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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That fluorite is a cave mineral - caf2 [11].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for h2s (Keyword) returned 81 results for the whole karstbase:
Showing 76 to 81 of 81
Hypogene Sulfuric Acid Speleogenesis and rare sulfate minerals in Baume Galinière Cave (Alpes-de-Haute-Provence, France). Record .., 2015, Audra P. , Gázquez F. , Rull F. , Bigot J. Y. , Camus H.

The oxidation of hydrocarbons and sulfide sources (H2S, pyrite) produces sulfuric acid that strongly reacts with bedrock, causing limestone dissolution and complex interactions with other minerals from the bedrock or from cave fillings, mainly clays. This type of cave development, known as Sulfuric Acid Speleogenesis (SAS), is a subcategory of hypogene speleogenesis, where aggressive water rises from depth. It also produces uncommon minerals, mainly sulfates, the typical byproducts of SAS. Baume Galinière is located in Southern France, in the Vaucluse spring watershed. This small maze cave displays characteristic SAS features such as corrosion notches, calcite geodes, iron crusts, and various sulfate minerals. Sulfur isotopes of SAS byproducts (jarosite and gypsum) clearly show they derive from pyrite oxidation. Using XRD and micro-Raman spectroscopy, thirteen minerals were identified, including elemental sulfur, calcite, quartz, pyrite, goethite, gypsum, and fibroferrite, plus all of the six members of the jarosite subgroup (jarosite, argentojarosite, ammoniojarosite, hydroniumjarosite, natrojarosite, plumbojarosite). The Baume Galinière deposits are the first documented cave occurrence of argentojarosite and the second known occurrence of plumbojarosite, hydronium jarosite, ammoniojarosite, and fibroferrite. In the Vaucluse watershed, there were numerous upwellings of deep water along major faults, located at the contact of the karstic aquifer and the overlying impervious covers. The mixing of deep and meteoric waters at shallow depths caused pyrite depositions in numerous caves, including Baume Galinière. Sulfuric Acid Speleogenesis occurred later after base-level drop, when the cave was under shallow phreatic conditions then in the vadose zone, with oxidation of pyrites generating sulfuric acid. Attenuated oxidation is still occurring through condensation of moisture from incoming air. Baume Galinière Cave records the position of the semi-impervious paleo-cover and documents its retreat in relationship to valley incision caused by uplift and tilting of the Vaucluse block during the Neogene.


Sulfuric acid speleogenesis (SAS) close to the water table: Examples from southern France, Austria, and Sicily, 2015,

Caves formed by rising sulfuric waters have been described from all over the world in a wide variety of climate  settings, from arid regions to mid-latitude and alpine areas. H2S is generally formed at depth by reduction of  sulfates in the presence of hydrocarbons and is transported in solution through the deep aquifers. In tectonically  disturbed areas major fractures eventually allow these H2S-bearing fluids to rise to the surface where oxidation  processes can become active producing sulfuric acid. This extremely strong acid reacts with the carbonate  bedrock creating caves, some of which are among the largest and most spectacular in the world. Production of  sulfuric acid mostly occurs at or close to the water table but also in subaerial conditions in moisture films and  droplets in the cave environment. These caves are generated at or immediately above the water table, where  condensation–corrosion processes are dominant, creating a set of characteristic meso- and micromorphologies.  Due to their close connection to the base level, these caves can also precisely record past hydrological and  geomorphological settings. Certain authigenic cave minerals, produced during the sulfuric acid speleogenesis  (SAS) phase, allow determination of the exact timing of speleogenesis. This paper deals with the morphological,  geochemical and mineralogical description of four very typical sulfuric acid water table caves in Europe: the  Grotte du Chat in the southern French Alps, the Acqua Fitusa Cave in Sicily (Italy), and the Bad Deutsch Altenburg  and Kraushöhle caves in Austria


Research frontiers in speleogenesis. Dominant processes, hydrogeological conditions and resulting cave patterns, 2015,

