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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That seepage velocity is see specific discharge.?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Karst environment, Culver D.C.
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Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for dolomitization (Keyword) returned 68 results for the whole karstbase:
Showing 46 to 60 of 68
Hypogene and supergene alteration of the Late Palaeozoic Ratburi Limestone during the Mesozoic and Cenozoic (Thailand, Surat Thani Province). Implications for the concentration of mineral commodities, 2005, Dill H. G. , Botz R. , Luppold F. W. , Henjeskunst F.
An interdisciplinary study of the Upper Carboniferous to Middle Permian Ratburi Group, Peninsular Thailand, is presented. The investigation involved sedimentary petrography, inorganic geochemistry, Sr, C, O isotope analyses, micropalaeontology as well as radio-carbon age dating. Emphasis was placed on the post-depositional evolution of the Ratburi Limestone in the Surat Thani Province. The Holocene chemical residues and the various calcite and dolomite minerals which have formed since the Late Palaeozoic in the Ratburi Limestone are the product of a complex, multistage alteration which is called supergene and hypogene karstifications, respectively. Sedimentation took place in a shelf environment with some reefs evolving during the late Murgabian at the shelf margin. There was no pre-concentration of elements, except for Ca and F during sedimentation. Diagenetic neomorphism and cementation under marine and freshwater conditions caused the Ratburi Limestone to convert into a marble-like rock. Fabric-selective dolomitization is of local scale and has impacted only on part of the Ratburi Limestone during the Lower to Upper Permian. A significant enhancement of pore space and better conduits were generated during the Late Cretaceous epithermal alteration. The most favorable conditions for the accumulation of metals were provided during the high-temperature stage of epithermal alteration when a low-metal concentration with As, Zn, Sb, U, Co and Pb existed. Unlike the other elements, Sb was subject to a multiphase concentration, giving rise to a considerable Sb deposit in the region. The most recent stage of karstification produced numerous caves, dripstones, tufa terraces and encrustations around brine pools in the study area. This alteration originated from per descensum and per ascensum processes which may be traced back to 15,000 years before present. The alteration of the Ratburi Limestone may be subdivided into two parts. The prograde post-depositional alteration, beginning with diagenesis, reached its temperature climax during epithermal subsurface alteration I. The retrograde branch of alteration lasted until the most recent times. The initial stages deposition and diagenesis took place under more or less closed-system conditions relative to the succeeding stages of the prograde alteration which saw the strongest influx of metal-bearing brine during the epithermal stage I. The retrograde branch of alteration is element-conservative.

Discrimination of meteoric karst breccias from tectono-thermobaric breccias, 2005, Smith Langhorne B. , Palmer Arthur
Tectono-thermobaric breccias and associated hydrothermal dolomite reservoirs, such as those in the Trenton-Black River play, represent a major remaining resource in North America. Tectono-thermobaric breccias must be differentiated from paleokarst breccias for sound exploration and development decisions. Paleokarst breccias and collapsed meteoric caves are genetically related to sequence boundaries. Many have non-carbonate detrital matrix with vestiges of calcite speleothems. Perching on low-permeability strata is common. Modern meteoric caves are far more common in limestone than dolomite, typically <10 meters wide, and limited to areas of local topographic relief and discharge into a surface drainage system. Cavernous porosity is irregularly distributed and rarely more than 5% of the total rock volume. Ancient collapsed caves should show evidence for these characteristics. Tectono-thermobaric breccias form where space is created in active fault zones. Thermobaric (high-pressure, high-temperature) fluids flow up the active faults, enlarge fractures and precipitate minerals such as saddle dolomite, calcite and sulfides between clasts. Breccias follow fault trends, can be up to hundreds of meters wide, and are commonly concentrated beneath sealing shales or argillaceous limestones. These breccias can occur in limestone or dolomite but are commonly associated with hydrothermal matrix dolomitization. High permeability and porosity can be preserved between partially cemented clasts and in linked vugs, fractures and matrix. Tectono-thermobaric breccias form mainly in previously unbrecciated strata, but they may serendipitously intersect earlier meteoric karst. Tectono-thermobaric brecciated reservoirs commonly occur around wrench faults identifiable on seismic data. These reservoirs commonly do not require structural closure, so many potential targets remain undrilled. Tectono-thermobaric carbonate breccias also host many of the world's sulfide ore deposits. Many brecciated reservoirs and ore deposits that have been previously interpreted as meteoric karst may in fact be tectono-thermobaric in origin.

