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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for dissolution kinetics (Keyword) returned 54 results for the whole karstbase:
Showing 16 to 30 of 54
Karst aquifer evolution in fractured rocks, 1999, Kaufmann G. , Braun J. ,
We study the large-scale evolution and flow in a fractured karst aquifer by means of a newly developed numerical method. A karst aquifer is discretized into a set of irregularly spaced nodal points, which are connected to their set of natural neighbors to simulate a network of interconnected conduits in two dimensions. The conduits are allowed to enlarge by solutional widening. The geometric flexibility of this method, along with a simplified model for the dissolution kinetics within the system water-carbon dioxide-calcite, enables us to study both laminar and turbulent flow in a karst aquifer during its early phase of evolution. A sensitivity analysis is conducted for parameters such as conduit diameter, hydraulic pressure differences, and recharge conditions along the surface of the aquifer and shows that passage evolution depends strongly on the recharge condition and the amount of water available. Under fixed hydraulic head boundary conditions an early single-passage system develops under laminar conditions and is transformed into a maze-like passage system after the onset of turbulence. Fixed recharge boundary conditions are more likely to result in a branchwork-like passage system, although the addition of distributed recharge may lead to a maze-like system of secondary passages

Comments on: Mixed transport/reaction control of gypsum dissolution kinetics in aqueous solutions and initiation of gypsum karst by Michael A.Raines and Thomas A.Dewers in Chemical Geology 140, 29-48,, 2000, Dreybrodt W. , Gabrovsek F.

Comments on: Mixed transport/reaction control of gypsum dissolution kinetics in aqueous solutions and initiation of gypsum karst by Michael A. Raines and Thomas A. Dewers in Chemical Geology 140, 29-4, 2000, Dreybrodt W, Gabrovsek F,

A model of early evolution of karst conduits affected by subterranean CO2 sources, 2000, Gabrovsek F, Menne B, Dreybrodt W,
In investigating early karstification of one-dimensional conduits by computer models, so far one has assumed that the CO2 content of the calcite aggressive water stems entirely from the surface. Subterranean sources of CO2, however, can rejuvenate the solutional power of water already close to equilibrium with respect to calcite, and boast dissolution rates. In a first scenario we have investigated the influence of a punctual source of CO2 as the most simple case of release of CO2 into a karstifiable fracture at some position KL from its entrance of the widening joint with length L, (K < 1). The results show that only a small increase of the p(CO2) in the solution to about 0.01 atm is sufficient to reduce the breakthrough times to about 0.3 with respect to the case, where no CO2 is delivered. Other sources of CO2 are due to the metabolic activity of microorganisms. The existence of such diverse subterraneous microbial life in karst systems demonstrated. Whether situated on the fissure surfaces or free floating in the karst water, one basic product of their metabolism is CO2. This contributes over the whole flow path to the p(CO2) of the karst water. Therefore in a second scenario we assumed a constant rate of CO2-input along parts of the fracture, as could be delivered by the activity of aerobic bacteria dwelling at its walls. Such a scenario also applies to an extended diffuse CO2 migration from volcanic activity deep underground. In this case drastic reductions of the breakthrough time by about one order of magnitude are observed. These reductions are enhanced when the fracture aperature width of the initial fracture decreases. The physicochemical mechanisms of enhancement of karstification are discussed in detail by considering the evolution of the fracture aperature width and of the dissolution rates in space and time

Role of mixing corrosion in calcite-aggressive H2O-CO2-CaCO3 solutions in the early evolution of karst aquifers in limestone, 2000, Gabrovsek F, Dreybrodt W,
Two cave-forming mechanisms in limestone are discussed currently. First, when two H2O-CO2-CaCO3 solutions, saturated with respect to calcite but with different chemical compositions mix, renewed aggressiveness to limestone dissolution occurs. This process called mixing corrosion [Bogli, 1964, 1980], in combination with linear dissolution kinetics, has been suggested as cave forming. Second, it has been shown that solely the action of nonlinear dissolution kinetics can generate extended karst conduits. This paper combines both mechanisms. By digital modeling of the evolution of the aperture widths of a confluence of two fractures into a third one it is shown that the first mechanism does not create large cave conduits. The combination of mixing corrosion and nonlinear kinetics, however, considerably intensifies karstification, compared to that of nonlinear kinetics solely. The times to terminate early evolution of karst are significantly reduced when the CO2 concentrations of the inflowing solutions differ by no more than 30%. We discuss the underlying mechanisms by inspection of the time dependence of the evolution of aperture widths, flow rates through them, and of the renewed undersaturation of the mixed solution at the confluence of two fractures. Finally, the evolution of a karst aquifer on a two-dimensional percolation network is modeled when mixing corrosion is present, and compared to that on an identical net with identical nonlinear dissolution kinetics, but mixing corrosion excluded. Large differences in the morphology of the net of cave conduits are found and also a reduction of the time of their evolution. From these findings we conclude that climatic changes, which influence the p(CO2) in the soil, can divert the evolving cave patterns