Speleogenesis is the development of well-organized cave systems by fluids moving through fissures of a soluble rock. Epigenic caves induced by biogenic CO2 soil production are dominant, whereas hypogenic caves resulting from uprising deep flow not directly connected to adjacent recharge areas appear to be more frequent than previously considered. The conceptual models of epigenic cave development moved from early models, through the “four-states model” involving fracture influence to explain deep loops, to the digital models demonstrating the adjustment of the main flow to the water table. The relationships with base level are complex and cave levels must be determined from the elevation of the vadose-phreatic transitions. Since flooding in the epiphreatic zone may be important, the top of the loops in the epiphreatic zone can be found significantly high above the base level. The term Paragenesis is used to describe the upward development of conduits as their lower parts fill with sediments. This process often records a general baselevel rise. Sediment influx is responsible for the regulation of long profiles by paragenesis and contributes to the evolution of profiles from looping to water table caves. Dating methods allow identification of the timing of cave level evolution. The term Ghost-rock karstification is used to describe a 2-phase process of speleogenesis, with a first phase of partial solution of rock along fractures in low gradient conditions leaving a porous matrix, the ghost-rock, then a second phase of mechanical removing of the ghost-rock mainly by turbulent flow in high gradient conditions opening the passages and forming maze caves. The first weathering phase can be related either to epigenic infiltration or to hypogenic upflow, especially in marginal areas of sedimentary basins. The vertical pattern of epigenic caves is mainly controlled by timing, geological structure, types of flow and base-level changes. We define several cave types as (1) juvenile, where they are perched above underlying aquicludes; (2) looping, where recharge varies greatly with time, to produce epiphreatic loops; (3) water-table caves where flow is regulated by a semi-pervious cover; and (4) caves in the equilibrium stage where flow is transmitted without significant flooding. Successive base-level drops caused by valley entrenchment make cave levels, whereas baselevel rise is defined in the frame of the Per ascensum Model of Speleogenesis (PAMS), where deep passages are flooded and drain through vauclusian springs. The PAMS can be active after any type of baselevel rise (transgression, fluvial aggradation, tectonic subsidence) and explains most of the deep phreatic cave systems except for hypogenic.

The term Hypogenic speleogenesis is used to describe cave development by deep upflow independent of adjacent recharge areas. Due to its deep origin, water frequently has a high CO2-H2S concentration and a thermal anomaly, but not systemati­cally. Numerous dissolution processes can be involved in hypogenic speleogenesis, which often include deep-seated acidic sources of CO2 and H2S, “hydrothermal” cooling, mixing corrosion, Sulfuric Acid Speleogenesis (SAS), etc. SAS particularly involves the condensation-corrosion processes, resulting in the fast expansion of caves above the water table, i.e. in an atmo­spheric environment. The hydrogeological setting of hypogenic speleogenesis is based on the Regional Gravity Flow concept, which shows at the basin scales the sites of convergences and upflows where dissolution focuses. Each part of a basin (mar­ginal, internal, deep zone) has specific conditions. The coastal basin is a sub-type. In deformed strata, flow is more complex according to the geological structure. However, upflow and hypogenic speleogenesis concentrate in structural highs (buried anticlines) and zones of major disruption (faults, overthrusts). In disrupted basins, the geothermal gradient “pumps” the me­teoric water at depth, making loops of different depths and characteristics. Volcanism and magmatism also produce deep hypogenic loops with “hyperkarst” characteristics due to a combination of deep-seated CO2, H2S, thermalism, and microbial activity. In phreatic conditions, the resulting cave patterns

can include geodes, 2–3D caves, and giant ascending shafts. Along the water table, SAS with thermal air convection induces powerful condensation-corrosion and the development of upwardly dendritic caves, isolated chambers, water table sulfuricacid caves. In the vadose zone, “smoking” shafts evolve under the influence of geothermal gradients producing air convectionand condensation-corrosion.

Likely future directions for research will probably involve analytical and modeling methods, especially using isotopes, dating, chemical simulations, and field investigations focused on the relationships between processes and resulting morphologies.