Cretaceous Karstic Cave-Fill Manganese-Lead-Barium Deposits of Imini, Morocco, 2006, Gutzmer J. , Beukes N. J. , Rhalmi M. , Mukhopadhyay J. ,
The economically important high-grade manganese ores of the Imini district, Morocco, are exceptional because of their unusually high Mn/Fe ratios and exceptional enrichment in Ba and Pb. There is ample evidence that the three strata-bound manganese orebodies of the Imini district formed in a laterally extensive karst cave system, associated with internal sediment, and developed in a shallow marine dolostone succession of Cretaceous age. The manganese ores occur in dolostone breccias and ferruginous clays that represent the earliest phase of internal sediment in the cave system. Later phases of cave fill are ferruginous without manganese enrichment. Ore formation, karstification, and meteoric dolomitization are all related to an extended period of exposure and terrestrial weathering, prior to the deposition of terrestrial red beds and evaporites of Upper Cretaceous age that overlie the ore-bearing dolostone succession above an erosional unconformity. The manganese ores formed when warm, acidic Mn2?? meteoric water migrated from the elevated regions of the Anti Atlas region into the exposed carbonate succession. Alkali feldspar-rich igneous basement rocks were the source for Mn, Pb, and Ba. Metals were deposited in a zone of mixing between metal-bearing, reducing meteoric water and oxygenated ground water resident in the cave system

Dolomite formation in breccias at the Musandam Platform border, Northern Oman Mountains, United Arab Emirates, 2006, Breesch L, Swennen R, Vincent B,
The presence of dolomite breccia patches along Wadi Batha Mahani suggests large-scale fluid flow causing dolomite formation. The controls on dolomitization have been studied, using petrography and geochemistry. Dolomitization was mainly controlled by brecciation and the nearby Hagab thrust. Breccias formed as subaerial scree deposits, with clay infill from dissolved platform limestones, during Early Cretaceous emergence. Cathodoluminescence of the dolostones indicates dolomitization took place in two phases. First, fine-crystalline planar-s dolomite replaced the breccias. Later, these dolomites were recrystallized by larger nonplanar dolomites. The stable isotope trend towards depleted values (delta O-18: -2.7 parts per thousand to - 10.2 parts per thousand VPDB and delta C-13: -0.6 parts per thousand to -8.9 parts per thousand VPDB), caused by mixing dolomite types during sampling, indicates type 2 dolomites were formed by hot fluids. Microthermometry of quartz cements and karst veins, post-dating dolomites, also yielded high temperatures. Hot formation waters which ascended along the Hagab thrust are invoked to explain type 2 dolomitization, silicification and hydrothermal karstification. (C) 2006 Elsevier B.V, All rights reserved

Growth, Demise, and Dolomitization of Miocene Carbonate Platforms on the Marion Plateau, Offshore NE Australia, 2006, Ehrenberg Sn, Mcarthur Jm, Thirlwall Mf,
Strontium-isotope stratigraphy has been used to examine the timing of depositional events and dolomitization in two Miocene carbonate platforms cored by Ocean Drilling Program (ODP) Leg 194, just seaward of the Great Barrier Reef. The results provide firm constraints for correlating surfaces and depositional stages between the two platforms and thereby relating seismic sequences previously defined in the off-platform sediments to the lithostratigraphic units described from cores in the seismically transparent platform-top sites. Oyster-bearing beds at the base of both platform successions yield early Oligocene ages (29-31 Ma), thus dating initial transgression of the Marion Plateau's volcanic basement. There followed a period of slow accumulation of shallow-water grainstones rich in quartz and phosphate grains in late Oligocene time (29-23 Ma; seismic Megasequence A). The main growth of the carbonate platforms took place in early to late Miocene time (23-7 Ma), comprising five depositional sequences. The first four of these (seismic Megasequence B) are common to both platforms and terminated with a possible karst surface at 10.7 Ma. Different sedimentologic expression of this megasequence in the two platforms reflects contrasting progradational versus aggradational geometries in the locations studied. The final growth stage (seismic Megasequence C) occurred only in the southern platform and terminated at 6.9 Ma. Both platform-demise events (10.7 and 6.9 Ma) approximately coincide with falls in global sea level combined with longer-term trends of decreasing water temperature. Sr-isotope ages of dolostones increase with depositional age, and older dolostones in the southern platform have more coarsely crystalline and fabric-destructive textures than overlying younger dolostones. These relationships are consistent with dolomitization by normal seawater shortly after deposition and overprinting of multiple times of dolomite recrystallization and cementation in the deeper strata