Speleogenesis in gypsum, 2000, Klimchouk A.
The main differences between the solutional properties of gypsum and those of calcite lie in the much higher solubility of gypsum, and in dissolution kinetics of gypsum which is solely diffusion controlled. Unlike calcite, no change of kinetic order occurs with an increase in concentration. Initiation of long lateral flow paths through gypsum is virtually impossible due to the rapid rate of dissolution; no kinetic mechanisms allow slow but uniform dissolutional enlargement throughout the flow paths. Near the surface, fissures are already wide enough for cave development to occur, which is extremely competitive due to rapid dissolution kinetics and the strong dependence of enlargement rates on flow velocity and discharge. Thus caves in gypsum in exposed settings are mainly linear or crudely branching, rapidly adjusting to the contemporary geomorphic setting and available recharge. Vertical pipes or pits form in the vadose zone. No deep phreatic development and no artesian development by lateral flow from distant recharge areas can occur. However, cave origin and development does occur in deep-seated confined settings where gypsum beds in stratified sequences are underlain by, or sandwiched between poorly soluble aquifers. Two situations support cave origin in gypsum in deep-seated settings: (1) transverse flow through gypsum between overlying and underlying aquifers, and (2) lateral flow in an insoluble but permeable aquifer underlying a gypsum bed. The former situation generates either maze caves where uniformly distributed fissure networks exist in the gypsum, or discrete voids where the otherwise low-fissured gypsum is disrupted by prominent tectonic fractures. If considerable conduit porosity has been created in a deep-seated setting, it provides ready paths for more intense groundwater circulation and further cave development when the gypsum is uplifted into the shallow subsurface. Thick and low-fissured sulfate strata can survive burial with no speleogenesis at all where surrounded by poorly permeable beds. When exposed to the surface, such gypsum deposits undergo speleogenetic development with no inherited features, presenting the pure line of open karst.

Speleogenesis of the great gypsum mazes in the Western Ukraine, 2000, Klimchouk A.
Speleogenesis in the region proceeded mainly under confined hydrogeological conditions. While such development still continues in part of the territory, other parts exhibit entrenched karst settings. Huge relict maze cave systems have been explored here, five of which are currently the longest known gypsum caves in the world. They account for well over half of the total length of gypsum caves that has been explored around the world. This unique concentration of large caves is due to the local coincidence of several factors: confined speleogenetic settings with dispersed upward recharge from a basal aquifer, specific structural prerequisites of artesian speleogenesis (nature and frequency of fissuring), favorable regional evolution (rapid uplift, and fossilization of maze systems), and the presence of an overlying limestone bed and a widespread clayey protective cover (which prevented later infilling and/or destruction of the caves). Maze cave development in the Western Ukraine is not specific to gypsum, but it is quite characteristic of confined flow and transverse speleogenesis in a multi-storey aquifer system, provided proper structural conditions exist. The main advantage of speleogenetic studies in gypsum is that, due to its high solubility and fast dissolution kinetics, morphologic evidence of the flow pattern is well displayed and can be rather easily reconstructed. The great gypsum caves in the Western Ukraine can serve as a model example of the transverse artesian speleogenesis.