Research frontiers in speleogenesis. Dominant processes, hydrogeological conditions and resulting cave patterns, 2015,

Speleogenesis is the development of well-organized cave systems by fluids moving through fissures of a soluble rock. Epigenic caves induced by biogenic CO2 soil production are dominant, whereas hypogenic caves resulting from uprising deep flow not directly connected to adjacent recharge areas appear to be more frequent than previously considered. The conceptual models of epigenic cave development moved from early models, through the “four-states model” involving fracture influence to explain deep loops, to the digital models demonstrating the adjustment of the main flow to the water table. The relationships with base level are complex and cave levels must be determined from the elevation of the vadose-phreatic transitions. Since flooding in the epiphreatic zone may be important, the top of the loops in the epiphreatic zone can be found significantly high above the base level. The term Paragenesis is used to describe the upward development of conduits as their lower parts fill with sediments. This process often records a general baselevel rise. Sediment influx is responsible for the regulation of long profiles by paragenesis and contributes to the evolution of profiles from looping to water table caves. Dating methods allow identification of the timing of cave level evolution. The term Ghost-rock karstification is used to describe a 2-phase process of speleogenesis, with a first phase of partial solution of rock along fractures in low gradient conditions leaving a porous matrix, the ghost-rock, then a second phase of mechanical removing of the ghost-rock mainly by turbulent flow in high gradient conditions opening the passages and forming maze caves. The first weathering phase can be related either to epigenic infiltration or to hypogenic upflow, especially in marginal areas of sedimentary basins. The vertical pattern of epigenic caves is mainly controlled by timing, geological structure, types of flow and base-level changes. We define several cave types as (1) juvenile, where they are perched above underlying aquicludes; (2) looping, where recharge varies greatly with time, to produce epiphreatic loops; (3) water-table caves where flow is regulated by a semi-pervious cover; and (4) caves in the equilibrium stage where flow is transmitted without significant flooding. Successive base-level drops caused by valley entrenchment make cave levels, whereas baselevel rise is defined in the frame of the Per ascensum Model of Speleogenesis (PAMS), where deep passages are flooded and drain through vauclusian springs. The PAMS can be active after any type of baselevel rise (transgression, fluvial aggradation, tectonic subsidence) and explains most of the deep phreatic cave systems except for hypogenic.

The term Hypogenic speleogenesis is used to describe cave development by deep upflow independent of adjacent recharge areas. Due to its deep origin, water frequently has a high CO2-H2S concentration and a thermal anomaly, but not systemati­cally. Numerous dissolution processes can be involved in hypogenic speleogenesis, which often include deep-seated acidic sources of CO2 and H2S, “hydrothermal” cooling, mixing corrosion, Sulfuric Acid Speleogenesis (SAS), etc. SAS particularly involves the condensation-corrosion processes, resulting in the fast expansion of caves above the water table, i.e. in an atmo­spheric environment. The hydrogeological setting of hypogenic speleogenesis is based on the Regional Gravity Flow concept, which shows at the basin scales the sites of convergences and upflows where dissolution focuses. Each part of a basin (mar­ginal, internal, deep zone) has specific conditions. The coastal basin is a sub-type. In deformed strata, flow is more complex according to the geological structure. However, upflow and hypogenic speleogenesis concentrate in structural highs (buried anticlines) and zones of major disruption (faults, overthrusts). In disrupted basins, the geothermal gradient “pumps” the me­teoric water at depth, making loops of different depths and characteristics. Volcanism and magmatism also produce deep hypogenic loops with “hyperkarst” characteristics due to a combination of deep-seated CO2, H2S, thermalism, and microbial activity. In phreatic conditions, the resulting cave patterns

can include geodes, 2–3D caves, and giant ascending shafts. Along the water table, SAS with thermal air convection induces powerful condensation-corrosion and the development of upwardly dendritic caves, isolated chambers, water table sulfuricacid caves. In the vadose zone, “smoking” shafts evolve under the influence of geothermal gradients producing air convectionand condensation-corrosion.

Likely future directions for research will probably involve analytical and modeling methods, especially using isotopes, dating, chemical simulations, and field investigations focused on the relationships between processes and resulting morphologies.


