimized parameters. The simulation model handled snowmelt, interception, infiltration, interflow, baseflow, overland flow, channel routing, and evaporation from the interception, soil water, ground water, snowpack and channel water. The modelled basin could be split up into 20 segments, each with different hydrological characteristics, but a maximum of 3 segments was used in this study.
A total of 29 parameters was used in the model although only 10 (other than those directly measurable) were found to be sensitive in the three basins. The simulated streamflow did not match the real flows very well due to errors in the data input and due to simplifications in the model. It was found, however, that as the proportion of the limestone in a segment increased the overland flow decreased, the interflow increased, the baseflow and interflow recessions were faster, the soil storages were smaller and the infiltration rate was higher, than in segments with a larger proportion of exposed clastics. The flow characteristics of the inaccessible conduits were inferred from the channel routing parameters and it was postulated that the majority of the underground flow in the karst basins was taking place under vadose conditions.


Hydrology and Geochemistry of the Upper Lost River Drainage Basin, Indiana, 1976,
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Bassett, John

The chemistry of cave waters, 1976,
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Picknett R. G. , Bray L. G. , Stenner R. D.

Karst Geomorphology of the Bruce Peninsula, Ontario, PhD Thesis, 1976,
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Cowell, Daryl William

This is the first detailed examination of the karst geomorphology of the Bruce Peninsula. It attempts to review all aspects including pavement phenomena and formation (microkarst features), surface and subsurface karst hydrology (meso to macro scale) and water chemistry. The latter is based on over 250 samples collected in 1973 and 1974.
The dolomite pavement is the best example of its kind that has been described in the literature. It covers much of the northern and eastern parts of the peninsula and can be differentiated into three types based on karren assemblages. Two of these are a product of lithology and the third reflects local environmental controls. The Amabel Formation produces characteristic karren such as rundkarren, hohlkarren, meanderkarren, clint and grike, kamentizas and rillenkarren on glacially abraded biohermal structures. The Guelph Formation develops into a very irregular, often cavernous surface with clint and grike and pitkarren as the only common recognizable karren. The third assemblage is characterized by pitkarren and is found only in the Lake Huron littoral zone. Biological factors are believed to have played a major role in the formation of the pavement. Vegetation supplies humic acids which help boost the solution process and helps to maintain a wet surface. This tends to prolong solution and permit the development of karren with rounded lips and bottoms.
Three types of drainage other than normal surface runoff are found on the Bruce. These are partial underground capture of surface streams, complete underground capture (fluvio-karst), and wholly vertical drainage without stream action (holokarst). Holokarst covers most of the northern and eastern edge of the peninsula along the top of the escarpment. Inland it is replaced by fluvial drainage, some of which has been, or is in the process of being captured. Four perennial streams and one lake disappear into sinkholes. These range from very simple channel capture and resurgence, as shown by a creek east of Wiarton, to more mature and complex cave development of the St. Edmunds cave near Tobermory. Partial underground capture represents the first stage of karst drainage. This was found to occur in one major river well inland of the fluvio-karst and probably occurs in other streams as well. This chapter also examines the possible future karst development of the Bruce and other karst feature such as isolated sinks and sea caves.
The water chemistry presented in Chapter 5 represents the most complete data set from southern Ontario. It is examined on a seasonal basis as well as grouped into classes representing water types (streams, Lake Huron and Georgian Bay, inland lakes, swamps, diffuse springs and conduit springs). The spring analyses are also fitted into climatic models of limestone solution based on data from other regions of North America. It was found that solution rates in southern Ontario are very substantial. Total hardness ranges from 150 to 250 ppm (expressed as CaCO3) in most lakes and streams and up to 326 ppm in springs. These rates compare with more southerly latitudes. The theoretical equilibrium partial pressure of CO2 was found to be the most significant chemical variable for comparing solution on different kinds of carbonates and between glaciated and non-glaciated regions. Expect for diffuse flow springs and Lake Huron, the Bruce data do not separate easily into water types using either graphical or statistical (i.e. Linear Discriminant Analysis) analyses. This is partly because of the seasonality of the data and because of the intimate contact all waters have with bedrock.