Speleogenesis: Evolution of Karst Aquifers., 2000,
The aim of this book is to present advances made in recent decades in our understanding of the formation of dissolutional caves, and to illustrate the role of cave genetic ( speleogenetic ) processes in the development of karst aquifers. From the perspective of hydrogeology, karst ground water flow is a distinct kind of fluid circulation system, one that is capable of self-organization and self-development due to its capacity to dissolve significant amounts of the host rock and transport them out of the system. Fluid circulation in soluble rocks becomes more efficiently organized by creating, enlarging and modifying patterns of cave conduits, the process of speleogenesis. We can assert that karst ground water flow is a function of speleogenesis and vice versa . The advances in cave science are poorly appreciated in what may be termed ?mainstream hydrogeology?, which retains a child-like faith in flow models developed in the sand box. Many karst students also will not be aware of all emerging concepts of cave origin because discussions of them are scattered through journals and books in different disciplines and languages, including publications with small circulation. An understanding of principles of speleogenesis and its most important controls is indispensable for proper comprehension of the evolution of the karst system in general and of karst aquifers in particular. We hope this book will be useful for both karst and cave scientists, and for general hydrogeologists dealing with karst terranes. This book is a pioneer attempt by an international group of cave scientists to summarize modern knowledge about cave origin in various settings, and to examine the variety of approaches that have been adopted. Selected contributions from 44 authors in 15 nations are combined in an integrated volume, prepared between 1994 and 1998 as an initiative of the Commission of Karst Hydrogeology and Speleogenesis, International Speleological Union. Despite a desire to produce an integrated book, rather than a mere collection of papers, the editors' policy has not been directed toward unifying all views. Along with some well-established theories and approaches, the book contains new concepts and ideas emerging in recent years. We hope that this approach will stimulate further development and exchange of ideas in cave studies and karst hydrogeology. Following this Introduction, (Part 1), the book is organized in seven different parts, each with sub-chapters. Part 2 gives a history of speleogenetic studies, tracing the development of the most important ideas from previous centuries (Shaw, Chapter 2.1) through the early modern period in the first half of this century (Lowe, Chapter 2.2) to the threshold of modern times (W.White, Chapter 2.3). The present state of the art is best illustrated by the entire content of this book. Part 3 overviews the principal geologic and hydrogeologic variables that either control or significantly influence the differing styles of cave development that are found. In Chapter 3.1 Klimchouk and Ford introduce an evolutionary approach to the typology of karst settings, which is a taken as a base line for the book. Extrinsic factors and intrinsic mechanisms of cave development change regularly and substantially during the general cycle of geological evolution of a soluble rock and , more specifically, within the hydrogeologic cycle. The evolutionary typology of karst presented in this chapter considers the entire life cycle of a soluble formation, from deposition (syngenetic karst) through deep burial, to exposure and denudation. It helps to differentiate between karst types which may concurrently represent different stages of karst development, and is also a means of adequately classifying speleogenetic settings. The different types of karst are marked by characteristic associations of the structural prerequisites for groundwater flow and speleogenesis, flow regime, recharge mode and recharge/discharge configurations, groundwater chemistry and degree of inheritance from earlier conditions. Consequently, these associations make a convenient basis to view both the factors that control cave genesis and the particular types of caves. Lithological and structural controls of speleogenesis are reviewed in general terms in Chapters 3.2 (Klimchouk and Ford). Lowe in Chapter 3.3 discusses the role of stratigraphic elements and the speleo-inception concept. Palmer in Chapter 3.4 overviews the hydrogeologic controls of cave patterns and demonstrates that hydrogeologic factors, the recharge mode and type of flow in particular, impose the most powerful controls on the formation of the gross geometry of cave systems. Hence, analysis of cave patterns is especially useful in the reconstruction of environments from paleokarst and in the prediction and interpretation of groundwater flow patterns and contaminant migration. Any opportunity to relate cave patterns to the nature of their host aquifers will assist in these applied studies as well. Osborne (Chapter 3.7) examines the significance of paleokarst in speleogenesis. More specific issues are treated by Klimchouk (The nature of epikarst and its role in vadose speleogenesis, Chapter 3.5) and by V.Dublyansky and Y.Dublyansky (The role of condensation processes, Chapter 3.6). Part 4 outlines the fundamental physics and chemistry of the speleogenetic processes (Chapter 4.1) and presents a variety of different approaches to modeling cave conduit development (Chapter 4.2). In Chapter 4.1, the chemical reactions during the dissolution of the common soluble minerals, calcite, gypsum, salt and quartz, are discussed with the basic physical and chemical mechanisms that determine their dissolution rates. As limestone is the most common karst rock and its dissolution is the most complex in many respects, it receives the greatest attention. Dreybrodt (Section 4.1.1) and Dreybrodt and Eisenlohr (Section 4.1.2) provide advanced discussion and report the most recent experimental data, which are used to obtain realistic dissolution rates for a variety of hydrogeologic conditions and as input for modeling the evolution of conduits. Although direct comparisons between theoretical or analytical dissolution rates and those derived from field measurements is difficult, a very useful comparison is provided by W.White (Section 4.1.3). The bulk removal of carbonate rock from karst drainage basins can be evaluated either by direct measurement of rock surface retreat or by mass balance within known drainage basins. All of these approaches make sense and give roughly accurate results that are consistent with theoretical expectations. It is well recognized today that the earliest, incipient, phases of speleogenesis are crucial in building up the pattern of conduits that evolve into explorable cave systems. It is difficult to establish the major controls on these initial stages by purely analytical or intuitive methods, so that modeling becomes particularly important. Various approaches are presented in Chapter 4.2. Ford, Ewers and Lauritzen present the results of systematic study of the propagation of conduits between input and output points in an anisotropic fissure, using a variety of hardware and software models, in series representing the "single input", "multiple inputs in one rank", and "multiple inputs in multiple ranks" cases (Section 4.2.1). The results indicate important details of the competitive development of proto-conduits and help to explain branching cave patterns. In the competition between inputs, some principal tubes in near ranks first link ("breakthrough") to an output boundary. This re-orients the flowfields of failed nearby competitors, which then extend to join the principal via their closest secondaries. The process extends outwards and to the rear, linking up all inputs in a "cascading system". The exploding growth of computer capability during the last two decades has greatly enhanced possibilities for digital modeling of early conduit development. Investigating the growth of a single conduit is a logical first step in understanding the evolution of caves, realized here by Dreybrodt and Gabrov?ek in the form of a simple mathematical model (Section 4.2.2) and by Palmer by numerical finite-difference modeling (Section 4.2.3). The models show that positive feedback loops operate; widening a fracture causes increasing flow through it, therefore dissolution rates increase along it and so on, until finally a dramatic increase of flow rates permits a dramatic enhancement of the widening. This breakthrough event terminates the initial stage of conduit evolution. From then on the water is able to pass through the entire conduit while maintaining sufficient undersaturation to preserve low-order kinetics, so the growth rate is very rapid, at least from a geological standpoint -- usually about 0.001-0.1 cm/yr. The initiation ("breakthrough") time depends critically on the length and the initial width of the fracture and, for the majority of realistic cases, it covers a time range from a few thousand years to ten million years in limestones. The modeling results give a clear explanation of the operation of selectivity in cave genesis. In a typical unconfined karst aquifer there is a great range of enlargement rates along the competing flow routes, and only a few conduits will grow to enterable size. The modeling also provides one starting point (others are discussed in Chapter 5.2) to explain uniform maze patterns, which will be favored by enlargement of all openings at comparable rates where the discharge/length ratio is great enough. Single-conduit modeling has the virtue of revealing how the cave-forming variables relate to each other in the simplest possible way. Although it is more difficult to extend this approach to two dimensions, many have done so (e.g. Groves & Howard, 1994; Howard & Groves, 1995; in this volume ? Ford, Ewers and Lauritzen, Section 4.2.1; Dreybrodt and Siemers, Section 4.2.4, and Sauter and Liedl, Section 4.2.5). The modeling performed by Dreybrodt and Siemers shows that the main principles of breakthrough derived from one-dimensional models remain valid. The evolution of karst aquifers has been modeled for a variety of different geological settings, including also variation in lithology with respect to the dissolution kinetics. Sauter and Liedl simulate the development of conduits at a catchment scale for fissured carbonate rocks with rather large initial openings (about 1 mm). The approach is based upon hydraulic coupling of a pipe network to matrix continuum in order to represent the well-known duality of karst aquifer flow systems. It is also shown how understanding of the genesis of karst aquifers and modeling of their development can assist in characterization of the conduit system, which dominates flow and transport in karst aquifers. An important point that has emerged from cave studies of the last three decades is that no single speleogenetic model applies to all geologic and hydrologic settings. Given that settings may also change systematically during the evolutionary geological cycles outlined above (Chapter 3.1), an evolutionary approach is called for. This is attempted in Part 5, which is organized to give extended accounts of speleogenesis in the three most important settings that we recognize: coastal and oceanic (Chapter 5.1), deep-seated and confined (Chapter 5.2) and unconfined (Chapter 5.3). Each Chapter begins with a review of modern ideas on cave development in the setting, followed by representative case studies. The latter include new accounts of some "classic" caves as well as descriptions of other, little-known cave systems and areas. Readers may determine for themselves how well the real field examples fit the general models presented in the introductory sections. Mylroie and Carew in Chapter 5.1 summarize specific features of cave and karst development in young rocks in coastal and island settings that result from the chemical interactions between fresh and salt waters, and the effects of fluctuating sea level during the Quaternary. The case studies include a review of syngenetic karst in coastal dune limestones, Australia (S.White, 5.1.1) and an example of speleogenesis on tectonically active carbonate islands (Gunn and Lowe, 5.1.2). Klimchouk in Chapter 5.2 reviews conditions and mechanisms of speleogenesis in deep-seated and confined settings, one of the most controversial but exciting topics in modern cave research. Conventional karst/speleogenetic theories are concerned chiefly with shallow, unconfined geologic settings, supposing that the karstification found there is intimately related to surface conditions of input and output, with the dissolution being driven by downward meteoric water recharge. The possibility of hypogenic karstification in deeper environments has been neglected for a long time, and the quite numerous instances of karst features found at significant depths have usually been interpreted as buried paleokarst. However, the last decade has seen a growing recognition of the variety and importance of hypogene dissolution processes and of speleogenesis under confined settings which often precedes unconfined development (Hill, 1987, 1995; Klimchouk, 1994, 1996, 1997; Lowe, 1992; Lowe & Gunn, 1995; Mazzullo & Harris, 1991, 1992; Palmer, 1991, 1995; Smart & Whitaker, 1991; Worthington, 1991, 1994; Worthington & Ford, 1995). Confined (artesian) settings were commonly ignored as sites for cave origin because the classic concept of artesian flow implies long lateral travel distances for groundwater within a soluble unit, resulting in a low capacity to generate caves in the confined area. However, the recognition of non-classical features in artesian flow, namely the occurrence of cross-formation hydraulic communication within artesian basins, the concepts of transverse speleogenesis and of the inversion of hydrogeologic function of beds in a sequence, allows for a revision of the theory of artesian speleogenesis and of views on the origin of many caves. It is proposed that artesian speleogenesis is immensely important to speleo-inception and also accounts for the development of some of the largest known caves in the world. Typical conditions of recharge, the flow pattern through the soluble rocks, and groundwater aggressiveness favor uniform, rather than competing, development of conduits, resulting in maze caves where the structural prerequisites exist. Cross-formational flow favors a variety of dissolution mechanisms that commonly involve mixing. Hydrogeochemical mechanisms of speleogenesis are particularly diverse and potent where carbonate and sulfate beds