Pleistocene speleothems of Mallorca: implications for palaeoclimate and carbonate diagenesis in mixing zones, 2006, Csoma Ae, Goldstein Rh, Pomar L,
The Pleistocene speleothems of Sa Bassa Blanca cave, Mallorca, are excellent indicators of palaeoclimate variations, and are samples that allow evaluation of the products and processes of mixing-zone diagenesis in an open-water cave system. Integrated stratigraphic, petrographic and geochemical data from a horizontal core of speleothem identified two main origins for speleothem precipitates: meteoric-marine mixing zone and meteoric-vadose zone. Mixing-zone precipitates formed at and just below the water-air interface of cave pools during interglacial times, when the cave was flooded as a result of highstand sea-level. Mixing-zone precipitates include bladed and dendritic high-Mg calcite, microporous-bladed calcite with variable Mg content, and acicular aragonite; their presence suggests that calcium-carbonate cementation is significant in the studied mixing-zone system. Fluid inclusion salinities, delta(13)C and delta(18)O compositions of the mixing-zone precipitates suggest that mixing ratio was not the primary control on whether precipitation or dissolution occurred, rather, the proximity to the water table and degassing of CO2 at the interface, were the major controls on precipitation. Thus, simple two-end-member mixing models may apply only in mixing zones well below the water table. Meteoric-vadose speleothems include calcite and high-Mg calcite with columnar and bladed morphologies. Vadose speleothems precipitated during glacial stages when sea level was lower than present. Progressive increase in delta(13)C and delta(18)O of the vadose speleothems resulted from cooling temperatures and more positive seawater delta(18)O associated with glacial buildup. Such covariation could be considered as a valid alternative to models predicting invariant delta(18)O and highly variable delta(13)C in meteoric calcite. Glacio-eustatic oscillations of sea-level are recorded as alternating vadose and mixing-zone speleothems. Short-term climatic variations are recorded as alternating aragonite and calcite speleothems precipitated in the mixing zone. Fluid-inclusion and stable-isotope data suggest that aragonite, as opposed to calcite, precipitated during times of reduced meteoric recharge

Structurally controlled hydrothermal dolomite reservoir facies: An overview, 2006, Davies G. R. , Smith Jr. L. B.

Structurally controlled hydrothermal dolomite (HTD) reservoir facies and associated productive leached limestones are major hydrocarbon producers in North America and are receiving increased exploration attention globally. They include multiple trends in the Ordovician (locally, Silurian and Devonian) of the Michigan, Appalachian, and other basins of eastern Canada and the United States, and in the Devonian and Mississippian of the Western Canada sedimentary basin. They also occur in Jurassic hosts along rifted Atlantic margins, in the Jurassic–Cretaceous of the Arabian Gulf region and elsewhere. Hydrothermal dolomitization is defined as dolomitization occurring under burial conditions, commonly at shallow depths, by fluids (typically very saline) with temperature and pressure (T and P) higher than the ambient T and P of the host formation. The latter commonly is limestone. Proof of a hydrothermal origin for HTD reservoir facies requires integration of burial-thermal history plots, fluidinclusion temperature data, and constraints on timing of emplacement. Hydrothermal dolomite reservoir facies are part of a spectrum of hydrothermal mineral deposits that include sedimentary-exhalative lead-zinc ore bodies and HTD-hostedMississippi Valley–type sulfide deposits. All three hydrothermal deposits show a strong structural control by extensional and/or strike-slip (wrench) faults, with fluid flowtypically focused at transtensional and dilational structural sites and in the hanging wall. Transtensional sags above negative flower structures on wrench faults are favored drilling sites for HTD reservoir facies. Saddle dolomite in both replacive and void-fillingmodes is characteristic of HTD facies. For many reservoirs, matrix-replacive dolomite and saddle dolomite appear to have formed near-contemporaneously and from the same fluid and temperature conditions. The original host facies exerts a major influence on the lateral extent of dolomitization, resultant textures, pore type, and pore volume. Breccias zebra fabrics, shear microfractures, and other rock characteristics record short-term shear stress and pore-fluid-pressure transients, particularly proximal to active faults. High-temperature hydrothermal pulses may alter kerogen in host limestones, a process designated ‘‘forced maturation.’’ basement highs, underlying sandstone (and/ or carbonate?) aquifers (probably overpressured), and overlying and internal shale seals and aquitards also may constrain or influence HTD emplacement. Although many questions and uncertainties remain, particularly in terms of Mg and brine source and mass balance, recognition and active exploration of the HTD play continues to expand. Increasing use of three-dimensional seismic imagery and seismic anomaly mapping, combined with horizontal drilling oblique to linear trends defined by structural sags, helps to reduce risk 