Coastal karst. Chemical evolution of waters and the development of underground drainage in coastal limestone regions. [in Polish], 1977,
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Rudnicki, Jan

Dan Yr Ogof Study - Cave Chemistry Researches, 1977,
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Bray L. G.

Karst Hydrogeology and Geomorphology of the Sierra de El Abra and the Valles-San Luis Potosí Region, México, PhD Thesis, 1977,
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Fish, Johnnie Edward

The general objective of this work was to develop a basic understanding of the karst hydrology, the nature and origin of the caves, the water chemistry, the surface geomorphology, and relationships among these aspects for a high relief tropical karst region having a thick section of limestone. The Valles-San Luis Potosí region of northeastern México, and in particular, the Sierra de El Abra, was selected for the study. A Cretaceous Platform approximately 200 km wide and 300 km long (N-S) delimits the region of interest. A thick Lower Cretaceous deposit of gypsum and anydrite, and probably surrounded by Lower Cretaceous limestone facies, is overlain by more than 1000 m of the thick-bedded middle Cretaceous El Abra limestone, which has a thick platform-margin reef. The Sierra de El Abra is a greatly elongated range along the eastern margin of the Platform. During the late Cretaceous, the region was covered by thick deposits of impermeable rocks. During the early Tertiary, the area was folded, uplifted, and subjected to erosion. A high relief karst having a wide variety of geomorphic forms controlled by climate and structure has developed. Rainfall in the region varies from 250-2500 mm and is strongly concentrated in the months June-October, when very large rainfalls often occur.
A number of specific investigations were made to meet the general objective given above, with special emphasis on those that provide information concerning the nature of ground-water flow systems in the region. Most of the runoff from the region passes through the karstic subsurface. Large portions of the region have no surface runoff whatsoever. The El Abra Formation is continuous over nearly the whole Platform, and it defines a region of very active ground-water circulation. Discharge from the aquifer occurs at a number of large and many small springs. Two of them, the Coy and the Frío springs group, are among the largest springs in the world with average discharges of approximately 24 m³/sec and 28 m³/sec respectively. Most of the dry season regional discharge is from a few large springs at low elevations along the eastern margin of the Platform. The flow systems give extremely dynamic responses to large precipitation events; floods at springs usually crest roughly one day after the causal rainfall and most springs have discharge variations (0max/0min) of 25-100 times. These facts indicate well-developed conduit flow systems.
The hydrochemical and hydrologic evidence in combination with the hydrogeologic setting demonstrate the existence of regional ground-water flow to several of the large eastern springs. Hydrochemical mixing-model calculations show that the amount of regional flow is at least 12 m³/sec, that it has an approximately constant flux, and that the local flow systems provide the extremely variable component of spring discharge. The chemical and physical properties of the springs are explained in terms of local and regional flow systems.
Local studies carried out in the Sierra de El Abra show that large conduits have developed, and that large fluctuations of the water table occur. The large fossil caves in the range were part of great deep phreatic flow systems which circulated at least 300 m below ancient water tables and which discharged onto ancient coastal plains much higher than the present one. The western margin swallet caves are of the floodwater type. The cave are structurally controlled.
Knowledge gained in this study should provide a basis for planning future research, and in particular for water resource development. The aquifer has great potential for water supply, but little of that potential is presently used.


A Chemical Investigation of some Groundwater of the Northern Limestone at Jenolan Caves, 1977,
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James Julia M. , Handel M. L.

A brief description of the geology and drainage of the Northern limestone at Jenolan Caves is introduced. Approaches to karst geochemistry are given. The reasons are given for the choice of complete chemical analyses followed by calculations of the thermochemical parameters (saturation indices with respect to calcite and dolomite, SIc and SId, and the partial pressure of carbon dioxide PCO2) for the Jenolan groundwaters. The methods of chemical analysis and thermochemical calculations are reported. The results of the groundwater survey are presented both as the raw chemical data and the derived thermochemical data. The raw data give more useful information than the calculated parameters. The results obtained by this survey are consistent with observations and the previous knowledge of the underground drainage of the Northern limestone. The water chemistry reflected the rock type and the residence time of the water in bedrock and gravels. It is concluded that the Jenolan underground River and Central River have different types of source and that Central River is not a braid of the Jenolan Underground River.