alternate and within or adjacent to hydrocarbon-bearing sedimentary basins. Hypogene speleogenesis occurs in rocks of varied lithology and can involve a variety of dissolution mechanisms that operate under different physical constraints but create similar cave features. Case studies include the great gypsum mazes of the Western Ukraine (Klimchouk, Section 5.2.1), great maze caves in limestones in Black Hills, South Dakota (Palmer, Section 5.2.2) and Siberia (Filippov, Section 5.2.3), karstification in the Redwall aquifer, Arizona (Huntoon, Section 5.2.4), hydrothermal caves in Hungary (Y.Dublyansky, Section 5.2.6), and sulfuric acid speleogenesis (Lowe, Bottrell and Gunn, Section 5.2.7, and Hill, Section 5.2.8). Y.Dublyansky summarizes the peculiar features of hydrothermal speleogenesis (Section 5.2.5), and V.Dublyansky describes an outstanding example of a hydrothermal cavity, in fact the largest ever recorded by volume, in the Rhodope Mountains (Section 5.2.9). Recognition of the scale and importance of deep-seated speleogenesis and of the hydraulic continuity and cross-formational communications between aquifers in artesian basins is indispensable for the correct interpretation of evolution of karst aquifers, speleogenetic processes and associated phenomena, regional karst water-resource evaluations, and the genesis of certain karst-related mineral deposits. These and other theoretical and practical implications still have to be developed and evaluated, which offers a wide field for further research efforts. Ford in Chapter 5.3 reviews theory of speleogenesis that occurs where normal meteoric waters sink underground through the epikarst or dolines and stream sinks, etc. and circulate in the limestone or other soluble rocks without any major artesian confinement. These are termed common caves (Ford & Williams, 1989) because they probably account for 90% or more of the explored and mapped dissolutional caves that are longer than a few hundred meters. This estimate reflects the bias in exploration; caves formed in unconfined settings and genetically related to surface recharge are the most readily accessible and hence form the bulk of documented caves. Common caves display chiefly the branchwork forms where the dissolutional conduits occupy only a tiny proportion of the total length or area of penetrable fissures that is available to the groundwaters. The rules that govern the selection of the successful linkages that will be enlarged into the branchwork pattern are supported in the models presented in Chapter 4.2. In the long section caves may be divided into deep phreatic, multi-loop, mixed loop and water table, and ideal water table types, with drawdown vadose caves or invasion vadose caves above them. Many large systems display a mixture of the types. The concepts of plan pattern construction, phreatic, water table or vadose state, and multi-phase development of common caves are illustrated in the case studies that follow the introduction. They are organized broadly to begin with examples of comparatively simple deep phreatic and multi-loop systems (El Abra, Mexico, Ford, Section 5.3.1 and Castleguard Cave, Canada, Ford, Lauritzen and Worthington, Section 5.3.2), proceeding to large and complex multi-phase systems such as the North of Thun System, Switzerland (Jeannin, Bitterly and Hauselmann, Section 5.3.3) and Mammoth Cave, Kentucky (Palmer, Section 5.3.8), to representatives of mixed vadose and phreatic development in mountainous regions (the Alps, Audra, Section 5.3.4; the Pyrenees, Fernandez, Calaforra and Rossi, Section 5.3.5; Mexico, Hose, Section 5.3.6) and where there is strong lithologic or structural control (Folded Appalachians, W.White, Section 5.3.7; gypsum caves in the South of Spain, Calaforra and Pulido-Bosch, Section 5.3.10). Two special topics are considered by W.White in Section 5.3.9 (Speleogenesis of vertical shafts in the eastern US) and Palmer (Maze origin by diffuse recharge through overlying formation). The set concludes with two instances of nearly ideal water table cave development (in Belize and Hungary, Ford, Section 5.3.12), and a review of the latest models of speleogenesis from the region where modern karst studies in the West began, the Classical Karst of Slovenia and Trieste (?u?ter?ic, Section 5.3.13). In Parts 2-5 attention is directed primarily on how the gross geometry of a cave system is established. Part 6 switches focus to the forms at meso- and micro- scales, which can be created during enlargement of the cave. Lauritzen and Lundberg in Chapter 6.1 summarize the great variety of erosional forms ( speleogenetic facies ) that can be created by a wide range of speleogenetic agents operating in the phreatic or vadose zones. Some forms of cave passages have been subject to intensive research and may be interpreted by means of simple physical and chemical principles, but many others are polygenetic and hence difficult to decipher with certainty. However, in addition to the analysis of cave patterns (see Chapter 3.4), each morphological element is a potential tool that can aid our inferences on the origin of caves and on major characteristics of respective past hydrogeological settings. In Chapter 6.2 E.White and W.White review breakdown morphology in caves, generalizing that the processes are most active during the enlargement and decay phases of cave development. Early in the process breakdown occurs when the flow regime shifts from pipe-full conditions to open channel conditions (i.e. when the roof first loses buoyant support) and later in the process breakdown becomes part of the overall degradation of the karst system. The chapter addresses the mechanism of breakdown formation, the geological triggers that initiate breakdown, and the role that breakdown plays in the development of caves. As the great majority of both theoretical considerations and case studies in this book deal with speleogenesis in carbonate rocks, it is useful to provide a special forum to examine dissolution cave genesis in other rocks. This is the goal of Part 7. Klimchouk (7.1) provides a review of speleogenesis in gypsum. This appears to be a useful playground for testing the validity and limitations of certain general speleogenetic concepts. Differences in solution kinetics between gypsum and calcite impose some limitations and peculiar features on the early evolution of conduits in gypsum. These peculiarities appear to be an extreme and more obvious illustration of some rules of speleogenetic development devised from conceptual and digital modeling of early conduit growth in limestones. For instance, it is shown (e.g. Palmer, 1984, 1991; Dreybrodt, 1996; see also Chapter 3.4 and Section 4.2.2) that initiation of early, narrow and long pathways does not seem feasible under linear dissolution rate laws (n=1) due to exponential decrease of the dissolution rates. Although the dissolution kinetics of gypsum are not well known close to equilibrium it is generally assumed that they are controlled entirely by diffusion and therefore linear. If dissolution of gypsum is solely diffusion-controlled, with no change in the kinetic order, conduit initiation could not occur in phreatic settings or by lateral flow through gypsum from distant recharge areas in artesian settings. Hence, the fact that maze caves are common in gypsum in artesian conditions (see Section 5.2.1) gives strong support to a general model of "transverse" artesian speleogenesis where gypsum beds are underlain by, or sandwiched between, insoluble or low-solubility aquifers (Chapter 5.2), and suggests that it may be applicable to cave development in carbonates. In unconfined settings, speleogenesis in gypsum occurs along fissures wide enough to support undersaturated flow throughout their length. Linear or crudely branching caves overwhelmingly predominate, which rapidly adjust to the contemporary geomorphic setting and to the maximum available recharge. Also, if considerable conduit porosity has been created in deep-seated settings, it provides ready paths for more intense groundwater circulation and further cave development when uplift brings the gypsum into the shallow subsurface. Speleogenesis in salt, reviewed in general and exemplified by the Monte Sedom case in Israel (Frumkin, Chapter 7.2), has been documented only in open, unconfined settings, where it provides a model for simple vadose cave development. Chapter 7.3 deals with speleogenesis in quartzites, illustrated by case studies from southeastern Minas Gerais, Brasil (Correa Neto, 7.3.1) and South Africa (Martini, 7.3.2). The process involves initial chemical weathering of the quartzite to create zones of friable rocks (sanding, or arenisation) which then are removed by piping, with further conduit enlargement due to mechanical erosion by flowing water. Part 8 combines the theoretical with some applied aspects of speleogenetic studies. Worthington, Ford and Beddows (8.1) show the important implications of what might be termed "speleogenetic wisdom" when studying ground water behaviour in karst. They examine some standard hydrogeological concepts in the light of knowledge of caves and their patterns, considering a range of case studies to identify the characteristic enhancement of porosity and permeability due to speleogenesis that occurs in carbonate rocks. The chapter focuses on unconfined carbonate aquifers as these are the most studied from the speleological perspective and most important for water supplies. Four aquifers, differing in rock type, recharge type (allogenic and autogenic), and age (Paleozoic, Mesozoic and Cenozoic), are described in detail to demonstrate the extent of dissolutional enhancement of porosity and permeability. It is shown that all four cases are similar in hydraulic function, despite the fact that some of them were previously characterized as different end members of a "karst ? non-karst" spectrum. Enhancement of porosity by dissolution is relatively minor: enhancement of permeability is considerable because dissolution has created dendritic networks of channels able to convey 94% or more of all flow in the aquifer, with fractures providing a small proportion and the matrix a negligible amount. These conclusions may be viewed as a warning to hydrogeologists working in carbonate terranes: probably the majority of unconfined aquifers function in a similar manner. Sampling is a major problem in their analysis because boreholes (the conventional exploration tool in hydrogeology) are unlikely to intersect the major channels that are conveying most of the flow and any contaminants in it. It is estimated, using examples of comprehensively mapped caves, that the probability of a borehole intersecting a conduit ranges from 1 in 50 to 1 in 1000 or more. Boreholes simply cannot be relied upon to detect the presence of caves or to ?characterise? the hydrologic functioning of cavernous aquifers. Wherever comprehensive evidence has been collected in unconfined carbonate aquifers (cave mapping plus boreholes plus lab analysis of core samples) it suggests that dissolution inexorably results in a similar structure, with channel networks providing most of the permeability of the aquifer, yet occupying a very minor fraction of its volume (Worthington, Ford and Beddows). Lowe (Chapter 8.2) focuses on developments in understanding the vital role played by karstic porosity, (broadly viewed as being the product of speleogenesis), in the migration of mineralizing fluids (or hydrocarbons) and in their deposition (or storage), and comments on the potential role of new speleogenetic concepts in developing greater understanding in the future. Although some early workers were clearly aware of actual evidence for some kind of relationship, and others noted its theoretical likelihood, it has been ignored by many until relatively recent times. This shortfall has gradually been redressed; new understanding of the extent and variety of karst processes is ensuring that new relationships are being recognized and new interpretations and models are being derived. The chapter does not pretend to give a comprehensive account of the topic but clearly demonstrates the wide applicability of speleogenetic knowledge to issues in economic geology. In Chapter 8.3 Aley provides an overview of the water and land-use problems that occur in areas with conduit aquifers. He stresses that sound land management must be premised on an understanding that karst is a three-dimensional landscape where the surface and subsurface are intimately and integrally connected. Failure to recognize that activity at the surface affects the subsurface, and the converse, has long been the root cause of many of the problems of water and land use in karst regions. Karst areas have unique natural resource problems, whose management can have major economic consequences. Although there is an extensive literature on the nature of particular problems, resource protection and hazard minimization strategies in karst, it rarely displays an advanced understanding of the processes of the conduit formation and their characteristics yet these will always be involved. This book does not pretend to be a definitive text on speleogenesis. However, it is hoped that readers will find it to be a valuable reference source, that it will stimulate new ideas and approaches to develop and resolve some of the remaining problems, and that it will promote an appreciation of the importance of speleogenetic studies in karst hydrogeology and applied environmental sciences. Acknowledgements: We sincerely thank all contributors for their willing cooperation in the long and difficult process of preparing this book, for their participation in developing its logic and methodology and their cheerful response to numerous requests. We thank all colleagues who discussed the work with us and encouraged it in many ways, even though not contributing to its content as authors. We are particularly grateful to Margaret Palmer for invaluable help in editing the English in many contributions, to Nataly Yablokova for her help in performing many technical tasks and to Elizabeth White who prepared comprehensive index. Our thanks are due to Dr. David Drew, Dr. Philip LaMoreaux, Dr. George Moore and Prof. Marian Pulina for reviewing the manuscript and producing constructive notes and comments on improvement of the final product. The organizational costs and correspondence related to the preparation of the book were partially sponsored by the National Speleological Society, the publisher. We thank David McClurg, the Chair of the NSS Special Publication Committee, for his extensive technical and organizational support in the preparation and publishing processes.