Evidence against the Dorag (mixing-zone) model for dolomitization along the Wisconsin arch - A case for hydrothermal diagenesis , 2006, Luczaj, J. A.

Ordovician carbonates near the Wisconsin arch represent the type locality in ancient rocks for the Dorag, or mixing-zone, model for dolomitization. Field, petrographic, and geochemical evidence suggests a genetic link between the pervasive dolomite, trace Mississippi Valley–type (MVT) minerals, and potassium (K)-silicate minerals in these rocks, which preserve a regional hydrothermal signature. Constraints were placed on the conditions of water-rock interaction using fluid-inclusion methods, cathodoluminescence and plane-light petrography, stable isotopic analyses, and organic maturity data. Homogenization temperatures of two-phase aqueous fluid inclusions in dolomite, sphalerite, and quartz range between 65 and 120°C. Freezing data suggest a Na-Ca-Mg-Cl-H2O fluid with salinities between 13 and 28 wt.% NaCl equivalent. The pervasive dolomitization of Paleozoic rocks on and adjacent to the Wisconsin arch was the result of water-rock interaction with dense brines at elevated temperatures, and it was coeval with regional trace MVT mineralization and K-silicate diagenesis. A reevaluation of the Dorag (mixing-zone) model for dolomitization, in conjunction with convincing new petrographic and geochemical evidence, has ruled out the Dorag model as the process responsible for pervasive dolomitization along the Wisconsin arch and adds to the abundant body of literature that casts serious doubt about the viability of the Dorag model in general.

John Luczaj is an assistant professor of earth science in the Department of Natural and Applied Sciences at the University of Wisconsin–Green Bay. He earned his B. S. degree in geology from the University of Wisconsin–Oshkosh. This was followed by an M.S. degree in geology from the University of Kansas. He holds a Ph.D. in geology from Johns Hopkins University in Baltimore, Maryland. His recent interests include the investigation of water-rock interaction in Paleozoic sedimentary rocks in the Michigan Basin and eastern Wisconsin. Previous research activities involve mapping subsurface uranium distributions, reflux dolomitization, and U-Pb dating of Permian Chase Group carbonates in southwestern Kansas.

Pervasive dolomitization with subsequent hydrothermal alteration in the Clarke Lake gas field, Middle Devonian Slave Point Formation, British Columbia, Canada , 2006, Lonnee J. , Machel H. G.