Karst development in Ordovician carbonates: Western Platform of Newfoundland, Master of Science (MS) Thesis, 1978,
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Karolyi, Marika Sarolta

The Appalachian fold belt system in Newfoundland is divided into three tectonic divisions: Western Platform; Central Mobile Belt; Avalon Platform Rocks of the Western Platform range in age from Precambrian to Carboniferous. Major karst areas are found there is Ordovician and Carboniferous rocks. Karst features of the study area (Goose Arm to Bonne Bay Big Pond) are in the Ordovician carbonates of the undivided St. George and Table Head Formations, covering a few hundred square kilometers. Features include karren, sinkholes, sinking streams, and karst springs, caves and other solutional and collapse features.
In the study area multiple fold and faulting episodes complicate the geology. Extensive and probably repeated glaciations have produced rugged terrane with U-shaped valleys and as much as 300m relief on the carbonates. There is variable but thick till cover. A class or classes of ice-scoured closed depressions with internal drainage are recognized. Postglacial karst forms are limited to varieties of karren (mainly littoral), small sinkholes, and cave systems that are inaccessively small in most instances. Distribution of all karst features is highly irregular.
Hydrologic patterns follow fluvial, fluviokarstic and holokarstic drainage. Large number of sinking ponds have seasonal overflow channels. The ground water drainage routes are generally short and shallow, with varied hydraulic gradients. Few instances of ground water route integration to regional springs is found.
The water chemistry of the area displays a tight normal distribution of hardness. This is attributed to the ponding effect. Seasonal trends show an overall increase in total hardness and other parameters, with some ponds showing linear increases and others cyclic variations.
Karst type and distribution is complex and irregular, but both glaciokarstic and karstiglacial development is present. The majority of karst forms point to karstiglacial development where previous karst forms have been modified by ice. Karstification is controlled by geology, rock lithology, hydraulic gradients and glacial scour and infill. Karstic processes continue to operate today, modifying the scoured basins and creating new karst forms.


Physical chemistry of hydrothermal systems with carbon dioxide, 1979,
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Malinin S. D.

Hardness Controls of Cave Drips, Murray Cave, Cooleman Plain, Kosciusko National Park, 1979,
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Jennings, J. N.

Drips in the forward part of the Murray Cave between 5 and 50m below the surface were sampled about once a month for 2 years, carbon dioxide in the soil above and in the cave air being measured also. Mean soil CO2 content was fifteen times atmospheric, summer yeilding higher values than winter though the dry 1972-3 summer had low values. Greater depths in the soil had more CO2 than shallower ones. Cave air had on the average little more CO2 than the atmosphere but river flooding of the cave was followed by large CO2 fluctuations. There was a slight tendency for drips to be warmer and to vary less in temperature inwards. Drip pH was greater in summer than winter because of high CO2 production. The (Ca+Mg)/(Na+K) ratio of the drips was nearly ten times that of the Blue Waterholes, showing that igneous rock weathering around the Plain supplies more of the Na and K in the spring output than was envisaged before. The drip Mg/Ca ratio lies close to that of the Blue Waterholes, underlining the dominance of the limestone in the output hydrochemistry. The mean total hardness of 141 mg.L-1, not significantly different from earlier Murray cave drip measurements, sustains the previous estimate that the superficial zone provides about 2/3 of the limestone solution. The summer value (149 mg.L-1) is significantly greater than the winter mean (132 mg.L-1), including high values in the dry 1972-3 summer when CO2 values were low. Lagged correlation on a weekly and three weekly basis of individual drip hardness on air temperature and precipitation yielded few significant results. Only a weak case for dominance of hardness by temperature through rhizosphere CO2 was evident but neither was the conflicting hypothesis of hardness in such contradictory ways that more detailed observations over equally long time periods are necessary to elucidate their influence.


Hydrochemistry of a dolomite terrain; the Bruce Peninsula, Ontario, 1980,
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Cowell D. W. , Ford D. C.

Environmental isotopes in groundwater hydrology, 1980,
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Fontes J.

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