Surface controlled dissolution rates of gypsum in aqueous solutions exhibit nonlinear dissolution kinetics., 2001, Jeschke A. A. , Vosbeck K. , Dreybrodt W.

A model of the early evolution of karst aquifers in limestone in the dimensions of length and depth, 2001, Gabrovsek F, Dreybrodt W,
A new model of the early evolution of limestone karst aquifers in the dimensions of length and depth is presented. In its initial state the aquifer consists of a rock massive with evenly spaced fractures of about 50 [mu]m aperture widths with an hydraulic conductivity of 10-7 ms-1. In addition to this a coarser network of prominent fractures with aperture widths of several 100 [mu]m is also present. Boundary conditions of constant recharge 450 mm/year, or constant head from the input of allogenic streams are imposed. First the position of the water table in the aquifer is calculated, then dissolutional widening during a time step in all the fractures below the water table is found by use of the well-known nonlinear dissolution kinetics of limestone. This is iterated and the position of the water table as well as the fracture widths are found as a function of time. In the case of constant recharge to a karst plateau, the water table in any case drops to base level and conduits there propagate from the spring headwards. If constant head conditions are valid the position of the water table remains almost stable and conduits propagate along the water table from the input towards the spring. There is competition between conduit evolution along prominent fractures and along tight fissures close to the water table. In any case under constant head conditions one of these pathways wins, and early karst evolution is terminated by a breakthrough event with an explosive increase of the flow through the aquifer until constant head conditions break down. Depending on the boundary conditions of constant head or constant recharge or a combination of both it is possible to describe models of cave genesis, which have been derived from field evidence, such as the water table models of Swinnerton and Rhoades as well as the four-state model by Ford and Ewers (Can. J. Earth Sci., 15 (1978) 1783)