The Clarke Lake gas field in British Columbia, Canada, is hosted in pervasively dolomitized Middle Devonian carbonates of the Slave Point Formation. The Clarke Lake field consists mostly of pervasive matrix dolomite and some saddle dolomite, the latter varying in volume from about zero in limestones to normally 20–40% (locally up to 80%) in dolostones over any given 10-m (33-ft) core interval. Some of the saddle dolomite is replacive, some is cement, and both varieties are associated with dissolution porosity and recrystallized matrix dolomite. The major objective of this study is to identify the causes and timing of matrix and saddle dolomite formation, specifically, whether these dolomites are hydrothermal. A comprehensive petrographic and geochemical examination indicates that pervasive matrix dolomitization was accomplished by long-distance migration of halite-saturated brines during the Late Devonian toMississippian. Fluid-inclusion homogenization temperatures suggest about 150 (uncorrected) to 190jC (corrected) at the time of matrix dolomitization. These temperatures differ markedly from most published work on the dolomitized Devonian reefs in the Alberta Basin south of the Peace River arch, where pervasive matrix dolomitization was accomplished by advection of slightly modified seawater at temperatures of about 60–80jC, and where no hydrothermal influence was ever present. The saddle dolomites at Clarke Lake are not cogenetic with matrix dolomite and are not the product of hydrothermal dolomitization (sensu stricto). Instead, they formed through the hydrothermal alteration of matrix dolomite by way of invasion of a gypsum-saturated brine during periods of extremely high heat flow and regional plate-margin tectonics in the Late Devonian to Mississippian. Fluidinclusion homogenization temperatures suggest that hydrothermal alteration occurred between 230 (uncorrected) and 267jC (corrected), which is significantly higher than the maximumtemperature of about 190jC attained by the Slave Point Formation during burial. The sources of the halite- and gypsum-saturated brines are Middle Devonian evaporite depositional environments roughly 200 km (124 mi) south and/or east of Clarke Lake, near the Peace River arch

Tectonic-hydrothermal brecciation associated with calcite precipitation and permeability destruction in Mississippian carbonate reservoirs, Montana and Wyoming , 2006, Katz D. A. , Eberli G. P. , Swart P. K. , Smith Jr. L. B.

The Mississippian Madison Formation contains abundant fracture zones and breccias that are hydrothermal in origin based on their morphology, distribution, and geochemical signature. The hydrothermal activity is related to crustal shortening during the Laramide orogeny. Brecciation is accompanied by dedolomitization, late-stage calcite precipitation, and porosity occlusion, especially in outcrop dolomites. The tectonic-hydrothermal late-stage calcite reduces permeability in outcrops and, potentially, high-quality subsurface reservoir rocks of the subsurface Madison Formation, Bighorn Basin. The reduction of permeability and porosity is increased along the margins of the Bighorn Basin but not predictable at outcrop scale. The destruction of porosity and permeability by hydrothermal activity in the Madison Formation is unique in comparison to studies that document enhanced porosity and permeability and invoke hydrothermal dolomitization models. Hydrothermal breccias from the Owl Creek thrust sheet are classified into four categories based on fracture density, calcite volume, and clast orientation. Shattered breccias dominate the leading edge of the tip of the Owl Creek thrust sheet in the eastern Owl Creek Mountains, where tectonic deformation is greatest, whereas fracture, mosaic, and chaotic breccias occur throughout the Bighorn Basin. The breccias are healed by calcite cements with d18O values ranging between _26.5 and _15.1xPeedee belemnite (PDB), indicating that the cements were derived from isotopically depleted fluids with elevated temperatures. In the chaotic and mosaic breccia types, large rotated and angular clasts of the host rock float in the matrix of coarse and nonzoned late-stage calcite. This appearance, combined with similar d18O values across even large calcite veins, indicates that the calcite precipitated rapidly after brecciation. Values for d13C(_5–12xPDB) from the frontal part of the Owl Creek thrust sheet indicate equilibrium between methane and CO2-bearing fluids at about 180jC. Fluid inclusions from the eastern basin margin show that these cements are in equilibrium with fluids having minimum temperatures between 120 and 140jC and formed from relatively low-salinity fluids, less than 5 wt.% NaCl. Strontium isotope ratios of these hydrothermal fluids are more radiogenic than proposed values for Mississippian seawater, suggesting that the fluids mixed with felsic-rich basement before migrating vertically into the Madison Formation. We envisage that the tectonic-hydrothermal late-stage calcitecemented breccias and fractures originated from undersaturated meteoric ground waters that migrated into the burial environment while dissolving and incorporating Ca2+ and CO3 2_ and radiogenic Sr from the dissolution of the surrounding carbonates and the felsic basement, respectively. In the burial environment, these fluids were heated and mixed with hypersaline brines from deeply buried parts of the basement. Expulsion of these fluids along basementrooted thrust faults into the overlying strata, including the Madison Formation, occurred most likely during shortening episodes of the Laramide orogeny by earthquake-induced rupturing of the host rock. The fluids were injected forcefully and in an explosive manner into the Madison Formation, causing brecciation and fracturing of the host rock, whereas the subsequent and sudden decrease in the partial pressure of CO2 caused the rapid precipitation of calcite cements. The explosive nature of hydrothermal fluid migration ultimately produces heterogeneities in reservoir-quality carbonates. In general, flow units in the Madison Formation are related to sequence boundaries, which create vertical subdivisions in the porous dolomite. The late-stage calcite cement surrounds hydrothermal breccia clasts and invades the dolomite, reducing porosity and permeability of the reservoir-quality rock. As a consequence, horizontal flow barriers and compartments are established that are locally unpredictable in their location and extent and regionally predictable along the margins of the Bighorn Basin. 