Research frontiers in speleogenesis. Dominant processes, hydrogeological conditions and resulting cave patterns, 2015,

Speleogenesis is the development of well-organized cave systems by fluids moving through fissures of a soluble rock. Epigenic caves induced by biogenic CO2 soil production are dominant, whereas hypogenic caves resulting from uprising deep flow not directly connected to adjacent recharge areas appear to be more frequent than previously considered. The conceptual models of epigenic cave development moved from early models, through the “four-states model” involving fracture influence to explain deep loops, to the digital models demonstrating the adjustment of the main flow to the water table. The relationships with base level are complex and cave levels must be determined from the elevation of the vadose-phreatic transitions. Since flooding in the epiphreatic zone may be important, the top of the loops in the epiphreatic zone can be found significantly high above the base level. The term Paragenesis is used to describe the upward development of conduits as their lower parts fill with sediments. This process often records a general baselevel rise. Sediment influx is responsible for the regulation of long profiles by paragenesis and contributes to the evolution of profiles from looping to water table caves. Dating methods allow identification of the timing of cave level evolution. The term Ghost-rock karstification is used to describe a 2-phase process of speleogenesis, with a first phase of partial solution of rock along fractures in low gradient conditions leaving a porous matrix, the ghost-rock, then a second phase of mechanical removing of the ghost-rock mainly by turbulent flow in high gradient conditions opening the passages and forming maze caves. The first weathering phase can be related either to epigenic infiltration or to hypogenic upflow, especially in marginal areas of sedimentary basins. The vertical pattern of epigenic caves is mainly controlled by timing, geological structure, types of flow and base-level changes. We define several cave types as (1) juvenile, where they are perched above underlying aquicludes; (2) looping, where recharge varies greatly with time, to produce epiphreatic loops; (3) water-table caves where flow is regulated by a semi-pervious cover; and (4) caves in the equilibrium stage where flow is transmitted without significant flooding. Successive base-level drops caused by valley entrenchment make cave levels, whereas baselevel rise is defined in the frame of the Per ascensum Model of Speleogenesis (PAMS), where deep passages are flooded and drain through vauclusian springs. The PAMS can be active after any type of baselevel rise (transgression, fluvial aggradation, tectonic subsidence) and explains most of the deep phreatic cave systems except for hypogenic.

The term Hypogenic speleogenesis is used to describe cave development by deep upflow independent of adjacent recharge areas. Due to its deep origin, water frequently has a high CO2-H2S concentration and a thermal anomaly, but not systemati­cally. Numerous dissolution processes can be involved in hypogenic speleogenesis, which often include deep-seated acidic sources of CO2 and H2S, “hydrothermal” cooling, mixing corrosion, Sulfuric Acid Speleogenesis (SAS), etc. SAS particularly involves the condensation-corrosion processes, resulting in the fast expansion of caves above the water table, i.e. in an atmo­spheric environment. The hydrogeological setting of hypogenic speleogenesis is based on the Regional Gravity Flow concept, which shows at the basin scales the sites of convergences and upflows where dissolution focuses. Each part of a basin (mar­ginal, internal, deep zone) has specific conditions. The coastal basin is a sub-type. In deformed strata, flow is more complex according to the geological structure. However, upflow and hypogenic speleogenesis concentrate in structural highs (buried anticlines) and zones of major disruption (faults, overthrusts). In disrupted basins, the geothermal gradient “pumps” the me­teoric water at depth, making loops of different depths and characteristics. Volcanism and magmatism also produce deep hypogenic loops with “hyperkarst” characteristics due to a combination of deep-seated CO2, H2S, thermalism, and microbial activity. In phreatic conditions, the resulting cave patterns

can include geodes, 2–3D caves, and giant ascending shafts. Along the water table, SAS with thermal air convection induces powerful condensation-corrosion and the development of upwardly dendritic caves, isolated chambers, water table sulfuricacid caves. In the vadose zone, “smoking” shafts evolve under the influence of geothermal gradients producing air convectionand condensation-corrosion.

Likely future directions for research will probably involve analytical and modeling methods, especially using isotopes, dating, chemical simulations, and field investigations focused on the relationships between processes and resulting morphologies.