Karst hydrology: recent developments and open questions, 2002, White W. B. ,
Karst aquifers are those that contain dissolution-generated conduits that permit the rapid transport of ground water, often in turbulent flow. The conduit system receives localized inputs from sinking surface streams and as storrn runoff through sinkholes. The conduit system interconnects with the ground water stored in fractures and in the granular permeability of the bedrock. As a conceptual framework, the basic components of karstic aquifers seem to be generally accepted. Progress in the decade of the 1990s has focused mainly on quantifying the conceptual model. The equilibrium chemistry of the limestone and dolomite dissolution has been reliably established, and there are formal models for the kinetics of dissolution. Kinetic models have been used to calculate both fracture enlargement to protoconduits (0.01-m aperture) and the enlargement of protoconduits to the size of typical cave passages. Modeling of ground water flow in karstic aquifers has been less successful. Progress has been made in the use of water budgets, tracer studies, hydrograph analysis and chemograph analysis for the characterization of karstic aquifers. Topics on which progress is needed include (a) the construction of models that describe the complete aquifer including the interactions of all components, (b) models for elastic sediment transport within the aquifer, and (c) working out processes and mechanisms for contaminant transport in karst aquifers. An optimistic assessment at the end of the millennium is that a complete model for karstic aquifers is visible on the horizon.