Burial dolomitization and dissolution of Upper Jurassic Abenaki platform carbonates, Deep Panuke reservoir, Nova Scotia, Canada, 2006, Wierzbicki R. , Dravis J. J. , Alaasm I. , Harland N.

A large gas reservoir was discovered in the previously unproductive Jurassic-aged Abenaki carbonate margin in 1998. Most of the reservoir porosity is developed in dolostones. These dolostones replaced preexisting wackestones, packstones, and grainstones(?) associated with reefal and adjacent depositional environments. Many dolomites were subsequently recrystallized or dissolved, accounting for much of the preserved secondary porosity. Subsequent fracturing helped enhance reservoir permeabilities. Enhanced petrographic techniques established that dissolution of previously dolomitized fabrics generated much of the secondary porosity in these dolostones. Diffused plane-polarized light revealed relict grains and textures invisible with standard microscopic observations. Petrographic and geochemical observations also confirmed that dissolution occurred under deep-burial conditions after incipient pressure solution. Dissolutionwas not confined to the centers of dolomitized grains, as is commonly seen when remnant calcitic grains dissolve out during the advanced stages of replacement dolomitization. Instead, dissolution was random within relict grains, as isolated dolomite crystals were also variably dissolved. The geochemistry of these dolomites and associated late-stage calcites implied precipitation from basinal hot fluids, as well as hydrothermal fluids. Later diagenetic fluids, either acidic or calcium rich, or perhaps both at different times (based on associated mineralization), seemingly promoted dolomite dissolution. The presence of tectonic fractures and stylolites, helium gas, and faults observed in seismic data implied that dolomitization and subsequent dissolution along the Abenaki platform margin were controlled by reactivated wrench faults tied to basement. On a finer scale, diagenetic fluids moved through fractures and pressuresolution seams. The data collected to date support our contention that the dolomitization and dissolution process, which has created most of the porosity in the Abenaki reservoir, was poststylotization and deeper burial in origin. Given the timing of tectonic activity in the area and its inferred connection to diagenesis, it is probable that at least a part of the diagenetic fluids were hydrothermal in nature 

Outcrop analog for TrentonBlack River hydrothermal dolomite reservoirs, Mohawk Valley, New York , 2006, Slater B. E. , Smith Jr. L. B.

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that the area has undergone a significant faultrelated hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally a Lower Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A three-dimensional (3-D) ground-penetrating radar (GPR) survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines, and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or sags flanked by anticlines. The dolomite structures are highly localized, occurring around faults, and are absent away from the faults and fractures. Trenches cut across the outcrop help relate offset along faults to the overall geometry of the dolomitized bodies. Geochemical analysis, although helpful in characterizing the conditions of dolomitization, does not define its origin absolutely. This study uses fluid inclusions, stable isotopes, 3-D GPR, core analysis, and surficial observations, which all show a link between faulting, dolomitization, and other hydrothermal alteration. Although the outcrop is much too small and shallow to act as a producing gas field, it serves as a scaled analog for the Trenton–Black River hydrothermal dolomite reservoirs of eastern United States. It may therefore be studied to help petroleum geologists characterize existing gas plays and prospect future areas of exploration.