Research frontiers in speleogenesis. Dominant processes, hydrogeological conditions and resulting cave patterns, 2015,

Speleogenesis is the development of well-organized cave systems by fluids moving through fissures of a soluble rock. Epigenic caves induced by biogenic CO2 soil production are dominant, whereas hypogenic caves resulting from uprising deep flow not directly connected to adjacent recharge areas appear to be more frequent than previously considered. The conceptual models of epigenic cave development moved from early models, through the “four-states model” involving fracture influence to explain deep loops, to the digital models demonstrating the adjustment of the main flow to the water table. The relationships with base level are complex and cave levels must be determined from the elevation of the vadose-phreatic transitions. Since flooding in the epiphreatic zone may be important, the top of the loops in the epiphreatic zone can be found significantly high above the base level. The term Paragenesis is used to describe the upward development of conduits as their lower parts fill with sediments. This process often records a general baselevel rise. Sediment influx is responsible for the regulation of long profiles by paragenesis and contributes to the evolution of profiles from looping to water table caves. Dating methods allow identification of the timing of cave level evolution. The term Ghost-rock karstification is used to describe a 2-phase process of speleogenesis, with a first phase of partial solution of rock along fractures in low gradient conditions leaving a porous matrix, the ghost-rock, then a second phase of mechanical removing of the ghost-rock mainly by turbulent flow in high gradient conditions opening the passages and forming maze caves. The first weathering phase can be related either to epigenic infiltration or to hypogenic upflow, especially in marginal areas of sedimentary basins. The vertical pattern of epigenic caves is mainly controlled by timing, geological structure, types of flow and base-level changes. We define several cave types as (1) juvenile, where they are perched above underlying aquicludes; (2) looping, where recharge varies greatly with time, to produce epiphreatic loops; (3) water-table caves where flow is regulated by a semi-pervious cover; and (4) caves in the equilibrium stage where flow is transmitted without significant flooding. Successive base-level drops caused by valley entrenchment make cave levels, whereas baselevel rise is defined in the frame of the Per ascensum Model of Speleogenesis (PAMS), where deep passages are flooded and drain through vauclusian springs. The PAMS can be active after any type of baselevel rise (transgression, fluvial aggradation, tectonic subsidence) and explains most of the deep phreatic cave systems except for hypogenic.

The term Hypogenic speleogenesis is used to describe cave development by deep upflow independent of adjacent recharge areas. Due to its deep origin, water frequently has a high CO2-H2S concentration and a thermal anomaly, but not systemati­cally. Numerous dissolution processes can be involved in hypogenic speleogenesis, which often include deep-seated acidic sources of CO2 and H2S, “hydrothermal” cooling, mixing corrosion, Sulfuric Acid Speleogenesis (SAS), etc. SAS particularly involves the condensation-corrosion processes, resulting in the fast expansion of caves above the water table, i.e. in an atmo­spheric environment. The hydrogeological setting of hypogenic speleogenesis is based on the Regional Gravity Flow concept, which shows at the basin scales the sites of convergences and upflows where dissolution focuses. Each part of a basin (mar­ginal, internal, deep zone) has specific conditions. The coastal basin is a sub-type. In deformed strata, flow is more complex according to the geological structure. However, upflow and hypogenic speleogenesis concentrate in structural highs (buried anticlines) and zones of major disruption (faults, overthrusts). In disrupted basins, the geothermal gradient “pumps” the me­teoric water at depth, making loops of different depths and characteristics. Volcanism and magmatism also produce deep hypogenic loops with “hyperkarst” characteristics due to a combination of deep-seated CO2, H2S, thermalism, and microbial activity. In phreatic conditions, the resulting cave patterns

can include geodes, 2–3D caves, and giant ascending shafts. Along the water table, SAS with thermal air convection induces powerful condensation-corrosion and the development of upwardly dendritic caves, isolated chambers, water table sulfuricacid caves. In the vadose zone, “smoking” shafts evolve under the influence of geothermal gradients producing air convectionand condensation-corrosion.

Likely future directions for research will probably involve analytical and modeling methods, especially using isotopes, dating, chemical simulations, and field investigations focused on the relationships between processes and resulting morphologies.


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