Basic processes and mechanisms governing the evolution of karst, 2003, Dreybrodt W, Gabrovek F.

Models of karstification based on the physics of fluid flow in fractures of soluble rock, and the physical chemistry of dissolution of limestone by CO2 containing water have been presented during the last two decades. This paper gives a review of the basic principles of such models, their most important results, and future perspectives.
The basic element of evolving karst systems is a single isolated fracture, where a constant hydraulic head drives calcite aggressive water from the input to the output. Non linear dissolution kinetics with order n = 4 induce a positive feedback by which dissolutional widening at the exit enhances flow rates thus increasing widening and so on until flow rates increase dramatically in a breakthrough event. After this the hydraulic head breaks down and widening of the fracture proceeds fast but even along its entire length under conditions of constant recharge. The significance of modelling such a single fracture results from the fact that an equation for the breakthrough time specifies the parameters determining the processes of early karstification. In a next step the boundary conditions for isolated fractures are varied by including different lithologies of the rock, expressed by different dissolution kinetics. This can enhance or retard karstification. Subterranean sources of CO2 can also be simulated by changing the equilibrium concentration of the solution at the point where CO2 is injected. This leads to accelerated karstification. At the confluence of solutions from two isolated tubes into a third one, mixing corrosion can release free carbon dioxide. Its effect to solutional widening in such a system of three conduits is discussed.
Although these simple models give interesting insights into karst processes more realistic models are required. Combining single fractures into two-dimensional networks models of karst in its dimensions of length and breadth under constant head conditions are presented. In first steps the Ford-Ewers' high-dip and low-dip models are simulated. Their results agree to what one expects from field observations. Including varying lithologies produces a variety of new features. Finally we show that mixing corrosion has a strong impact on cave evolution. By this effect micro climatic conditions in the catchment area of the cave exert significant influence. A common feature in the evolution of such two-dimensional models is the competition of various possible pathways to achieve breakthrough first. Varying conditions in lithologies, carbon dioxide injection or changing hydrological boundary conditions change the chances for the competing conduits.
Karst systems developing at steep cliffs in the dimensions of length and depth are characterized by unconfined aquifers with constant recharge to the water table. Modelling of such systems shows that dissolution of limestone occurs close to the water table. The widening of the fractures there causes lowering of the water table until it becomes stable when base level is reached, and a water table cave grows headwards into the aquifer. When prominent deep fractures with large aperture widths are present deep phreatic loops originate below the water table. A river or a lake on a karst plateau imposes constant head conditions at this location in addition to the constant recharge from meteoric precipitation. In this case a breakthrough cave system evolves along the water table kept stable by the constant head input. But simultaneously deep phreatic loops arise below it.
In conclusion we find that all cave theories such as those of Swinnerton (1932), Rhoades and Sinacori (1941), and the Four-state-model of Ford are reconciled. They are not contradictory but they result from the same physics and chemistry under different boundary conditions


Karst landscape evolution, 2003, Kaufmann, G.