Nonsulfide and sulfide-rich zinc mineralizations in the Vazante, Ambrsia and Fagundes deposits, Minas Gerais, Brazil: Mass balance and stable isotope characteristics of the hydrothermal alterati, 2007, Soares Monteiro Lena Virgí, Nia, Bettencourt Jorge Silva, Juliani Caetano, De Oliveira Tolentino Flvio
The Vazante Group hosts the Vazante nonsulfide zinc deposit, which comprises high-grade zinc silicate ore (ZnSiO4), and late-diagenetic to epigenetic carbonate-hosted sulfide-rich zinc deposits (e.g. Morro Agudo, Fagundes, and Ambrósia). In the sulfide-rich deposits, hydrothermal alteration involving silicification and dolomitization was related with ground preparation of favorable zones for fluid migration (e.g. Fagundes) or with direct interaction with the metalliferous fluid (e.g. Ambrósia). At Vazante, hydrothermal alteration resulted in silicification and dolomite, siderite, jasper, hematite, and chlorite formation. These processes were accompanied by strong relative gains of SiO2, Fe2O3(T), Rb, Sb, V, U, and La, which are typically associated with the nonsulfide zinc mineralization. All sulfide-rich zinc ores in the district display a similar geochemical signature suggesting a common metal source from the underlying sedimentary sequences. Oxygen and carbon isotope compositions of hydrothermally altered rocks reveal a remarkable alteration halo at the Vazante deposit, which is not a notable feature in the sulfide-rich deposits. This pattern could be attributed to fluid mixing processes involving the metalliferous fluid and channelized meteoric water, which may control the precipitation of the Vazante nonsulfide ore. Sulfide deposition resulted from fluid?rock interaction processes and mixing between the ascending metalliferous fluids and sulfur-rich tectonic brines derived from reduced shale units.

Paleokarst reservoirs and gas accumulation in the Jingbian field, Ordos Basin, 2008, Li J. , Zhang W. , Luo X. , Hu G.

The Jingbian gas field in central Ordos Basin, with a proven initial in place gas reserve of approximately 11 trillion cubic meters, is the largest paleokarst carbonate gas field in China. Paleokarst in Ordovician strata of central Ordos most commonly occurs in the paleoweathering surface of the O1m5 member of the Majiagou Formation. The karst intervals are generally proximal to the sub-Upper Paleozoic unconformity; however, dissolution features in strata well below that exposure surface are possibly related to intra-Majiagou Formation unconformities. The quality of gas reservoirs are initially controlled by sedimentary facies, with anhydrite-bearing dolomite flat facies being the most favorable zones for dissolution and dolomitization to form karst and large/small dissolution cavities. The gases are generally dry, derived dominantly from the overlying Carboniferous–Permian coal measures. The gases are accumulated in stratigraphic traps related to karst paleo-geomorphology and lithologic traps associated with late diagenetic features of carbonate rocks. Although the precise timings of the thermal events during the evolution of the Ordos Basin are still subject to considerable debate, there is a general consensus that events occurring during the Yenshanian orogeny (150–115 Ma) were the most important for the Paleozoic source rocks. It appears that two episodes of hydrocarbon charge have occurred in the Ordovician gas reservoirs in the Jingbian field.  

Fluid flow reconstruction in karstified Panormide platform limestones (north-central Sicily): Implications for hydrocarbon prospectivity in the Sicilian fold and thrust belt, 2010, Dewever B. , Berwouts I. , Swennen R. , Breesch L. , Ellam R. M.

Diagenetic analysis based on field and petrographic observations, isotope and microthermometric data was used to reconstruct the fluid flow history of the Cretaceous shallow water limestones from the Panormide platform exposed in north-central Sicily. Analysis focused on diagenetic products in cavities and dissolution enlarged fractures of the karstified limestones that occur just below a regional unconformity. The fluid flow history could be broken down into five stages that were linked to the kinematic and burial history of the region. (1) Petrography (zoned cathodoluminescence and speleothem textures) and stable isotopes (6.5 PDB &/Tm_2 to _5 _C), but at increasingly higher temperatures (Th 60–120 _C). This has been interpreted as precipitation during Oligocene foredeep burial. (4) Hot (Th 130–180 _C), low saline (Tm he low salinity and relatively high d18OSMOW signatures of the fluids are interpreted to be the result of clay dewatering reactions. The presence of bitumen and associated fluorite with hydrocarbon inclusions at this stage in the paragenesis constrains the timing of oil migration in the region. (5) Finally, high saline fluids with elevated 87Sr/86Sr (0.7095–0.7105) signatures invaded the karst system. This last fluid flow event was possibly coeval with localized dolomitization and calcite cementation along high-angle faults of Pliocene age, as suggested by identical radiogenic signatures of these diagenetic products.

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