We present results of a numerical study of karst denudation on limestone plateaux. The landscape evolution model used incorporates not only long-range fluvial processes and short-range hill-slope processes, but also large-scale chemical dissolution of limestone surfaces. The relative efficiencies of fluvial and chemical processes are of equal importance to the landscape evolution of a plateau dropping to sea level along an escarpment. While fluvial processes have an impact confined to river channels, the karst denudation process is more uniform, removing material also from the plateau surface. The combined effect of both processes results in a landscape evolution almost twice as effective as the purely erosional evolution of an insoluble landscape.


Dam sites in soluble rocks: a model of increasing leakage by dissolutional widening of fractures beneath a dam, 2003, Romanov D. , Gabrovsek F. , Dreybrodt W. ,
Water flowing through narrow fissures and fractures in soluble rock, e.g. limestone and gypsum, widens these by chemical dissolution. This process, called karstification, sculptures subterranean river systems which drain most of their catchment. Close to dam sites, unnaturally high hydraulic gradients are present to drive the water impounded in the reservoir downstream through fractures reaching below the dam. Under such conditions, the natural process of karstification is accelerated to such an extent that high leakage rates may arise, which endanger the operation of the hydraulic structure. Model simulations of karstification below dams by coupling equations of dissolutional widening to hydrodynamic flow are presented. The model scenario is a dam 100 in wide in limestone or gypsum. The modelling domain is a two-dimensional slice 1 m wide directed perpendicular to the dam. It extends 375 in vertically and 750 in horizontally. The dam is located in its center. This domain is divided by fractures and fissures into blocks of 7.5 x 7.5 x 1 m. The average aperture width of the fractures is 0.02 cm. We performed model runs on standard scenarios for a dam site in limestone with the height H of impounded water 150 in, a horizontal impermeable apron of width W=262 m and a grouting curtain reaching down to a depth of G=97 m. In a second scenario, we changed these construction features to G=187 m and W=82 m. To calculate widening of the fractures, well-established experimental data on the dissolution of limestone and gypsum have been used as they occur in such geochemical settings. All model runs show similar characteristic behaviour. Shortly after filling, the reservoir exhibits a small leakage of about 0.01 m(-3) s(-1), which increases steadily until a breakthrough event occurs after several decades with an abrupt increase of leakage to about 1 m(3) s(-1) within the short time of a few years. Then, flow in the fractures becomes turbulent and the leakage increases to 10 m(3) s(-1) in a further time span of about 10 years. The widths of the fractures are visualized in various time steps. Small channels propagate downstream and leakage rises slowly until the first channel reaches the surface downstream. Then breakthrough occurs, the laminar flow changes to turbulent and a dense net of fractures which carry flow is established. We performed a sensitivity analysis on the dependence of breakthrough times on various parameters, determining breakthrough. These are the height of impounded water H, the depth G of grouting, the average aperture width a(0) of the fractures and the chemical parameters, which are c(eq) the equilibrium concentration of Ca with respect to calcite and the Ca-concentration c(in) of the inflowing water. The results show that the most critical parameter is a(0). At fracture aperture widths of 0.01 cm, breakthrough times are above 500 years. For values of a(0)>0.02 cm, however, breakthrough times are within the lifetime of the structure. We have also modelled dam sites in gypsum, which exhibit similar breakthrough times. However, after breakthrough, owing to the much larger dissolution rates of gypsum, the time until unbearable leakage is obtained, is only a few years. The modelling can be applied to complex geological settings, as phreatic cave conduits below the dam, or a complex stratigraphy with varying properties of the rock with respect to hydraulic conductivity and solubility. A few examples are given. In conclusion, our results support the assumption that increasing leakage of dam sites may be caused by dissolutional widening of fractures. (C) 2003 Elsevier Science B.V. All rights reserved

A deterministic approach to the coupled analysis of karst springs' hydrographs and chemographs, 2003, Grasso D. A. , Jeannin P. Y. , Zwahlen F. ,
During the chemically based recession flow phase of karstic springs the carbonate (dissolved limestone) concentration can be expressed as negative power of the flow rate. The empirically determined Conc/Q relationship allows two parameters (alpha and A) to be defined, of which one (alpha) depends on the geometric dimensions of the saturated (submerged) karstic network. In this paper we present a deterministic model which simulates the concentration of carbonate at the outlet of a network of circular rectilinear conduits as a function of flow rate. This model, based on hydraulic principles and the calcite dissolution kinetics, allows the sensitivity of the alpha and A parameters to be studied under different chemical, physical and geometric scenarios. Simulation results show that A is a function of the calcite saturation concentration, whereas alpha depends on the spatial dimensions of the karstic network (void length and aperture). The deterministic model results were applied to real karstic systems to evaluate the geometric dimensions of submerged karstic networks. (C) 2002 Elsevier Science B.V. All rights reserved

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